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排序方式: 共有1124条查询结果,搜索用时 15 毫秒
1.
Marius Lupu Adnana Zaulet Prof. Dr. Francesc Teixidor Prof. Dr. Eliseo Ruiz Prof. Dr. Clara Viñas 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(18):6888-6897
The metallacarborane [3,3′‐Co(1,2‐closo‐C2B9H11)2]? has been synthesized. This species allows the formation of redox couples in which both partners are negatively charged. The E1/2 potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3′‐Co(1,2‐closo‐C2B9H7I4)2]? is the most favorable, as it is isolatable and stable in air. A DFT study on stability and redox potentials of complexes has been performed. 相似文献
2.
3.
Francesc Carreras M. Dolors Llongueras Antonio Magaña 《Annals of Operations Research》2005,137(1):67-89
A partnership in a cooperative game is a coalition that possesses an internal structure and, simultaneously, behaves as an
individual member. Forming partnerships leads to a modification of the original game which differs from the quotient game
that arises when one or more coalitions are actually formed.
In this paper, the Shapley value is used to discuss the convenience to form either coalitions or partnerships. To this end,
the difference between the additive Shapley value of the partnership in the partnership game and the Shapley alliance value
of the coalition, and also between the corresponding value of the internal and external players, are analysed. Simple games
are especially considered.
Research partially supported by Grant BFM 2003-01314 of the Science and Technology Spanish Ministry and the European Regional
Development Fund. 相似文献
4.
The derivative expansion of the effective action is a perturbative development in derivatives of the fields. The expansion breaks down when some of the derivatives are too large. We show how to sum exactly the first and second derivatives and treat perturbatively derivatives higher than second. 相似文献
5.
Theoretical models for Monte Carlo simulation of radiative processes, i.e. bremsstrahlung and characteristic x-ray emission, are presented. Possible strategies for simulating electron transport are briefly described. For mechanisms involving energy loss and angular deflections, difficulties for strict implementation of accurate numerical differential cross sections still remain due to the strong correlations between these variables. Practical solutions for the case of inelastic collisions and bremsstrahlung emission are described. Comparisons of simulation results with experimental data for several problems of interest in electron probe microanalysis are presented. 相似文献
6.
Antonio Domnech Hermenegildo Garca Mara Teresa Domnech-Carb Francesc Llabrs-i-Xamena 《Electrochemistry communications》2006,8(12):1830-1834
Electrodeposition of copper from Cu/MOF immersed into acetate buffer produces a quasi-periodic series of 10–20 nm sized laminae sandwiched within the pristine MOF lattice as monitored by voltammetry of microparticles/atomic force microscopy. This anisotropic patterning can be qualitatively described in terms of a highly orientation-dependent diffusion of electrons and charge-balancing electrolyte counterions in the MOF network. 相似文献
7.
Olga Ordeig Craig E Banks Trevor J Davies F Javier del Campo Francesc Xavier Mu?oz Richard G Compton 《Analytical sciences》2006,22(5):679-683
Gold ultra-microelectrode arrays are used to explore the electrochemical oxidation of hydroxide ions and are shown to be analytical useful. Two types of ultra-microelectrode arrays are used; the first consist of 256 individual electrodes of 5 microm in radius, 170 of which are electrochemically active in a cubic arrangement which are separated from their nearest neighbour by a distance of 100 microm. The second array compromises 2597 electrodes of 2.5 microm in radius and of which 1550 of which are electrochemically active in a hexagonal arrangement separated by the nearest neighbour by 55 microm. Well defined voltammetric waves are found with peak currents proportional to the concentration of hydroxide ions in the range 50 microM to 1 mM. Detection limits of 20 microM using the 170 ultra-microelectrode and 10 microM with the 1550 ultra-microelectrode array are shown to be possible but with a higher sensitivity of 4 mA M(-1) observed using the 1550 ultra-microelectrode array compared to 1.2 mA M(-1) with the 170 ultra-microelectrode array. 相似文献
8.
We prove the vanishing of the Koszul homology group H
μ(Kos(M)μ), where μ is the minimal number of generators of M. We give a counterexample that the Koszul complex of a module is not always
acyclic and show its relationship with the homology of commutative rings. 相似文献
9.
B. Freisinger U. Kogelschatz J. H. Schäfer J. Uhlenbusch W. Viöl 《Applied physics. B, Lasers and optics》1989,49(2):121-129
Ozone is generated in pure oxygen (p5 kPa), synthetic air (p7 kPa) and oxygen-argon mixtures (p3 kPa) by irradiation of these gases with the VUV light of a repetitively pulsed (f
L15 Hz) F2-laser at =157.6 nm with maximum about 4 mJ/pulse. An absorption photometer measurement operating at 253.7 nm (Hg line) determines the ozone concentration as a function of oxygen and/or additive gas pressure, the repetition frequency of the laser and the wall temperature of the reaction chamber. The temporal development of the ozone concentration as a function of these parameters is calculated by means of rate equations for the species O(3
P), O2(X
3
g
–
), O3(1
A
1), O(1
D), O2(a
1g), O2(b
1
g
+
) and vibrationally excited O
3
*
(1
A
1) and the photon distribution. The maximum concentration of O3 in the sealed-off chamber reaches 1.6% in pure O2, 4.1% in air and 1.2% in a 1:5 O2-Ar mixture at 3 kPa. The annihilation of O3 by the wall and temperature dependent volume processes (300 KT395 K) is studied and the experimental and theoretical results are compared. 相似文献
10.
CuAl2O4, NiAl2O4, and three ternary spinels CuxNi1?xAl2O3 have been prepared, in polycrystalline form, by solid-state reaction of mixtures of CuO, NiO, and Al2O3 at 1223 K. X-Ray powder diffractometry, coupled with adequate computational methods, allowed determination of the unit-cell length, oxygen positional parameter, and cation distribution for each compound. Interdependence of these structural parameters is closely analyzed on the ternary oxide spinels. The one-electron difference between the Cu2+ and Ni2+ ions was found to be enough to render them distinguishable by X-ray powder diffraction. 相似文献