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1.
Elliot P. Farney Prof. Tehshik P. Yoon 《Angewandte Chemie (International ed. in English)》2014,53(3):793-797
Irradiation of vinyl and aryl azides with visible light in the presence of Ru photocatalysts results in the formation of reactive nitrenes, which can undergo a variety of C? N bond‐forming reactions. The ability to use low‐energy visible light instead of UV in the photochemical activation of azides avoids competitive photodecomposition processes that have long been a significant limitation on the synthetic use of these reactions. 相似文献
2.
Moldovan L Melinte S Bayot V Papadakis SJ De Poortere EP Shayegan M 《Physical review letters》2000,85(20):4369-4372
We report very low temperature ( T) thermopower and resistivity ( rho) measurements on variable-density, two-dimensional hole systems confined to GaAs quantum wells. As the hole density is lowered from 1.49x10(11) cm(-2) to 0.14x10(11) cm(-2), the system crosses from an insulating ( drho / dT less, similar0) to a metallic regime ( drho / dT>0) and finally displays insulating behavior ( drho / dT<0). Diffusion thermopower shows a striking sign reversal in a narrow range of density in the metallic regime, suggesting a qualitative change in the conduction or the scattering mechanism. 相似文献
3.
EP Sheretov VS Gurov MV Dubkov OV Korneeva 《Rapid communications in mass spectrometry : RCM》1999,13(16):1699-1702
In this article we compare the classical monopole mass filter of von Zahn and the monopole mass filter with a hyperbolic V-shaped electrode. The experimental results and those of computer simulation for both mass spectrometers are presented. We show that the replacement of a conventional 90 degrees V-shaped electrode by an electrode with a hyperbolic profile substantially improves the peak shape of any given mass, and increases the mass resolution by a factor of 3-4 and the abundance sensitivity by a factor of 100. The potential of high analytical performance combined with electroforming techniques for electrode manufacture indicate future practical uses of such instruments. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
4.
NL Asfandiarov AI Fokin VG Lukin EP Nafikova GS Lomakin VS Fal'ko YV Chizhov 《Rapid communications in mass spectrometry : RCM》1999,13(12):1116-1123
A series of anthraquinone (C(14)O(2)H(8)) derivatives has been studied by means of electron capture negative ion mass spectrometry (ECNI-MS), photoelectron spectroscopy (PES), and AM1 quantum chemical calculations. Mean lifetimes of molecular negative ions M(-.) (MNI) have been measured. The mechanism of long-lived MNI formation in the epithermal energy region of incident electrons has been investigated. A simple model of a molecule (a spherical potential well with the repulsive centrifugal term) has been applied for the analysis of the energy dependence of cross sections at the first stage of the electron capture process. It has been shown that a temporary resonance of MNI at the energy approximately 0.5 eV corresponds to a shape resonance with lifetime 1-2.10(-13) s in the f-partial wave (l = 3) of the incident electron. The next resonant state of MNI at the energy approximately 1.7 eV has been associated with the electron excited Feshbach resonance (whose parent state is a triplet npi* transition). In all cases the initial electron state of the MNI relaxes into the ground state by means of a radiationless transition, and the final state of the MNI is a nuclear excited resonance with a lifetime measurable on the mass spectrometry timescale. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
5.
We extend the approach of Cai and Widlund (Domain decompositionalgorithms for indefinite elliptic problems, SIAM J. Sci. Stat.Comput. 13 (1992), 243-258), which was designed for finite elementdiscretizations, to boundary element discretizations of indefiniteweakly singular integral equations. Both the h and p versionsof the Galerkin approximation are considered. We prove thatthe additive Schwarz method suggested by Cai and Widlund canbe used for this equation as an efficient preconditioner forGMRES, an iterative method of conjugate gradient type. For bothversions, the rates of convergence of this iterative methodare shown to approach 1 only logarithmically as the degreesof freedom tend to infinity. 相似文献
6.
Spin‐Selective Generation of Triplet Nitrenes: Olefin Aziridination through Visible‐Light Photosensitization of Azidoformates
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Spencer O. Scholz Elliot P. Farney Sangyun Kim Desiree M. Bates Prof. Tehshik P. Yoon 《Angewandte Chemie (International ed. in English)》2016,55(6):2239-2242
Azidoformates are interesting potential nitrene precursors, but their direct photochemical activation can result in competitive formation of aziridination and allylic amination products. Herein, we show that visible‐light‐activated transition‐metal complexes can be triplet sensitizers that selectively produce aziridines through the spin‐selective photogeneration of triplet nitrenes from azidoformates. This approach enables the aziridination of a wide range of alkenes and the formal oxyamination of enol ethers using the alkene as the limiting reagent. Preparative‐scale aziridinations can be easily achieved under continuous‐flow conditions. 相似文献
7.
α,β-Unsaturated 2-imidazolyl ketones undergo [2 + 2] cycloaddition with a variety of Michael acceptors upon irradiation with visible light in the presence of Ru(bpy)(3)(2+). Cleavage of the imidazolyl auxiliary from the cycloadducts affords cyclobutane carboxamides, esters, thioesters, and acids that would not be accessible from direct cycloaddition of the corresponding unsaturated carbonyl compounds. 相似文献
8.
Experiments on high-quality GaAs (311)A two-dimensional holes at low temperatures reveal a remarkable dependence of the magnetoresistance, measured with an in-plane magnetic field ( B), on the direction of B relative to both the crystal axes and the current direction. The magnetoresistance features, and in particular the value of B above which the resistivity exhibits an insulating behavior, depend on the orientation of B. To explain the data, the anisotropic band structure of the holes and a repopulation of the spin subbands in the presence of B, as well as the coupling of the orbital motion to B, need to be taken into account. 相似文献
9.
Ferro-Luzzi M Bouwhuis M Passchier E Zhou Z Alarcon R Anghinolfi M van Bommel R Botto T van den Brand JF Buchholz M Bulten HJ Choi S Comfort J Dolfini S Ent R Gaulard C Higinbotham D de Jager CW van Klaveren EP Konstantinov E Lang J de Lange DJ Miller MA Nikolenko D Nooren GJ Papadakis N Passchier I Poolman HR Popov SG Rachek I Ripani M Six E Steijger JJ Taiuti M Unal O Vodanis N de Vries H 《Physical review letters》1996,77(13):2630-2633
10.
The frequencies of Shubnikov-de Haas oscillations have long been used to measure the unequal population of spin-split two-dimensional subbands in inversion asymmetric systems. We report self-consistent numerical calculations and experimental results which indicate that these oscillations are not simply related to the zero-magnetic-field spin-subband densities. 相似文献