Mixing and sweeping out

A weakly mixing transformationT and a sequence (d _n) are constructed such thatT is uniformly mixing on (d _n),T is uniformly sweeping out on ([αd _n]) for allα∈(0, 1), and for all rationalα∈(0, 1)T is not mixing on ([αd _n]).     

Student Attitudes and Calculus Reform

This paper compares the attitudes about mathematics of students from traditionally taught calculus classes and those from a “reformed” calculus course. The paper is based on three studies, which together present a consistent picture of student attitudes about calculus reform. The reformed course appeared to violate students' deeply held beliefs about the nature of mathematics and how it should be learned. Although during their first months in the reformed course most students disliked it, their attitudes gradually changed. One and 2 years after, reform students felt significantly more than the traditionally taught students that they better understood how math was used and that they had been required to understand math rather than memorize formulas.     

Mössbauer and infrared spectroscopic studies of novel mixed valence states in cobaltous ferrocyanides and ferricyanides

Novel mixed valence states have been obtained by the treatment of cobaltous ferrocyanides (Co⁺²Fe^II) and ferricyanides (Co⁺²Fe^III) in an ozone flow. The CN stretching bands occur at 2085 cm^–1 for Co⁺²Fe^II and at 2160 cm^–1 for Co⁺²Fe^III. After the ozonization process of Co⁺²Fe^II, an intense band approximately at 2125 cm^–1 is detected. This intermediate band must correspond to a mixed valence state of the type: Fe^II–CN–Co²⁺–NC–Fe^III Mössbauer spectra recorded in situ during the ozonization of Co⁺²Fe^II show the presence of two components: a doublet with isomer shift and quadrupole splitting values close to the cobalti ferricyanide and a very broad line for the mixed valence state. From the Mössbauer and infrared spectra of the aged samples of the Co⁺²Fe^II after ozonization, a relaxation process to the initial state of the samples is observed but the mixed valence state is stable.     

Delaunay graphs are almost as good as complete graphs

LetS be any set ofN points in the plane and let DT(S) be the graph of the Delaunay triangulation ofS. For all pointsa andb ofS, letd(a, b) be the Euclidean distance froma tob and let DT(a, b) be the length of the shortest path in DT(S) froma tob. We show that there is a constantc (≤((1+√5)/2) π≈5.08) independent ofS andN such that $$\frac{{DT(a,b)}}{{d(a,b)}}< c.$$      

Anionic hyperconjugation

Although hyperconjugation involving alkyl groups to a carbocation is a well-established concept, the analogous charge delocalization generated in anions by electronegative substitution has long been a subject of controversy. We have investigated this phenomenon for the β-hydroxyethyl and β-trifluoroethyl anions using ab initio electronic structure calculations. Split valence basis sets augmented by diffuse functions were used with fully optimized geometries. Three dimensional molecular orbital plots clearly show an in-plane HOMO-LUMO mixing of a C-X σ antibonding orbital with the carbon lone pair which yields hyperconjugative π bonding in the anti conformation. Deformation density maps further demonstrate that this delocalization leads to the development of a π component as well as a previously unrecognized sigma enhancement. These results support and extend the work of Apeloig and that of Schleyer and Kos, but are in opposition to the induction hypothesis of Streitwieser and Holtz. The recent experimental determination of the acidity of (CF₃)₃CH by Tatlow $\text{et al}$ and their interpretation in terms of fluorine hyperconjugation are also in accord with this work.     

Bang-bang optimal control for the dam problem

The dam problem with general geometry is considered. Fluid is drawn from the bottomS ₁ at a ratek where 0 k N, _{S 1} k M; the objective is to minimize the total pressure of the fluid in the dam. A bang-bang principle is established for any optimal controlk ₀, that is,k ₀ = 0 on a setA andk ₀ =N on the complement setS ₁ A. In the case of a rectangular dam the structure ofA is determined and the uniqueness of the minimizerk ₀ is established.This work is partially supported by National Science Foundation Grants DMS-8501397 and DMS-8420896.     

Simultaneous observation of coherent and incoherent resonant re-emission in the condensed phase

We report simultaneous observation of coherent resonance Raman scattering and incoherently broadened resonance fluorescence following excitation of cytochrome c in the α(0, 0) region. The influence of incoherent broadening processes on resonance Raman scattering experiments is considered.