Aromatic poly(sulfone sulfide amide imide)s as new types of soluble thermally stable polymers

A new diamine monomer containing flexible sulfone, sulfide, and amide units was prepared via three steps. Nucleophilic chloro displacement reaction of 4‐aminothiophenol with 4‐nitrobenzoyl chloride in the presence of propylene oxide afforded N‐(4‐mercapto‐phenyl)‐4‐nitrobenzamide and subsequent reduction of the nitro intermediate led to 4‐amino‐N‐(4‐mercapto‐phenyl)benzamide. Two moles of this amino thiophenol compound was reacted with bis‐(4‐chloro phenyl)sulfone to provide a novel diamine monomer. The diamine was reacted with aromatic dianhydrides to form polyimides via a two‐step polycondensation method, formation of poly(amic acid)s, followed by chemical imidization. The resulting polymers were characterized and their physical properties including thermal behavior, thermal stability, solubility and inherent viscosity were studied. Copyright © 2007 John Wiley & Sons, Ltd.     

Capable Lie algebras with the derived subalgebra of dimension 2 over an arbitrary field

In this paper, we classify all capable nilpotent Lie algebras with the derived subalgebra of dimension 2 over an arbitrary field. Moreover, the explicit structure of such Lie algebras of class 3 is given.     

Luciferin‐Regenerating Enzyme Mediates Firefly Luciferase Activation Through Direct Effects of D‐Cysteine on Luciferase Structure and Activity

Luciferin‐regenerating enzyme (LRE) contributes to in vitro recycling of D‐luciferin. In this study, reinvestigation of the luciferase‐based LRE assay is reported. Here, using quick change site‐directed mutagenesis seven T‐LRE (Lampyris turkestanicusLRE) mutants were constructed and the most functional mutant of T‐LRE (T⁶⁹R) was selected for this research and the effects of D‐ and L‐cysteine on T⁶⁹R T‐LRE‐luciferase‐coupled assay are examined. Our results demonstrate that bioluminescent signal of T⁶⁹R T‐LRE‐luciferase‐coupled assay increases and then reach equilibrium state in the presence of 5 mm D‐cysteine. In addition, results reveal that 5 mm D‐ and L‐cysteine in the absence of T⁶⁹R T‐LRE cause a significant increase in bioluminescence intensity of luciferase over a long time as well as decrease in decay rate. Based on activity measurements, far‐UV CD analysis, ANS fluorescence and DLS (Dynamic light scattering) results, D‐cysteine increases the activity of luciferase due to weak redox potential, antiaggregatory effects, induction of changes in conformational structure and kinetics properties. In conclusion, in spite of previous reports on the effect of LRE on luciferase bioluminescent intensity, the majority of increase in luciferase light output and time‐course originate from the direct effects of D‐cysteine on structure and activity of firefly luciferase.     

Robust synchronization of a class of uncertain chaotic systems based on quadratic optimal theory and adaptive strategy

This paper presents a chaos synchronization method for a class of uncertain chaotic systems using the combination of an optimal control theory and an adaptive strategy. A quadratic optimal regulator and an adaptive control are used to represent the controller's structure. The asymptotic stability of the corresponding error dynamical system is guaranteed through Lyapunov stability analysis. The proposed controller is employed in two uncertain chaotic Lu systems, and their promising performances are illustrated.     

c-capability of Lie algebras with the derived subalgebra of dimension two

The current article is devoted to classify the c-capability of finite dimensional nilpotent Lie algebras with the derived subalgebra of dimension two.     

Preparation and properties of polyimides and polyamide-imides from diisocyanates

Polyimides of different structures were synthesized by reaction of 1,4-phenylene diisocyanate (PPDI) and 1,5-naphthalene diisocyanate (NDI) with pyromellitic dianhydride (PMDA) and 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA). Polyamide-imides were also prepared by reaction of PPDI and NDI with trimellitic anhydride. The optimized condition for polymerization reactions were obtained via the study of model compounds. All polymers and model compounds were characterized by conventional methods. Physical properties of polymers, including thermal behavior, thermal stability, solution viscosity, and solubility behavior, were also studied. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 2245–2250, 1999     

Control of chaos in permanent magnet synchronous motor by using optimal Lyapunov exponents placement

Permanent Magnet Synchronous Motor (PMSM) experiences chaotic behavior for a certain range of its parameters. In this case, since the performance of the PMSM degrades, the chaos should be eliminated. In this Letter, the control of the undesirable chaos in PMSM using Lyapunov exponents (LEs) placement is proposed that is also improved by choosing optimal locations of the LEs in the sense of predefined cost function. Moreover, in order to provide the physical realization of the method, nonlinear parameter estimator for the system is suggested. Finally, to show the effectiveness of the proposed methodology, the simulation results for applying this control strategy are provided.