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排序方式: 共有140条查询结果,搜索用时 15 毫秒
1.
Feng Xian Liu-Cai Charlotte Pham Farida Bey Gilbert Hervé 《Reaction Kinetics and Catalysis Letters》2002,75(2):305-314
Effects of Cs+, H+ and Cu2+ counterions in the vanadium containing heteropoly compounds CsxH1-xVO[PMo12O40] and CsyH0.5-yCu0.25VO[PMo12O40] on the catalytic oxidation of isobutane and characterization by TGA, IR and ESR spectroscopies are reported. A high selectivity of 76% for methacrylic acid and methacrolein together has been obtained with Cs0.75H0.25VO[PMo12O40] catalysts at a reactivity of 5.3x10-1 mmol/h cm3. 相似文献
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Farida Larit Khaled M. Elokely Manal A. Nael Samira Benyahia Francisco Len Stephen J. Cutler Mohammed M. Ghoneim 《Molecules (Basel, Switzerland)》2021,26(4)
The in vitro activity of L. donovani (promastigotes, axenic amastigotes and intracellular amastigotes in THP1 cells) and T. brucei, from the fractions obtained from the hydroalcoholic extract of the aerial part of Hypericum afrum and the isolated compounds, has been evaluated. The chloroform, ethyl acetate and n-butanol extracts showed significant antitrypanosomal activity towards T. brucei, with IC50 values of 12.35, 13.53 and 12.93 µg/mL and with IC90 values of 14.94, 19.31 and 18.67 µg/mL, respectively. The phytochemical investigation of the fractions led to the isolation and identification of quercetin (1), myricitrin (2), biapigenin (3), myricetin (4), hyperoside (5), myricetin-3-O-β-d-galactopyranoside (6) and myricetin-3’-O-β-d-glucopyranoside (7). Myricetin-3’-O-β-d-glucopyranoside (7) has been isolated for the first time from this genus. The chemical structures were elucidated by using comprehensive one- and two-dimensional nuclear magnetic resonance (1D and 2D NMR) spectroscopic data, as well as high-resolution electrospray ionization mass spectrometry (HR-ESI–MS). These compounds have also been evaluated for their antiprotozoal activity. Quercetin (1) and myricetin (4) showed noteworthy activity against T. brucei, with IC50 and IC90 values of 7.52 and 5.71 µM, and 9.76 and 7.97 µM, respectively. The T. brucei hexokinase (TbHK1) enzyme was further explored as a potential target of quercetin and myricetin, using molecular modeling studies. This proposed mechanism assists in the exploration of new candidates for novel antitrypanosomal drugs. 相似文献
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Methane production characteristics of anaerobic co-digestion of pig manure (PM) and fermented liquid feed (FLF) were investigated in a continuous digester under mesophilic conditions. The experiment followed three phases. PM alone was digested in phase I. In phases II and III, PM and FLF were mixed in a ratio of 95:5 and 90:10 (% v/v), respectively. The specific methane yields (SMYs) during phases I, II, and III were 238, 278, and 326.8 mLCH4·gVS−1-added, respectively. It was due to the effect of balancing the feedstock carbon-to-nitrogen ratio by adding FLF. This improvement can also be attributed to the readily biodegradable compounds in the FLF. The higher SMY obtained in this study showed a positive synergistic effect in the anaerobic co-digestion of PM and FLF. The results also indicate that adding the FLF positively affected and maintained a constant pH level, avoiding volatile fatty acid accumulation and ammonia inhibition in the anaerobic digestion (AD). Thus, this study provides valuable information regarding the usage of unused or wasted FLF as a co-substrate for the practical AD of PM. The production of fermented liquid additives such as FLF to improve the methane production from the AD of PM is a potential novel alternative to food waste recycling in Japan, besides compost and animal feeding. 相似文献
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The spin coherent state path integral describing the dynamics of a two-level system interacting with electromagnetic wave of circular polarization is considered. The propagator is first written in the standard form by replacing the spin by a unit vector aligned along the polar and azimuthal directions. Then it is determined exactly using a simple transformations. Thus, the exact energy spectra with corresponding wave functions are deduced. 相似文献
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We present the comaprative study of semileptonic and leptonic decays of Ds, D±and D0meson(D →M l+-αl-β, D → l+αlβ, D → l+αvα;α,β=e,μ) within the framework of R-parity violating the( Rp) Minimal Supersymmetric Standard Model(MSSM). The comparison shows that combination and product couplings,(λβiα λ* ij qor λβqkλ*αj k)contribution to the branching fractions of the said processes(under consideration) is consistent with or comparable to the experimental measurements in most of the cases. However, some cases exist where these contributions are highly suppressed. We identify such cases in our analysis and single out the important ones suitable for exploring in the future and current experiments. 相似文献
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Multifunctional mesoporous silica nanoparticles in poly(ethylene‐co‐vinyl acetate) for transparent heat retention films 下载免费PDF全文
Md Abdul Mumin Kazi Farida Akhter Sara Dresser Sasha T. van Dinther Wei Wu Paul A. Charpentier 《Journal of Polymer Science.Polymer Physics》2015,53(12):851-859
Transparent inorganic‐polymer nanocomposite films are of tremendous current interest inemerging solar coverings including photovoltaic encapsulants and commercial greenhouse plastics, but suffer from significant radiative heat loss. This work provides a new and simple approach for controlling this heat loss by using mesoporous silica/quantum dot nanoparticles in poly(ethylene‐co‐vinyl acetate) (EVA) films. Mesoporous silica shells were grown on CdS‐ZnS quantum dot (QDs) cores using a reverse microemulsion technique, controlling the shell thickness. These mesoporous silica nanoparticles (MSNs) were then melt‐mixed with EVA pellets using a mini twin‐screw extruder and pressed into thin films of concentration variable controlled thickness. The results demonstrate that the experimental MSNs showed improved infrared and thermal wavebands retention in the EVA transparent films compared to commercial silica additives, even at lower concentrations. It was also found MSNs enhanced the quantum yield and photostability of the QDs, providing high visible light transmission and blocking of UV transmission of interest for next generation solar coatings. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 851–859 相似文献
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We use Zimm's single-contact approximation to investigate the concentration dependence of the first cumulant for partially labeled chains in dilute solutions. This approximation allows us to express interchain properties (such as the interference part of the generalized mobility) in terms of static structure factors, which are then modeled using a Gaussian chain model. We present numerical results for three specific labeling sequences. 相似文献