First example of the formation of bipolar spiro σ-complexes from 6-bromo-5,7-dinitrobenzo[e]-1,2,3,4-tetrazine 1,3-di-N-oxide

The reactions of 3,5,7-trimethyltropolone and 2-(N-benzylamino)tropone with 6-bromo-5,7-dinitrobenzo[e]-1,2,3,4-tetrazine 1,3-di-N-oxide afforded novel bipolar spiro -complexes. The kinetic and activation parameters of the R,S-enantiotopomerization of a chiral spiro -complex of 2-(N-benzylamino)tropone were determined using dynamic ¹H NMR spectroscopy.     

On the charge transfer in the process of adsorption at the electrode/solution interface: Remarks on the paper “experimental determination and interpretation of the electrosorption valency γ” by J. Schultze and K. Vetter

A critical analysis shows that the approach to the estimation of the charge transfer in the process of adsorption at the electrode/solution interface used by Vetter and Schultze in the general case is not justified without introduction of non-thermodynamic models. This approach can prove useful in the investigation of the electric double layer within the limits of applicability of Grahame's model. A number of cases can however be cited where the approach of Schultze and Vetter is inapplicable. The conclusions of Schultze and Vetter regarding the adsorption of hydrogen at platinum are apparently based on some misunderstanding. In this case the thermodynamic approach^{6, 23} should be used.It would be more correct to call the quantity γ “the formal coefficient of charge transfer”, rather than “the electrosorption valency”.     

Determination of formal charge transfer coefficients in adsorption processes in the system Hg,Tl, Tl+, H2O: I. Electrocapillary curves of the first kind

The determination of the formal charge transfer coefficient n₂ from the equilibrium electrocapillary curves of the first kind (taken under the condition μ_Tl+=const) leads to values which are close to the values of the quantity l of Lorenz, obtained from a.c. measurements.     

Synthesis of 1,2,3,4-tetrazino[5,6-f]benzo-1,2,3,4-tetrazine 1,3,7,9-tetra-N-oxides

[reaction: see text] The novel heterocyclic system 10 with the phenanthrene type skeleton, in which the benzene ring is annulated with two 1,2,3,4-tetrazine 1,3-di-N-oxide rings, is of considerable interest in the context of the high nitrogen system stability and from a heteroaromaticity standpoint. The step-by-step synthetic approach to this system involves treatment of 5 with N2O5, resulting in the first 1,2,3,4-tetrazine 1,3-dioxide ring formation. The following displacement of the chlorine atom at the 6-position with ammonia and subsequent repeated treatment with N2O5 results in the second 1,2,3,4-tetrazine 1,3-dioxide ring formation. The structure of 10 was confirmed by a 13C and 14N NMR study.     

Investigation of the surface properties of platinum,rhodium and iridium electrodes in hydrofluoric acid solutions

The charging curves, the potentiodynamic curves and the isoelectric potential shifts have been measured on Pt, Rh and Ir electrodes in HF and HF + KF solutions in a Teflon cell. From the obtained data, the Γ_H⁺?? curves and the Δσ?? curves of the first kind have been calculated by means of the thermodynamic theory of the hydrogen electrode. The Γ_H⁺ values in 0.14 M HF and 0.3 M HF + 0.12 M KF are much less than in 0.005 M H₂SO₄ and 0.005 M H₂SO₄ + 0.5 M K₂SO₄ solutions. In the presence of F^? anions, the potentials ?_ε=0 and ?_Q=0 are by 25–55 mV more anodic than in the presence of SO^2?₄ anions. In an acidified fluoride solution the values of σ are higher than in an acidified sulfate solution. The analysis of the results obtained leads to the conclusion that on platinum metals the fluoride anions in the ?_r region investigated (from ?_r = 0 to ?_r = 900 mV) are the most weakly adsorbed anions.     

Ueber den Zusammenhang zwischen den balloelektrischen Erscheinungen und der Potentialdifferenz an der Trennungsfläche Gas/Lösung

Ohne Zusammenfassung     

The conjugacy character ofS n tends to be regular

Consider the regular and the conjugacy characters ofS _n as vectors in Euclidean space, with the standard inner product. Asn grows, the angle between them tends to zero and the ratio of their lengths tends to one. The two characters have therefore asymptotically similar decompositions into irreducible components.     

Rank of inclusion matrices and modular representation theory

We use results from the modular representation theory of the groupsS _n and GL _n (F _q ) to determine the rank of inclusion matrices.     

Temporal characteristics of nanosecond magnetization reversal of flat permalloy films

A comparative study was made of different time intervals characterizing nanosecond magnetization reversal of flat permalloy films. These intervals increase with increasing relative coercive force of the samples. The results obtained for the durations of the magnetization reversal by different methods are practically the same in the case of the fastest regimes and are different for the slow regimes.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 58–61, December, 1970.