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1.
The electrooxidation of Gabapentin was studied on nanotubes of nickel oxide-modified carbon paste electrode for the first time. Cyclic voltammetry was employed
to investigate the electrooxidation process. A simple, sensitive, and efficient amperometric method was developed for the
analysis of the drug, and the corresponding analytical parameters were reported. For Gabapentin, a detection limit of 0.3 μM
was obtained in a linear range of 2.4–50 μM. The proposed amperometric method was also applied to the analysis of commercial
capsules, and the results were in good agreement with the declared values. Also, the applicability of the method to the direct
assay of the drug in human serum and urine was described. 相似文献
2.
Ghodsi Mohammadi Ziarani Sakineh Faramarzi Negar Lashgari Alireza Badiei 《Journal of the Iranian Chemical Society》2014,11(3):701-709
Sulfonic acid functionalized SBA-15 (SBA-Pr-SO3H) as a new nanoporous solid acid catalyst was applied in the green one-pot synthesis of spiro[indole-tetrahydropyrano(2,3-d)pyrimidine] derivatives via three-component reaction of isatins, malononitrile or cyanoacetic esters and barbituric acids under solvent-free conditions. SBA-Pr-SO3H was proved to be an efficient heterogeneous nanoporous solid acid catalyst with a pore size of 6 nm, which could be easily handled and removed from the reaction mixture by simple filtration and can be recovered and reused several times without any loss of activity. The advantages of this methodology are high product yields, being environmentally benign, short reaction times, and easy handling. 相似文献
3.
Mohsen Gorji Saeedeh Mazinani Abdol-Rahim Faramarzi Saeedeh Ghadimi Mohammadreza Kalaee Ali Sadeghianmaryan Lee D. Wilson 《Molecules (Basel, Switzerland)》2021,26(12)
Textiles coated with silver nanowires (AgNWs) are effective at suppressing radiative heat loss without sacrificing breathability. Many reports present the applicability of AgNWs as IR-reflective wearable textiles, where such studies partially evaluate the parameters for practical usage for large-scale production. In this study, the effect of the two industrial coating methods and the loading value of AgNWs on the performance of AgNWs-coated fabric (AgNWs-CF) is reported. The AgNWs were synthesized by the polyol process and applied onto the surface of cotton fabric using either dip- or spray-coating methods with variable loading levels of AgNWs. X-ray diffraction, scanning electron microscopy (SEM), infrared (IR) reflectance, water vapor permeability (WVP), and electrical resistance properties were characterized. The results report the successful synthesis of AgNWs with a 30 μm length. The results also show that the spray coating method has a better performance for reflecting the IR radiation to the body, which increases with a greater loading level of the AgNWs. The antibacterial results show a good inhibition zone for cotton fabric coated by both methods, where the spray-coated fabric has a better performance overall. The results also show the coated fabric with AgNWs maintains the level of fabric breathability similar to control samples. AgNWs-CFs have potential utility for cold weather protective clothing in which heat dissipation is attenuated, along with applications such as wound dressing materials that provide antibacterial protection. 相似文献
4.
M. Torshabi M. Badiee M. A. Faramarzi H. Rastegar H. Forootanfar E. Mohit 《Chemistry of Natural Compounds》2011,47(1):59-63
Fungi have proved to be powerful biocatalysts in steroid biotransformations. In the present study, the soil isolate filamentous
fungus Mucor racemosus was applied for bioconversion of methyltestosterone (1), an anabolic steroid, in a five-day fermentation. Microbial metabolites were purified chromatographically and identified
on the basis of their spectral data as 7α-hydroxymethyltestosterone (2), 15α-hydroxymethyltestosterone (3), and 12,15α-dihydroxymethyltestosterone (4). Observed modifications were hydroxylations at C-7α, C-12, and 15α-positions. Best fermentation condition for production of hydroxylated derivatives was found to be 25°C at 150 rpm for 5 days
with a substrate concentration of 1 mg/mL. 相似文献
5.
The extended UNIQUAC model [K. Thomsen, P. Rasmussen, Chem. Eng. Sci. 54 (1999) 1787–1802] was applied to the thermodynamic representation of carbon dioxide absorption in aqueous monoethanolamine (MEA), methyldiethanolamine (MDEA) and varied strength mixtures of the two alkanolamines (MEA–MDEA). For these systems, altogether 13 interaction model parameters are adjusted. Out of these parameters, 11 are temperature dependent. 相似文献
6.
