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排序方式: 共有248条查询结果,搜索用时 15 毫秒
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Summary Complexes of platinum(II) with 2-(acetylamino)benzoic acid, 2-(benzoylamino)benzoic acid, maleanilic acid, malea-1-naphthanilic acid, 2-(phenylamino)benzoic acid, 2-[(2-aminophenylamino)carbonyl]benzoic acid, 2-(aminobenzoyl)benzoic acid, 2-[1-naphthalenylamino)-carbonyl]benzoic acid, 2-(2-aminobenzoylamino)-benzoic acid have been prepared and characterized by elemental analysis, molar conductivity measurements, thermal data and i.r., electronic and n.m.r. spectra. 相似文献
4.
Summary The mixed ligand complex, [Fe(Phen)2(N3)2] can be extracted into nitrobenzene giving a molar absorptivity of 16750 at 510 nm. This is the basis of a photometric method for iron which may be either in the trivalent or bivalent state. The new method is free from interference from a number of substances and is more sensitive than the ferroin method.
Zusammenfassung Der Eisen-Phenanthrolin-Azid-Mischkomplex [Fe(Phen)2(N3)2] ist mit Nitrobenzol extrahierbar und gibt bei 510 nm eine molare Absorption von 16750. Darauf läßt sich eine photometrische Bestimmungsmethode für zweioder dreiwertiges Eisen begründen. Diese wird von vielen Stoffen nicht gestört und ist empfindlicher als die Ferroinmethode.相似文献
5.
Several novel substituted bis(2‐pyridylimino)isoindolato (BPI) cobalt(II) and iron(II) complexes [M(BPI)(OAc)(H2O)] (M = Co: 1 ‐ 6, Fe: 7) have been synthesized by reaction of bis(2‐pyridylimino)isoindole derivatives with the corresponding metal(II) acetates. Reaction of 1‐6 with 1.5 ‐ 2 molar equivalents of t‐BuOOH gave the corresponding alkylperoxocobalt(III) complexes [Co(BPI)(OAc)(OOtBu)] (10 ‐ 15). Using an aqueous solution of t‐BuOOH (70 %), cyclohexene was selectively catalytically oxidized to the dialkylperoxide cyclohex‐2‐ene‐1‐t‐butylperoxide. 相似文献
6.
Foltz C Stecker B Marconi G Bellemin-Laponnaz S Wadepohl H Gade LH 《Chemical communications (Cambridge, England)》2005,(40):5115-5117
Chiral C3-symmetric trisoxazolines are highly efficient stereodirecting ligands in enantioselective Cu(II) Lewis acid catalysis which is based on the concept of a stereoelectronic hemilability of the divalent copper; in direct comparison with the analogous bisoxazoline systems they are more efficient in the enantioselective alpha-amination as well as the enantioselective Mannich reaction of prochiral beta-ketoesters. 相似文献
7.
Gade LH Renner P Memmler H Fecher F Galka CH Laubender M Radojevic S McPartlin M Lauher JW 《Chemistry (Weinheim an der Bergstrasse, Germany)》2001,7(12):2563-2580
A comprehensive study into the coordination chemistry of two C3-chiral tripodal amido ligands has been carried out. The amido ligands contain a trisilylmethane backbone and chiral peripheral substituents. The amine precursors. HC(SiMe2NH[(S)-1-phenylethyl]]3 (1) and HC[SiMe2NH[(R)-1-indanyl]]3 (2) were found to be in equilibrium in solution with the cyclic diamines HC[SiMe2N[(S)-1-phenylethyl]2](SiMe2NH-[(S)-1-phenylethyl]] (3) and HC[SiMe2NH[(R)-1-indanyl]][SiMe2NH[(R)-1-indanyl]) (4), which are generated upon ejection of one molecule of the chiral primary amine. Reaction of these equilibrium mixtures with three molar equivalents of butyllithium instantaneously gave the trilithium triamides HC[SiMe2N(Li)[(S)-1-phenylethyl]]3 (5) and HC[SiMe2N(Li)[(R)-1-indanyl]]3 (6), both of which were characterised by an X-ray diffraction study. Both lithium compounds possess a central heteroadamantane core, in which the two-coordinate Li atoms are additionally weakly solvated by the three aryl groups of the chiral peripheral substituents, the Li-C contacts being in the range of 2.65-2.73 A. Reaction of 5 and 6 with [TiCl4(thf)2] and ZrCl4 gave the corresponding amido complexes [TiCl-[HC[SiMe2N[(S)-1-phenylethyl]]3]] (7), [TiCl(HC[SiMe2N[(R)-1-indanyl]]3]] (8), [ZrCl[HC[SiMe2N[(S)-1-phenylethyl]]3]] (9) and [ZrCl[HC[SiMe2N[(R)-1-indanyl]]3]] (10), respectively. Of these, compound 7 was structurally characterised by X-ray structure analysis and was shown to possess a C3-symmetrical arrangement of the tripod ligand. The chiral anionic dinuclear complex [Li-(OEt2)4][Zr2Cl3[HC[SiMe2N[(S)-1-phenylethyl]]3]2] (11) was isolated from reaction mixtures leading to 9. An X-ray diffraction study established its dimeric structure, in which the chiral amido ligands cap the two metal centres, which are linked through three symmetrically arranged, bridging chloro ligands. Reaction of 9 and 10 with a series of alkyl Grignard and alkyllithium reagents yielded the corresponding alkylzirconium complexes. X-ray structure analyses of [Zr(CH3)[HC[SiMe2N[(S)-1-phenylethyl]]3]] (12) and [Zr(CH3)-[HC[SiMe2N)[(R)-1-indanyl]]3]] (20) established their detailed molecular arrangements. While the reaction of 12 with the aryl ketones PhC(O)R (R = CH = CHPh, iPr, Et) gave the corresponding C-O insertion products, which contain an additional chiral centre in the alkoxy group, with low stereoselectivity (0-40% de). The corresponding conversions with several aryl aldehydes yielded the alkoxo complexes with high stereoselectivity. Upon hydrolysis, the chiral alcohols were isolated and shown to have enantiomeric excesses between 68 and 82%. High stereodiscrimination was also observed in the insertion reactions of several chiral ketones and aldehydes. However, this was shown to originate primarily from the chirality of the substrate. In analogous experiments with carbonyl compounds, the ethyl- and butyl-zirconium analogues of 12 did not undergo CO insertion into the metal-alkyl bond. Instead, beta-elimination and formal insertion into the metal-hydride bond occurred. It was found that the elimination of the alkene was induced by 相似文献
8.
Vaman C Andreoiu C Bazin D Becerril A Brown BA Campbell CM Chester A Cook JM Dinca DC Gade A Galaviz D Glasmacher T Hjorth-Jensen M Horoi M Miller D Moeller V Mueller WF Schiller A Starosta K Stolz A Terry JR Volya A Zelevinsky V Zwahlen H 《Physical review letters》2007,99(16):162501
Rare isotope beams of neutron-deficient 106,108,110Sn from the fragmentation of 124Xe were employed in an intermediate-energy Coulomb excitation experiment. The measured B(E2,0(1)(+)-->2(1)(+)) values for 108Sn and 110Sn and the results obtained for the 106Sn show that the transition strengths for these nuclei are larger than predicted by current state-of-the-art shell-model calculations. This discrepancy might be explained by contributions of the protons from within the Z = 50 shell to the structure of low-energy excited states in this region. 相似文献
9.
Copper–Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations 下载免费PDF全文
Dr. Qing‐Hai Deng Christoph Rettenmeier Prof. Dr. Hubert Wadepohl Prof. Dr. Lutz H. Gade 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(1):93-97
The enantioselective trifluoromethylthiolation of β‐ketoesters using chiral copper–boxmi complexes as catalysts is reported. A number of α‐SCF3‐substituted β‐ketoesters have been obtained with up to >99 % enantiomeric excess (ee), and the trifluoromethylthiolated products were then transformed diastereoselectively to α‐SCF3‐β‐hydroxyesters with two adjacent quaternary stereocenters. 相似文献
10.
P. von Brentano C. Fransen A. Gade A. Lisetskiy N. Pietralla 《The European Physical Journal A - Hadrons and Nuclei》2002,15(1-2):99-103
Due to the recent development of radioactive beam production, various direct reaction studies in reversed kinematics have
been made to investigate the behavior of the N = 20 shell closure in the neutron-rich region. Coulomb excitation, proton inelastic scattering, and fragmentation of unstable
nuclei have been studied with γ-ray detection.
Received: 21 March 2002 / Accepted: 16 May 2002 / Published online: 31 October 2002
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ID="a"e-mail: motobaya@rikkyo.ne.jp 相似文献