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1.
Schôichi Ôta Franciszek Hugon Szafraniec 《Journal of Mathematical Analysis and Applications》2007,329(2):987-997
We are in progress of extending the family of ‘q-deformed operators’ considered in the previous papers by joining to them q-subnormal as well as q-formally subnormal ones. It turns out that q-positive definiteness, a notion generalizing Halmos' standard positive definiteness of bounded subnormal operators, is likewise central for our new scheme. 相似文献
2.
Czechowski F Golonka I Jezierski A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2004,60(6):1387-1394
The lignins separated from angiosperm and gymnosperm trees, peat and xylitic brown coal were investigated by quantitative EPR. Observed free radicals in lignins are sensitive to alkaline environment. Gaseous ammonia interacting with solid lignins in resonance cavity shifts quinone-hydroquinone equilibria towards formation of semiquinone anions. Complexation of copper(II) by lignins causes drastic decrease of the semiquinones in the matrices. Formation of lignin-Pb(II) complexes yielded radicals characterised by unusually low g-value (1.9999-2.0003). Monomeric structural units of the investigated lignins were recognised by pyrolysis with in situ methylation by tetramethylammonium hydroxide. Although for the natural lignins the mixture of normal semiquinone signals at g about 2.0034 and signals at g 1.9999 were observed, some monomeric components of lignins (e.g., caffeic acid, pyrogallol) gave pure lines at g = 1.9999. The bacterial oxidative biodegradation of lignin monomeric components and their Pb(II) complexes resulted in increase of the radical signals. 相似文献
3.
Franciszek Saczewski Anita Bulakowska Maria Gdaniec 《Journal of heterocyclic chemistry》2002,39(5):911-915
The ureidation reactions of 2‐ and 4‐picoline N‐oxides with 2‐chloro‐4,5‐dihydroimidazole are described. A mechanism of novel thioureidation reaction of 4‐picoline N‐oxide with 2‐(4,5‐dihydro‐1H‐imidazol‐2‐ylthioxy)‐4,5‐dihydro‐1H‐imidazole is proposed. Structural assignment is confirmed by 1H and 13C nmr as well as by X‐ray crystallography. 相似文献
4.
Zbigniew Gregorowicz Barbara Piwowarska Franciszek Buhl und Krystyna Kania 《Fresenius' Journal of Analytical Chemistry》1968,237(5):347-351
Zusammenfassung Es wurde eine UV-spektrophotometrische Methode zur Bestimmung der 2,2-Dicinchoninsäure beschrieben. Messung erfolgt bei pH 10 bei dem Absorptionsmaximum von 260 nm. Der Bestimmungsbereich beträgt 1,71–20,52 g der 2,2-Dicinchonin-Ionen in 25 ml Lösung. Ba2+, Sr2+, Ca2+, Mg2+, Ni2+, Co2+, Zn2+, Hg2+ und Al3+ in 100fachem sowie Pb2+ in 10fachem Überschuß verursachen keine Störungen. Blei in 20 fachem sowie Ag+ und Hg2
2+ in einfachem Überschuß verursachen Ausscheidung von Niederschlägen.
Summary An UV-spectrophotometric method for the determination of 2,2-dicinchonic acid is described. The absorption is measured in a solution of pH 10 at the maximum of 260 nm.The range of application of the method was 1,71 to 20,52 g of DC2– ions in 25 ml of solution. Ba2+, Sr2+, Ca2+, Mg2+, Ni2+, Co2+, Al3+, Zn2+, Hg2+ ions present in hundredfold excess do not interfere with the determination. Ag+, Hg2 2+ ions in one-fold and Pb2+ ion in twenty-fold excess cause the deposition of a precipitate, but five-fold and ten-fold excess of Pb2+ does not interfere.相似文献
5.
Synthesis of novel 5-methylidene-1,2,3,5-tetrahydro[2,1-b]-quinazoline derivatives 2-4 with potential biological activities mediated by alpha-adrenergic and/or imidazoline receptors was performed by reacting 2-chloro-4,5-dihydroimidazole (1) with the corresponding 2-aminoacetophenones. Compound 2, which incorporates an enamine moiety, underwent a 1,3-dipolar cycloaddition reaction with the appropriate nitrones 5-9 to give 1,2,3,5-tetrahydro-imidazo[2,1-b]quinazolin-5,5'-spiro-2',3'-diphenylisoxazol-idines 10-14. Reactions of the title compounds 2 and 4 with dimethyl acetylene-dicarboxylate (DMAD) afforded dimethyl 2-(2,3-dihydroimidazo[2,1-b]quinazolin-5(1H)-ylidenemethyl)but-2-enedioates 15, 16. Imidazo[2,1-b]quinazoline 2 was further treated with acetyl chloride, benzoyl chloride and mesyl chloride to give the 1-substituted derivatives 17, 18 and 19, respectively. The structures of all new compounds obtained were confirmed by elemental analysis and spectral data (IR, (1)H- and (13)C-NMR) as well asX-ray crystallographic analysis of 3 and 18. 相似文献
6.
