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1.
Danilov Felix I. Bogdanov Dmytro A. Smyrnova Olena V. Korniy Sergiy A. Protsenko Vyacheslav S. 《Journal of Solid State Electrochemistry》2022,26(4):939-957
Journal of Solid State Electrochemistry - The electrochemical deposition of a nickel–iron alloy from a plating solution based on a deep eutectic solvent (a eutectic mixture of ethylene glycol... 相似文献
2.
Herein, we report an addition to the toolbox for the monitoring and quantification of the hydrolytic decay of pentose-1-phosphates, which are known to be elusive and difficult to quantify. This communication describes how apparent equilibrium shifts of a nucleoside phosphorolysis reaction can be employed to calculate hydrolytic loss of pentose-1-phosphates based on the measurement of post-hydrolysis equilibrium concentrations of a nucleoside and a nucleobase. To demonstrate this approach, we assessed the stability of the relatively stable ribose-1-phosphate at 98 °C and found half-lives of 1.8–11.7 h depending on the medium pH. This approach can be extended to other sugar phosphates and related reaction systems to quantify the stability of UV-inactive and hard-to-detect reaction products and intermediates. 相似文献
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5.
Pan Huang Dawen Xu Robert M. Reich Felix Kaiser Boping Liu Fritz E. Kühn 《Tetrahedron letters》2019,60(24):1574-1577
A first example of an Et2Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis. 相似文献
6.
Felix Klein 《Mathematische Annalen》1870,2(2):198-226
Ohne Zusammenfassung 相似文献
7.
Oracle inequality is a relatively new statistical tool for the analysis of nonparametric adaptive estimates. Oracle is a good pseudo-estimate that is based on both data and an underlying estimated curve. An oracle inequality shows how well an adaptive estimator mimics the oracle for a particular underlying curve. The most advanced oracle inequalities have been recently obtained by Cavalier and Tsybakov (2001) for Stein type blockwise estimates used in filtering a signal from a stationary white Gaussian process. The authors also conjecture that a similar result can be obtained for Efromovich–Pinsker (EP) type blockwise estimators where their approach, based on Stein's formula for risk calculation, does not work. This article proves the conjecture and extends it upon more general models which include not stationary and dependent processes. Other possible extensions, a discussion of practical implications and a numerical study are also presented. 相似文献
8.
To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007 相似文献
9.
Julie Clutterbuck Oliver C. Schnürer Felix Schulze 《Calculus of Variations and Partial Differential Equations》2007,29(3):281-293
We prove stability of rotationally symmetric translating solutions to mean curvature flow. For initial data that converge
spatially at infinity to such a soliton, we obtain convergence for large times to that soliton without imposing any decay
rates.
The authors are members of SFB 647/B3 “Raum – Zeit – Materie: Singularity Structure, Long-time Behaviour and Dynamics of Solutions
of Non-linear Evolution Equations”. 相似文献
10.
Let X be a 1-connected CW-complex of finite type and ε?(X) be the group of homotopy classes of self-equivalences of X which induce the identity on homotopy groups. In this paper, we prove that every finitely generated 2-solvable rational nilpotent group is realizable as ε?(X) where X is the rationalization of a 1-connected CW-complex of finite type. 相似文献