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1.
E. S. Filatov S. V. Sysoev Ludmila N. Zelenina Tamara P. Chusova V. A. Logvinenko P. P. Semyannikov I. K. Igumenov 《Journal of Thermal Analysis and Calorimetry》2006,86(2):537-539
Thermal behaviour
of a series of lithium β-diketonates: Li(dpm) (dpm=dipivaloylmethanate
(2,2,6,6-tetramethylheptane-3,5- dionate)), Li(pta) (pta=pivaloyltrifluoracetonate
(2,2-dimethyl-6,6,6-trifluoro-3,5-hexanedionate)), Li(tfa) (tfa=trifluoracetylacetonate
(1,1,1-trifluoro-2,4-pentandionate)), Li(hfa) (hfa=hexafluoracetylacetonate
(1,1,1,5,5,5-hexafluoro-2,4-pentandionate)) has been investigated. Gas phase
composition of these complexes has been established. Temperature dependences
of vapor pressure of lithium compounds were obtained by static and dynamic
methods, and thermodynamic parameters were calculated. Dependence of compound
volatility on ligand structure is shown. For Li(dpm) detailed investigation
has been done by differential scanning calorimetry (DSC). 相似文献
2.
3.
Ginzburg B. M. Smirnov A. S. Filatov S. K. Shibaev L. A. Melenevskaya E. Yu. Novoselova A. V. Shepelevskii A. A. 《Russian Journal of Applied Chemistry》2003,76(3):457-459
The structure of aggregates of fullerene C6
0 introduced into films of radical polymethyl methacrylate in the stage of solution preparation was studied by wide-angle X-ray diffraction. 相似文献
4.
5.
K. Dzilinski G. N. Synyakov A. M. Shulga I. V. Filatov G. P. Gurinovich 《Radiation Physics and Chemistry》1995,45(6):923-928
Radical anions of Zn-chlorin, Zn-octaethylchlorin complexes and their 15N and deuterium substituted analogues have been studied by EPR spectroscopy and the INDO molecular orbital method in the unrestricted Hartree-Fock procedure. Parameters of experimental spectra, determined by using the iterative least-squares fitting method, have been compared with those calculated on the basis of spin density distribution. A satisfactory agreement between the experimental hyperfine coupling constants and theoretical ones for the systems studied has been obtained. 相似文献
6.
Two electromeric forms, a and b (a is the ground state in a solvent) exist for the hydroxo-iron complex 1, an intermediate in the rebound mechanism of alkane hydroxylation by cytochrome P450. Results of density functional and model solvent calculations of various species are in agreement with experimental findings, and imply the role of 1 a in the rebound mechanism. 相似文献
7.
I. E. Filatov G. L. Rusinov O. N. Chupakhin X. Solans M. Font-Bardia M. Font-Altaba 《Russian Chemical Bulletin》1994,43(7):1214-1219
The reaction of 2-chloro-3,5-dinitropyridine with two equivalents of KN3 in the presence of ROH results in stable Meisenheimer-type -adducts of 4,6-dinitrotetra-zolo[1,5-a]pyridine with RO– anions (R = H, Alk, Ph). The mechanism of -complex formation was suggested. The structure of the -adduct with R = Me was established by IR and NMR spectroscopy and by X-ray diffraction analysis.For the preliminary communication, see Ref. 1.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1278–1283, July, 1994.This work was supported by the Russian Foundation for Basic Research (project code 93-03-5329). 相似文献
8.
O. P. Filatov 《Mathematical Notes》1996,59(5):547-553
It is proved that the limit $$\mathop {\lim }\limits_{\Delta \to \infty } \mathop {\sup }\limits_\gamma \tfrac{1}{\Delta }\int_0^\Delta {f(\gamma (t))dt} $$ , wheref: ? → ? is a locally integrable (in the sense of Lebesgue) function with zero mean and the supremum is taken over all solutions of the generalized differential equation γ ∈ [ω1, ω2], coincides with the limit $$\mathop {\lim }\limits_{T \to \infty } \mathop {\sup }\limits_{c \geqslant 0} \varphi _f (k,{\mathbf{ }}T,{\mathbf{ }}c)$$ , where $$\varphi _f = \frac{{(k - 1)\bar I_f (T,c)}}{{1 + (k - 1)\bar \lambda _f (T,c)}},k = \frac{{\omega _2 }}{{\omega _1 }}$$ . Here ¯λf = λf /T, ¯ If =If/T, and λf is the Lebesgue measure of the set $$\{ \gamma \in [\gamma _0 ,\gamma _0 + T]:f(\gamma ) \geqslant c\} = A_f ,I_f = \int_{A_f } {f(\gamma )d\gamma } $$ . It is established that this limit always exists for almost-periodic functionsf. 相似文献
9.
T. A. Kravchenko V. A. Krysanov A. S. Stolpovskii G. A. Filatov E. V. Zolotukhina A. A. Zagorodnii 《Russian Journal of Electrochemistry》2006,42(3):233-238
The average size of copper particles in copper-containing electron-ion exchangers is determined with the aid of microscopy and x-ray diffractometry. The results are used to calculate the contribution made by a dimensional factor to the electrode potential. Compared to the potential of compact copper, the potential shift in the negative direction measured experimentally falls within the region of calculated values. The average size of copper particles remains practically unchanged after contact with a copper sulfate solution, testifying to stabilization of an ultradisperse state of copper particles by a polymer matrix. 相似文献
10.
The limits of isomorphous substitutions and the symmetry of synthetic binary solid solutions of paraffins CnH2n+2 with n=17–24 have been studied by X-ray diffraction and thermal X-ray diffraction. Principles of isomorphous substitutions of paraffin molecules are suggested which take into consideration the length (n), the symmetry (parity of n), and the intensity of thermal rotational motion of component molecules.St. Petersburg State University. Translated fromZhurnal Strukturnoi Khimii Vol. 34, No. 4, pp. 117–127, July–August, 1993.Translated by T. Yudanova 相似文献