Frontera A Saczewski F Gdaniec M Dziemidowicz-Borys E Kurland A Deyà PM Quiñonero D Garau C 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(22):6560-6567
Several structures of pi complexes of isocyanuric acid and of several thio derivatives with anions have been computed by using high level ab initio calculations. The nature of the complexes has been studied by means of the method of molecular interaction potential with polarization (MIPp) and Bader's theory of atoms-in-molecules. These molecules form favorable complexes with anions and can be used as binding units for building receptors for the molecular recognition of anions. In several cases, the anion-pi interaction has been demonstrated experimentally by means of X-ray crystallography. 相似文献
7.
ukasz Balewski Franciszek Sczewski Patrick J. Bednarski Lisa Wolff Anna Nadworska Maria Gdaniec Anita Kornicka 《Molecules (Basel, Switzerland)》2020,25(24)
The appropriate 1-arylhydrazinecarbonitriles 1a–c are subjected to the reaction with 2-chloro-4,5-dihydro-1H-imidazole (2), yielding 7-(4,5-dihydro-1H-imidazol-2-yl)-2-aryl-6,7-dihydro-2H-imidazo[2,1-c][1,2,4]triazol-3(5H)-imines 3a–c, which are subsequently converted into the corresponding amides 4a–e, 8a–c, sulfonamides 5a–n, 9, ureas 6a–I, and thioureas 7a–d. The structures of the newly prepared derivatives 3a–c, 4a–e, 5a–n, 6a–i, 7a–d, 8a–c, and 9 are confirmed by IR, NMR spectroscopic data, as well as single-crystal X-ray analyses of 5e and 8c. The in vitro cytotoxic potency of these compounds is determined on a panel of human cancer cell lines, and the relationships between structure and antitumor activity are discussed. The most active 4-chloro-N-(2-(4-chlorophenyl)-7-(4,5-dihydro-1H-imidazol-2-yl)-6,7-dihydro-2H-imidazo[2,1-c][1,2,4]triazol-3(5H)-ylidene)benzamide (4e) and N-(7-(4,5-dihydro-1H-imidazol-2-yl)-2-(p-tolyl)-6,7-dihydro-2H-imidazo[2,1-c][1,2,4]triazol-3(5H)-ylidene)-[1,1′-biphenyl]-4-sulfonamide (5l) inhibits the growth of the cervical cancer SISO and bladder cancer RT-112 cell lines with IC50 values in the range of 2.38–3.77 μM. Moreover, N-(7-(4,5-dihydro-1H-imidazol-2-yl)-2-phenyl-6,7-dihydro-2H-imidazo[2,1-c][1,2,4]triazol-3(5H)-ylidene)-4-phenoxybenzenesulfonamide (5m) has the best selectivity towards the SISO cell line and induces apoptosis in this cell line. 相似文献
8.
Franciszek Feret 《Spectrochimica Acta Part B: Atomic Spectroscopy》1982,37(4):349-357
A number of iron ores from all parts of the world were analysed with a powder sample preparation technique. Calibration curves were plotted for Fe, Ca, Si, Al and Mg in wide concentration ranges using 32 international and a few local standards. All iron ores were divided into 5 groups related to mineralogical differences; however, the calibration curve for Ca is common for all samples. For hematites and magnetites the relationship FeO + Fe2O3 = f(Fe) was experimentally established. The total time for sample preparation and analysis is about 5 min. A good correlation of chemical and X-ray results was obtained in this routine work. 相似文献
9.
Franciszek Hugon Szafraniec 《Reports on Mathematical Physics》2004,53(3):393-400
The classical Hamiltonian ) of the very classical quantum harmonic oscillator, which is regarded as a germ of the most of what comes about in quantum mechanics, can be sublimed to an abstract operator in a separable Hilbert space. Having this done one may ask for a condition which would allow it to be identified among operators of a suitable class. This class is that corresponding to three diagonal matrices and the property which makes the action successful is a kind of diagonal invariance (up to change of basis) within the class in question. 相似文献
10.
Franciszek Hugon Szafraniec 《Numerical Algorithms》2003,33(1-4):475-483
We discuss a possibility of deciding whether measures representing a moment sequence or realizing orthogonality of polynomials have atoms. This is done on the real line and in several variables. 相似文献