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1.
Avdic Senada Demirovic Damir Hadzimustafic Edin Cickusic Zerina Sehic Faruk 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2645-2654
Journal of Radioanalytical and Nuclear Chemistry - Responses of the hand-held gamma monitors available for the ambient dose equivalent rate measurements in the Federation of Bosnia and Herzegovina... 相似文献
2.
A bifunctional amido-thiophene namely hexamethylene (bis-3-thiophene acetamide) (HMTA) was synthesized by the reaction of 3-thiophene acetic acid with hexamethylene diamine. Copolymerization in the presence of thiophene was achieved electrochemically in tetrabutylammonium tetrafluoroborate/acetonitrile (TBAFB/AN). Spectroelectrochemical analysis of the resulting copolymer [P(HMTA-co-Th)] reflected electronic transitions at 505 nm, 740 nm and ∼1000 nm, revealing π to π* transition, polaron and bipolaron band formation respectively. Switching ability was evaluated by a kinetic study via measuring the transmittance (%T) at the maximum contrast. Dual type polymer electrochromic devices (ECDs) based on P(HMTA-co-Th) and poly(ethylene dioxythiophene) (PEDOT) have been constructed. Spectroelectrochemistry, switching ability and stability of the devices were investigated by UV-vis spectroscopy and cyclic voltammetry. These devices exhibit low switching voltages (between 0.0 V and +1.6 V), short switching times with reasonable switching stability under atmospheric conditions. 相似文献
3.
(1R,2R)-1,2-bis-(5-amino-1,3,4-thiadiazole-2-yl)ethane-1,2-diol (L) has been prepared by the reaction of thiosemicarbazide with (2R,3R)-(+)-tartaric
acid (I) and phosphorous oxychloride, and its complexes with Co(II), Ni(II) and Cu(II) have been obtained. The structures
of the ligand and its complexes have been established by i. r., 1H- and 13C-n.m.r. spectra, u.v.–vis–nir spectroscopy, elemental analyses, T.g.-D.t.a. and magnetic susceptibility measurements. 相似文献
4.
Regio- and stereoselectivities in cycloadditions of nitrones to dipolarophiles bearing an allylic oxygen, which furnishes substituted-isoxazolidine analogs of the furanose ring of nucleosides, have been investigated. Although the obtained regioselectivities are anticipated, a rationalization of the preferred formation of endo-cycloadducts necessitates the involvement of an allylic oxygen in secondary interaction. The obtained isoxazolidines display cytotoxic activities against a number of human cancer cell lines. 相似文献
5.
New complexes cis-[M(CO)4-DABRd] (M = Cr(I), Mo(II) and fac-[M(CO)3-SAT] (M = Cr(III), Mo(IV)) have been synthesized by the photochemical reactions of cis-[(η4-NBD)M(CO)4] (NBD is norbornadiene; M=Cr, Mo) with 5-(4-dimethylaminobenzylidene) rhodanine (DABRd) and salicylidene-3-amino-1,2,4-triazole
(SAT) ligands and characterized by elemental analysis, FT-IR and 1H NMR spectroscopy, and mass spectrometry. The spectroscopic studies show that the DABRd ligand acts as a bidentate ligand
coordinating via both NH-(S)C=S sulfur donor atoms in I and II and SAT ligand behaves as a tridentate ligand coordinating via its all imine nitrogen-C=N-donor atoms in III and IV to the metal center.
The article was submitted by the authors in English. 相似文献
6.
Sevtap Yildiz Faruk Yilmaz Haluk Özbek Önder Pekcan Koi˙chi˙ Ito 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1573-1588
Random copolymers of poly(ethylene oxide) macromonomer with p‐vinylbenzyl end‐functional group (PEOVB) and liquid crystalline monomer, namely 6‐(4‐cyanobiphenyl‐4′‐oxy)hexyl acrylate (COA), were prepared by conventional free radical polymerization. A living anionic polymerization technique was employed for the synthesis of PEO macromonomers bearing p‐vinylbenzyl moiety at one end. The photon transmission method was also applied to study the phase transitions of COA monomer and its random copolymer with PEO. It was found that, for both samples, the nematic‐smectic A transition is continuous, but the critical fluctuation regions do not allow to obtain 3D XY values. Instead, we have obtained the values close to mean field regime. Scaling of thermal hystersis for random copolymer sample near the nematic‐isotropic transition was studied as well. Thermal hysteresis loops were produced under linearly varying temperature. It was shown that the areas of the hysteresis loops scale with the temperature scanning rate with an exponent being equal to 0.614 which is in good agreement with the field‐theoretical value. 相似文献
7.
Francine F. Nachtigall Eduardo Ernesto Castellano Faruk Nome 《Supramolecular chemistry》2013,25(6):453-458
The interactions of calix[6]arene and p-tert-butylcalix[6]arene with aliphatic amines in acetonitrile solution were studied by spectrophotometric titrations in the UV region and 1H NMR spectrometry. Calix[6]arenes can undergo two deprotonations by aliphatic amines and the extent of the second proton transfer is mainly governed by the size of the α-substituent of the amine. 1H NMR spectra show that the macrocycle adopts a 1,2,3-alternate conformation and that the α-hydrogens of the ammonium ions are shielded by the π-clouds of the aromatic rings. The X-ray crystal structure of the dihexylammonium complex of the p-tert-butylcalix[6]arene dianion, reported here, confirms the 1,2,3-alternate conformation and shows one of the two ammonium moieties encapsulated in the inner cavity of the macrocycle. 相似文献
8.
Emma Drinkel Franciane D. Souza Haidi D. Fiedler Faruk Nome 《Current Opinion in Colloid & Interface Science》2013,18(1):26-34
Zwitterionic surfactants are relatively overlooked and some of their properties resemble those of ionic and non-ionic surfactants, but others are unique. There is unimpeachable evidence that aqueous solutions of zwitterionic micelles interact specifically with anions, forming “anionoid” micelles, which concentrate cations in the surfaces. Thus, unlike ionic micelles, both the cation and anion of the electrolyte solution can be concentrated at zwitterionic interfaces. This unique effect, known as the “Chameleon Effect”, can be used to catalyze a variety of simple reactions, as the attraction of ions to the micelle brings the reactants together. Furthermore, zwitterionic surfactants stabilize metallic nanoparticles and the magnetically stirred two-phase system could be reused 3 more times in the hydrogenation of cyclohexene (Pd:cyclohexene ratio of 1:18300), with very little loss in activity, and an average turn-over frequency of 1000 h? 1. 相似文献
9.
The reactions of 2,2,2-trichloro-1-phenylethanone with various oxygen, carbon and sulfur nucleophiles were investigated with a view of widening the use of trichloroethanones as acylating agents. 相似文献
10.
Ozlem Karahan Duygu Avci Vİktorya Avİyente 《Journal of polymer science. Part A, Polymer chemistry》2011,49(14):3058-3068
A series of alkyl α‐hydroxymethacrylate derivatives with various secondary functionalities (ether, ester, carbonate, and carbamate) and terminal groups (alkyl, cyano, oxetane, cyclic carbonate, phenyl and morpholine) were synthesized to investigate the effect of intermolecular interactions, H‐bonding, π–π interactions, and dipole moment on monomer reactivity. All of the monomers except one ester and one ether derivative are novel. The polymerization rates, determined by using photo‐DSC, showed the average trend (aromatic carbamate > hydroxyl > ester > carbonate ~ aliphatic carbamate ~ ether), with several exceptions due to the differences in terminal groups. There is a correlation between the chemical shift differences of the double bond carbons, the calculated dipole moments, and the reactivities only for nonhydrogen bonded monomers. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献