7.
S. Sanjabi A. Faramarzi Z.H. Barber 《Journal of Physics and Chemistry of Solids》2008,69(8):1940-1944
Size-dependent thermodynamic parameters, such as Gibbs free energy, enthalpy and entropy, for the transition of a Ni nanofilm to catalyst particles for subsequent carbon nanotube growth have been explored. In this investigation, we consider the derived equations of the size-dependent melting temperature of nanosolids based on our previous works. Using this thermodynamic approach, it is found that the diameter of Ni particles is 3 times greater than the thickness of the original film. From the critical and stable sizes of transformed Ni nanoparticles, a minimum film thickness for transformation of film to nanoparticles was obtained. Our predictions are in good agreement with experimental results. 相似文献
8.
MICROBE-METAL-INTERACTIONS FOR THE BIOTECHNOLOGICAL TREATMENT OF METAL-CONTAINING SOLID WASTE 总被引:3,自引:0,他引:3
Helmut Brandl Mohammad A. Faramarzi 《中国颗粒学报》2006,4(2):93-97
In nature, microbes are involved in weathering of rocks, in mobilization of metals from minerals, and in metal precipitation and deposition. These microbiological principles and processes can be adapted to treat particulate solid wastes. Especially the microbiological solubilization of metals from solid minerals (termed bioleaching) to obtain metal values is a well-known technique in the mining industry. We focus here on non-mining minerai wastes to demonstrate the applicability of mining-based technologies for the treatment of metal-containing solid wastes. In the case study presented, microbial metal mobilization from particulate fly ash (originating from municipal solid waste incineration) by Acidithiobacilli resulted in cadmium, copper, and zinc mobilization of 〉80%, whereas lead, chromium, and nickel were mobilized by 2, 11 and 32%, respectively. In addition, the potential of HCN-forming bacteria (Chromobacterium violaceum, Pseudornonas fluorescens) was investigated to mobilize metals when grown in the presence of solid materials (e.g.,copper-containing ores, electronic scrap, spent automobile catalytic converters). C. violaceum was found capable of mobilizina nickel as tetracyanonickelate from fine-grained nickel powder. Gold was microbially solubJlized as dicyanoaurate from electronic waste. Additionally, cyanide-complexed copper was detected during biological treatment of shredded printed circuit-board scraps. Water-soluble copper and platinum cyanide were also detected during the treatment of spent automobile catalytic converters. 相似文献
9.
Hojat-Allah Arab Mohammad Ali Faramarzi Nasrin Samadi Hamid Irannejad Alireza Foroumadi Saeed Emami 《Molecular diversity》2018,22(4):815-825
A series of 7-piperazinylquinolones containing a (benzo[d]imidazol-2-yl)methyl moiety were designed and synthesized as new antibacterial agents. The antibacterial activity of title compounds was evaluated against Gram-positive (Staphylococcus aureus, Staphylococcus epidermidis and Bacillus subtilis) and Gram-negative (Escherichia coli, Pseudomonas aeruginosa and Klebsiella pneumonia) microorganisms. Among the tested compounds, the N1-cyclopropyl derivative 4a showed the highest activity against S. aureus, S. epidermidis, B. subtilis and E. coli (\(\text {MIC} = 0.097\) \(\upmu \)g/mL), being 2–4 times more potent than reference drug norfloxacin. A structure-activity relationship study demonstrated that the effect of the nitro group on the benzimidazole ring depends on the pattern of substitutions on the piperazinylquinolone. 相似文献
10.
Nasli Esfahani Anita Iraji Aida Alamir Amir Moradi Shahram Asgari Mohammad Sadegh Hosseini Samanesadat Mojtabavi Somayeh Nasli-Esfahani Ensieh Faramarzi Mohammad Ali Bandarian Fatemeh Larijani Bagher Hamedifar Haleh Hajimiri Mir Hamed Mahdavi Mohammad 《Molecular diversity》2022,26(4):1995-2009
Molecular Diversity - A novel series of phenoxymethybenzoimidazole derivatives (9a-n) were rationally designed, synthesized, and evaluated for their α-glycosidase inhibitory activity. All... 相似文献