全文获取类型
收费全文 | 430篇 |
免费 | 11篇 |
国内免费 | 1篇 |
专业分类
化学 | 296篇 |
晶体学 | 3篇 |
力学 | 31篇 |
数学 | 79篇 |
物理学 | 33篇 |
出版年
2021年 | 3篇 |
2020年 | 3篇 |
2016年 | 8篇 |
2015年 | 5篇 |
2014年 | 6篇 |
2013年 | 18篇 |
2012年 | 20篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 8篇 |
2008年 | 27篇 |
2007年 | 17篇 |
2006年 | 17篇 |
2005年 | 25篇 |
2004年 | 29篇 |
2003年 | 9篇 |
2002年 | 12篇 |
2001年 | 10篇 |
2000年 | 13篇 |
1999年 | 4篇 |
1998年 | 9篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 9篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 8篇 |
1991年 | 3篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1978年 | 3篇 |
1977年 | 7篇 |
1974年 | 3篇 |
1973年 | 8篇 |
1972年 | 5篇 |
1970年 | 2篇 |
1967年 | 4篇 |
1966年 | 2篇 |
1964年 | 2篇 |
1963年 | 3篇 |
1940年 | 3篇 |
1939年 | 2篇 |
1938年 | 2篇 |
排序方式: 共有442条查询结果,搜索用时 46 毫秒
1.
2.
3.
The exchange-correlation self-energies and quasiparticle shifts are calculated for band states of covalent materials (diamond, silicon) and their (001) 2×1 surface in order to solve the bulk and surface band-gap problem of the LDA. The screening properties are described by a model dielectric function taking into account the spatial nonlocality in the surface case assuming specular electron reflection. The wave functions are expanded in terms of localized orbitals. The quasiparticle bandstructures obtained are in reasonable agreement with experimental results. 相似文献
4.
H. Fiedler 《Numerische Mathematik》1987,51(5):571-581
Summary Interpolatory quadrature formulae consist in replacing
by
wherep
f
denotes the interpolating polynomial off with respect to a certain knot setX. The remainder
may in many cases be written as
wherem=n resp. (n+1) forn even and odd, respectively. We determine the asymptotic behaviour of the Peano kernelP
X
(t) forn for the quadrature formulae of Filippi, Polya and Clenshaw-Curtis. 相似文献
5.
[reaction: see text] A resin-based chromium catalyst for performing [6pi + 2pi] cycloaddition reactions has been prepared from chloromethylated polystyrene. The catalyst provides cycloadducts in yields comparable to the photochemical and thermal versions of these transformations, and the process is effective with a wide range of 6pi and 2pi reaction partners. 相似文献
6.
A rapid and specific ion-pair reversed-phase high-performance liquid chromatographic method was developed for the determination of bleomycins. The use of 5-microns particles of less adsorptive reversed-phase packings and sodium perchlorate as ion-pairing reagent permitted a short analysis time and the transferability of the separations on different batches of the reversed-phase materials. The detection sensitivity and precision of the method demonstrated that the system is suitable for routine analysis. 相似文献
7.
Krzystek J Fiedler AT Sokol JJ Ozarowski A Zvyagin SA Brunold TC Long JR Brunel LC Telser J 《Inorganic chemistry》2004,43(18):5645-5658
A variety of physical methods has been used to probe the non-Kramers, S = 1, V(III) ion in two types of pseudooctahedral complexes: V(acac)(3), where acac = anion of 2,4-pentanedione, and VX(3)(thf)(3), where thf = tetrahydrofuran and X = Cl and Br. These methods include tunable frequency and high-field electron paramagnetic resonance (HFEPR) spectroscopy (using frequencies of approximately 95-700 GHz and fields up to 25 T) in conjunction with electronic absorption, magnetic circular dichroism (MCD), and variable-temperature variable-field MCD (VTVH-MCD) spectroscopies. Variable-temperature magnetic susceptibility and field-dependent magnetization measurements were also performed. All measurements were conducted on complexes in the solid state (powder or mull samples). The field versus sub-THz wave quantum energy dependence of observed HFEPR resonances yielded the following spin Hamiltonian parameters for V(acac)(3): D = +7.470(1) cm(-1); E = +1.916(1) cm(-1); g(x) = 1.833(4); g(y) = 1.72(2); g(z) = 2.03(2). For VCl(3)(thf)(3), HFEPR detected a single zero-field transition at 15.8 cm(-1) (474 GHz), which was insufficient to determine the complete set of spin Hamiltonian parameters. For VBr(3)(thf)(3), however, a particularly rich data set was obtained using tunable-frequency HFEPR, and analysis of this data set gave the folowing: D = -16.162(6) cm(-1); E = -3.694(4) cm(-1); g(x) = 1.86(1); g(y) = 1.90(1); g(z) = 1.710(4). Analysis of the VTVH-MCD data gave spin Hamiltonian parameters in good agreement with those determined by HFEPR for both V(acac)(3) and VBr(3)(thf)(3) and in rough agreement with the estimate for VCl(3)(thf)(3) (D approximately 10 cm(-1), |E/D| approximately 0.18), together with the finding that the value of D is negative for both thf complexes. The electronic structures of these V(III) complexes are discussed in terms of their molecular structures and the electronic transitions observed by electronic absorption and MCD spectroscopies. 相似文献
8.
A design of a combined ozone/electron beam irradiation process for treating a 50 m3/h waste water stream from a molasses processing is discussed. Moreover, a cost evaluation of such a process in comparison to a conventional ozonation/biology treatment process has been performed to assess the potential of the irradiation process for technical use. Although the result of this comparison is not bad for the irradiation process an implementation into a full scale plant would not seem to be the thing to do in the present case. 相似文献
9.
The equilibrium constants and molar absorptivities for the fast formation of a 1:3 complex between cadmium(II) (Cd(II)) and dithizonate anion, in the presence of cationic and non-ionic surfactants, allowed a simple and fast spectrophotometric determination of total cadmium. Indeed, the molar absorptivities of the Cd(II)-dithizone (Dz) complex formed in the presence of the neutral Triton X-100 and cationic cetyltrimethylammonium bromide (CTAB) surfactants are almost twice the value observed in the standard method and the maxima of absorption are shifted by about 40 nm when compared with the standard method. Clearly, the use of neutral and cationic surfactants promotes a higher value of the molar absorptivities of the complex, resulting in an increase in the sensitivity of the method. Application of the method to the desorption of Cd(II) ions from clays is illustrated. 相似文献
10.
Philippe Quevauviller Gemma Rauret Allan Ure Roser Rubio José-Fírmin López-Sánchez Haidé Fiedler Herbert Muntau 《Mikrochimica acta》1995,120(1-4):289-300
The determination of extractable trace metal contents in soil using single extraction procedures is currently performed in many laboratories to assess the bioavailable metal fraction (and related phytotoxic effects) and the accessability to the environment (e.g. contamination of ground waters). Owing to the need for validation of the extraction schemes used and of the analytical techniques, the EC Measurements and Testing Programme (formerly BCR) has organized a project for improving the quality of determination of extractable trace metal contents in soil, the first step being an interlaboratory study to adopt common extraction procedures and the second being a certification campaign to certify two soils for their extractable trace element contents following these procedures. This paper gives a brief overview of the project organisation and describes the preparation, homogeneity and stability studies of two soil candidate reference materials (sewage sludge-amended and terra rossa soils). 相似文献