全文获取类型
收费全文 | 265篇 |
免费 | 14篇 |
国内免费 | 1篇 |
专业分类
化学 | 171篇 |
晶体学 | 3篇 |
力学 | 11篇 |
综合类 | 1篇 |
数学 | 41篇 |
物理学 | 53篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 8篇 |
2020年 | 12篇 |
2019年 | 10篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 12篇 |
2015年 | 9篇 |
2014年 | 14篇 |
2013年 | 16篇 |
2012年 | 21篇 |
2011年 | 22篇 |
2010年 | 13篇 |
2009年 | 21篇 |
2008年 | 19篇 |
2007年 | 12篇 |
2006年 | 10篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 9篇 |
2002年 | 9篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有280条查询结果,搜索用时 46 毫秒
1.
本文研究了全部根构成一个等比数列的多项式的性质,并将所得的结果用到数值积分的Romberg方法^「1」,得到了相应遥改进。 相似文献
2.
Ata N. Al-Hussaini 《Applied Mathematics and Optimization》1989,20(1):63-69
A simple proof is given for the stochastic integral representation of a Fréchet differentiable functional of the paths of a given diffusion process. The proof begins when the functional depends on one coordinate, then passes to (by appropriate conditioning) a perhaps more difficult case—when the functional depends on a finite number of coordinates—and finally, by approximation, to the general case. 相似文献
3.
4.
5.
Atta-ur-Rahman Nasim S Baig I Sener B Orhan I Ayanoglu F Choudhary MI 《Natural product research》2004,18(5):465-471
Two new isoflavones 1 and 2 along with eleven known compounds 3-13, have been isolated for the first time from the rhizomes of Iris soforana. The structures of these compounds were determined on the basis of spectroscopic methods and found to be 5,3'-dihydroxy-4'-methoxy-6,7-methylenedioxyisoflavone (1) (Soforanarin A), and 5,7,5'-trimethoxy-6,3',4'-trihydroxyisoflavone (2) (Soforanarin B). 相似文献
6.
Leyla Bitiş Sevda Süzgeç Ulaş Sözer Hasan Özçelik Josef Zapp Alexandra K. Kiemer Filiz Meriçli Ali H. Meriçli 《Helvetica chimica acta》2007,90(11):2217-2221
From the aerial parts of Delphinium buschianum Grossh ., collected in Turkey, a new diterpenoid alkaloid 1 , named budelphine, was isolated along with the known diterpenoid alkaloids karakoline ( 2 ), 18‐hydroxy‐14‐O‐methylgadesine ( 3 ), delsoline ( 4 ), lapaconidine ( 5 ), columbianine ( 6 ), 14‐benzoylneoline ( 7 ), and hetisine ( 9 ). The structure of 1 was established on the basis of 1H‐, 13C‐, DEPT, 1H,1H‐COSY, NOESY, HSQC, and HMBC NMR studies. 相似文献
7.
8.
9.
Fanny Danton Dr. Mohamed Othman Dr. Ata Martin Lawson Dr. Ján Moncol Dr. Alina Ghinet Prof. Benoît Rigo Prof. Adam Daïch 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(24):6113-6118
An efficient domino transformation using a phenyliodine(III) diacetate (PIDA)/I2 combination towards Morin 1,4-thiazine compounds has been developed starting from N,S-acetals. The latter leads to “one-step” regioselective methylene insertion without the need for traditional sulfoxide intermediates in good yields. The reaction involves easily accessible N,S-acetals obtained from cost-effective basic ketones and cysteamine as starting materials. This process ultimately leads to 1,4-thiazines related to natural product and fused derivatives necessary for further QSAR study. 相似文献
10.
Fernando Castañeda Paul Silva M. Teresa Garland Ata Shirazi Clifford A. Bunton 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8):2152-2168
The phosphonium ylidic diesters, methyl and ethyl isopropyl and, methyl and ethyl t-butyl triphenylphosphoranylidene malonates, 1a,b and 2a,b , respectively, have the syn-anti conformation in solution, as in the crystal, and the bulkier alkoxy group is oriented towards phosphorus. The 1 H NMR spectra show that in 1a,b , the isopropyl group is oriented towards the face of a phenyl group, consistent with π shielding in the 1 H signals, and examination of the 1 H coupled 13 C NMR spectra allows assignment of the acyl carbon signals. Computed bond lengths and angles for isolated molecules are similar to those in the crystal, and the geometry and the NMR spectra indicate extensive ylidic resonance. Estimated partial atomic charges on the ester oxygens are more negative when they are oriented towards, rather than away from, phosphorus. 相似文献