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1.
2.
Alberto Mariani Simone Bidali Stefano Fiori Marco Sangermano Giulio Malucelli Roberta Bongiovanni Aldo Priola 《Journal of polymer science. Part A, Polymer chemistry》2004,42(9):2066-2072
By combining frontal polymerization and radical‐induced cationic polymerization, it was possible to cure thick samples of an epoxy monomer bleached by UV light. The effect of the relative amounts of cationic photoinitiator and radical initiator was thoroughly investigated and was related to the front's velocity and its maximum temperature. The materials obtained were characterized by quantitative conversion also in the deeper layers, not reached by UV light. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2066–2072, 2004 相似文献
3.
The concept of strong interactions need not be limited to the sector of physics taken by QCD. While this domain is investigated by RHIC, LHC will be able to probe potential new strong interactions simultaneously: Finding the precise mechanism for electroweak symmetry breaking is one of the prime problems of physics. Intricately linked to this point is the question after the true nature or even the existence of the Higgs boson. Here, we present stronly interacting theories providing an explanation for the hierarchy problem and leading to a light composite Higgs boson, favoured by experimental data. Our variation of the standard model is consistent with precision data. We achieve this accordance by using technifermions in a higher representation of their gauge group. Anomaly conditions require at least one extra lepton family for some of the theories whereby they contain a natural dark matter candidate. We can accurately determine the masses of said leptons from experimental data. 相似文献
4.
CuPc molecules adsorbed on Au(1 1 0)-(1 × 2): growth morphology and evolution of valence band states
Fabrizio Evangelista A. RuoccoValdis Corradini M.P. DonzelloCarlo Mariani Maria Grazia Betti 《Surface science》2003,531(2):123-130
We present the growth morphology, the long-range ordering, and the evolution of the valence band electronic states of ultrathin films of copper phthalocyanine (CuPc) deposited on the Au(1 1 0)-(1 × 2) reconstructed surface, as a function of the organic molecule coverage. The low energy electron diffraction patterns present a (5 × 3) reconstruction from the early adsorption stages. High-resolution UV photoelectron spectroscopy data show the disappearance of the Au surface states related to the (1 × 2) reconstruction, and the presence of new electronic features related to the molecule-substrate interaction and to the CuPc molecular states. The CuPc highest occupied molecular orbital gradually emerges in the valence band, while the interface electronic states are quenched, upon increasing the coverage. 相似文献
5.
Franca M. Cordero Francesco De Sarlo Alberto Brandi 《Monatshefte für Chemie / Chemical Monthly》2004,40(2):649-669
The review outlines the various different azaheterocycles available from 5-spirocyclopropane isoxazolidines. These compounds can be regarded as versatile direct precursors of tetrahydro-, dihydropyridone and azetidinone derivatives. The current scope and limitations, and the selectivity aspects of the different processes are discussed therein. 相似文献
6.
A new microwave dielectric method for studying photoinitiated chain radical polymerization processes
Carlo Carlini Francesco Ciardelli Pier Angelo Rolla Elpidio Tombari 《Journal of Polymer Science.Polymer Physics》1987,25(6):1253-1261
Measurements of both real and imaginary parts of the dielectric constant at a fixed microwave frequency have been performed on n-butyl acrylate/poly(n-butyl acrylate) mixtures. The dielectric constant of the mixtures has been compared with that of neat n-butyl acrylate during UV photoinitiated polymerization. The values of the imaginary part of the dielectric constant thus obtained have allowed determination of the instantaneous monomer concentration and verified the kinetic equation for the photoinitiated polymerization process. The limits of validity of the method as well as its capability of providing detailed kinetic information are also discussed. 相似文献
7.
Francesco Catoni Roberto Cannata Paolo Zampetti 《Advances in Applied Clifford Algebras》2006,16(2):85-101
It is known that complex numbers can be associated with plane Euclidean geometry and their functions are successfully used
for studying extensions of Euclidean geometry, i.e., non-Euclidean geometries and surfaces differential geometry.
In this paper we begin to study the constant curvature spaces associated with the geometry generated by commutative elliptic-quaternions
and we show how the “mathematics” they generate allows us to introduce these spaces and obtain the geodesic equations without
developing a complete mathematical apparatus as the one developed for Riemannian geometry. 相似文献
8.
9.
Nicola Fusco Michele Gori Francesco Maggi 《NoDEA : Nonlinear Differential Equations and Applications》2006,13(4):425-433
An approximation theorem for families of weakly coercive convex functions by means of countably many smooth families of convex
functions is proved. As a consequence, the classical “three-fold” lower semicontinuity theorem for integral functionals of
the Calculus of Variations by James Serrin is unified in one single statement. 相似文献
10.
We have investigated the distribution of conformations and orientations for a simple internal rotor molecule, 2,2'-bithienyl dissolved in liquid crystal solvents, by re-analysing published proton dipolar coupling data with the maximum entropy internal order method (MEIO). We show that detailed, model independent, conformational information can be obtained when data of sufficiently high quality are available. We also propose a novel and convenient representation method for the orientational-conformational coupling. 相似文献