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A series of sialyloligosaccharides was synthesized using the transglycolytic activity of the sialidases from Vibrio cholerae, Clostridium perfringens, Salmonella typhimurium, and Newcastle disease virus. According to their hydrolytic activities the sialidases from V. cholerae and C. perfringens catalyze preferentially the formation of sialyl alpha(2-6)-linkages whereas the sialidases from S.typhimurium and Newcastle disease virus show a distinct preference for alpha(2-3) directed sialylations. Using combined chemical and enzymatic methodologies structures such as T-(Thomsen-Friedenreich) antigen [beta-D-Gal-(1-3)-alpha-D-GalNAc-OThr], Tn-(Thomsen nouveau) antigen (alpha-D-GalNAc-OThr) and beta-D-Gal-(1-4)-alpha-D-2-deoxy-Gal-OMe were sialylated in alpha(2-3)- and alpha(2-6)-positions regioselectively or in high regioisomeric excess and purified by simple isolation procedures. Depending on the enzyme source and acceptor structure yields for transsialylation varied between 10 and 30%.  相似文献   
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Ternary Halides of the A3MX6 Type. II. The System Ag3?xNaxYCl6: Synthesis, Structures, Ionic Conductivity . The influence of the substitution of Ag+ by Na+ ions on the crystal structure and the ionic conductivity of Ag3YCl6 (stuffed LiSbF6-type structure) has been investigated. The system Ag3?xNaxYCl6 forms a complete solid solution. The stuffed LiSbF6-type structure is stable for all compositions. For compounds with Na+ contents of x > 1.67, the cryolite-type structure is observed as the high-temperature form. The transition temperature decreases steadily with increasing Na+ content. The “end member” phase Na3YCl6 transforms at 243 K from the monoclinic cryolite-type structure to the stuffed LiSbF6-type structure (trigonal, R3 ; a = 697.3(1), c = 1 868.4(14) pm, Z = 3; R = 0.094; Rw = 0.069). The crystal structures of Ag1.3Na1.7YCl6 (trigonal, R3 ; a = 691.5(2), c = 1 853.7(6) pm, Z = 3; R = 0.099, Rw = 0.081) and AgNa2YCl6 (trigonal, R3 ; a = 691.7(1), c = 1 853.9(5) pm, Z = 3; R = 0.099, Rw = 0.064) have also been determined. Both chlorides crystallize like Ag3YCl6 and Na3YCl6-I in the stuffed LiSbF6-type structure. The monovalent cations, Ag+ and Na+, are distributed over the five octahedral voids that are occupied by the Ag+ ions alone in Ag3YCl6. The ionic conductivity for compounds within the solid solution Ag3?xNaxYCl6 decreases with increasing Na+ content. The values for Na3YCl6 (σ = 1 · 10?6 Ω?1 cm?1 at T = 500 K) are by 2.5 to 3.5 orders of magnitude smaller than those for Ag3YCl6 (σ = 6 · 10?4 Ω?1 cm?1 at T = 500 K).  相似文献   
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The dipole moments of 24 selenophene analogs of the chalcones have been measured and have been compared with the data calculated by a vectorial additive scheme and also with their chemical structures. Considerations are expressed on the conformational state of the molecules of the compounds investigated. The existence of a correlation between the dipole moments the intramolecular distances, and the Hammett's -parameters has been shown. The applicability of Higashi's equation to the calculation of for , -unsaturated ketones is pointed out.  相似文献   
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Abstract

Acylations at the 6-position of alkyl glycosides were obtained using the esterification potential of lipases. Thus, sugars with two alkyl chains result showing columnar discotic phases. The correlation between the configuration of the sugar moieties and the different clearing points can be understood on the basis of simple stereochemical assumptions.  相似文献   
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Let k be a field and let Λ be an indecomposable finite dimensional k-algebra such that there is a stable equivalence of Morita type between Λ and a self-injective split basic Nakayama algebra over k. We show that every indecomposable finitely generated Λ-module V has a universal deformation ring R(Λ,V) and we describe R(Λ,V) explicitly as a quotient ring of a power series ring over k in finitely many variables. This result applies in particular to Brauer tree algebras, and hence to p-modular blocks of finite groups with cyclic defect groups.  相似文献   
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