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J. -L. Fortier P. -A. Leduc P. Picker J. E. Desnoyers 《Journal of solution chemistry》1973,2(5):467-475
The enthalpies of dilution of NaCl, Me4NBr, andn-Bu4NBr were measured in water at 25°C with a new flow microcalorimeter. The data were analyzed with a polynomial equation, and the derived relative apparent molal enthalpies L are in good agreement with literature values. Provided care is taken that mixing is complete, flow calorimeters are as reliable and much less time-consuming than cell-type instruments for enthalpies of dilution measurements. 相似文献
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A quick, reliable method for the determination of Al(III) in the presence of other metal ions is presented. A Chromatographic system consisting of a low-capacity cation-exchange column, an eluent of diprotonated p-phenylenediamine, and a conductivity detector was used to measure the retention times for various cations. During the course of this work, it was found that Al(III) was eluted later than most bivalent metal ions but earlier than other tervalent metal ions. Therefore the concentration of eluent was adjusted so that an early sharp peak was obtained for Al(III) and the bivalent metal ions were eluted as a group. Through analysis of an NBS standard, as well as of solutions containing Al(III) and other metal ions, the method was shown to be precise, accurate and rapid for determination of Al(III) without interference from common bivalent metal ions. 相似文献
4.
Volumetric heat capacities of the six binary mixtures formed from cyclopentane, cyclohexane, cycloheptane and cyclooctane were determined at 298.15 K in a Picker flow microcalorimeter. Excess heat capacities obtained from the results are compred with the temperature variation of excess enthalpies from the literature. 相似文献
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A simple equation has been derived relating the temperature dependence of activity functions with excess enthalpies and excess heat capacities. Using experimentally determined parameters at 298.15°K, it is possible to predict osmotic coefficients and mean activity coefficients of alkali halides in water up to 1 m from 273°K to about 350°K. In general, the predicted functions agree with the measured values within the uncertainty of the activity data. An equation is also given for the pressure dependence of the excess free energies, but it was not possible to check the limitation of this equation due to lack of activity data at various pressures.To whom correspondence should be addressed. 相似文献
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The carrier-envelope phase of the pulse train emitted by a 10-fs mode-locked laser has been stabilized such that carrier-envelope phase coherence is maintained for at least 150 s (measurement limited). The phase coherence time was measured independently of the feedback loop. 相似文献
8.
The (τ, α) reaction on 48Ca, 50Ti, 52Cr and 54Fe target nuclei has been studied at 25 MeV incident energy. Angular distributions have been measured from 5° to 40° with a split-pole spectrometer in a large range of excitation energy. A local zero-range DWBA analysis has been carried out, using an isospin-dependent potential for the calculation of the neutron form factor, in order to get a coherent set of spectroscopic factors for both T> and T< levels in different nuclei. Assignments of l-values have been done for a large number of levels, most of them previously unknown, and energy centroids of hole states have been determined. Spectroscopic factors in 39Ca, 47Ti, 49, 52, 53Cr have also been obtained for strongly excited states. A sum rule analysis has been carried out for the N = 27 nuclei: the hole strengths are generally fully exhausted by the observed levels, whereas only a fraction of the strength has been evidenced. The analog states have been observed in all nuclei; in 53Fe, the analog states appear to be split in several components. In addition, a CRC analysis has been carried out for some levels with angular distributions not accounted for by a direct pick-up process. These levels are tentatively identified with states resulting from the coupling of one neutron hole with excited states of the target nucleus. In particular, the members of the configuration have been identified in each final nucleus. Unambiguous Jπ assignments are made; and the two-step (τ, α) reaction therefo e appears as a useful spectroscopic tool, especially for investigating high spin states. 相似文献
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Binamé J Meurice N Leherte L Glasgow J Fortier S Vercauteren DP 《Journal of chemical information and computer sciences》2004,44(4):1394-1401
In this paper, we propose a reduced representation of molecules of pharmacological interest based on their chemical functions. The proposed representations of the molecules are obtained by a topological analysis of their electron density maps at medium resolution, leading to graphs of critical points. The distribution of the different types of critical points are compared at various levels of resolution for a training set of 22 molecules in order to define the optimal resolution level leading to the best representation of the various chemical functions. The reduced representations can in the future be used for molecular similarity research and pharmacophore proposals. 相似文献
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