全文获取类型
收费全文 | 143篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 77篇 |
晶体学 | 1篇 |
力学 | 10篇 |
数学 | 33篇 |
物理学 | 25篇 |
出版年
2023年 | 1篇 |
2022年 | 6篇 |
2021年 | 4篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 7篇 |
2014年 | 4篇 |
2013年 | 19篇 |
2012年 | 7篇 |
2011年 | 11篇 |
2010年 | 10篇 |
2009年 | 6篇 |
2008年 | 10篇 |
2007年 | 3篇 |
2006年 | 5篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1997年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有146条查询结果,搜索用时 0 毫秒
1.
Aloui M Chambers DJ Cumpstey I Fairbanks AJ Redgrave AJ Seward CM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(11):2608-2621
The technique of intramolecular aglycon delivery (IAD), whereby a glycosyl acceptor is temporarily appended to a hydroxyl group of a glycosyl donor is an attractive method that can allow the synthesis of 1,2-cis glycosides in an entirely stereoselective fashion. 2-O-Allyl protected thioglycoside donors are excellent substrates for IAD, and may be glycosylated stereoselectively through a three-step reaction sequence. This sequence consists of quantitative yielding allyl bond isomerisation, to produce vinyl ethers that can then undergo N-iodosuccinimide mediated tethering of the desired glycosyl acceptor, and subsequent intramolecular glycosylation, to yield either alpha-glucosides or beta-mannosides accordingly. Although attempted one-pot tethering and glycosylation is hampered by competitive intermolecular reaction with excess glycosyl acceptor, this problem can be simply overcome by the use of excess glycosyl donor. Allyl mediated IAD is a widely applicable practical alternative to other IAD approaches for the synthesis of beta-mannosides, that is equally applicable for alpha-gluco linkages. It is advantageous in terms of both simplicity of application and yield, and in addition has no requirement for cyclic 4,6-protection of the glycosyl donor. 相似文献
2.
Amel Souibgui Anne Gaucher Jérôme Marrot Flavien Bourdreux Faouzi Aloui Béchir Ben Hassine Damien Prim 《Tetrahedron》2014
New series of acridines and phenanthrolines have been prepared from β-chlorovinyl aldehydes and various aniline derivatives allowing the installation of valuable substituents, such as ketone, nitro or amino groups at the heterocyclic core. X-ray analyses confirmed the structures of acridines and phenanthrolines as well as the presence of partially hydrogenated rings and their crucial impact on the overall shape of the acridine-based architectures. 1H NMR revealed the helical behaviour of several acridine motives. Comparison of UV data between architectures and influence of number of partially hydrogenated rings is also described. 相似文献
3.
Baghdadi Aloui 《Periodica Mathematica Hungarica》2018,76(1):126-132
It is well known that monic orthogonal polynomial sequences \(\{T_n\}_{n\ge 0}\) and \(\{U_n\}_{n\ge 0}\), the Chebyshev polynomials of the first and second kind, satisfy the relation \(DT_{n+1}=(n+1)U_n\) (\(n\ge 0\)). One can also easily check that the following “inverse” of the mentioned formula holds: \({\mathcal {U}}_{-1}(U_n)=(n+1)T_{n+1}\) (\(n\ge 0\)), where \({\mathcal {U}}_\xi =x(xD+{\mathbb {I}})+\xi D\) with \(\xi \) being an arbitrary nonzero parameter and \({\mathbb {I}}\) representing the identity operator. Note that whereas the first expression involves the operator D which lowers the degree by one, the second one involves \({\mathcal {U}}_\xi \) which raises the degree by one (i.e. it is a “raising operator”). In this paper it is shown that the scaled Chebyshev polynomial sequence \(\{a^{-n}U_n(ax)\}_{n\ge 0}\) where \(a^2=-\xi ^{-1}\), is actually the only monic orthogonal polynomial sequence which is \({\mathcal {U}}_\xi \)-classical (i.e. for which the application of the raising operator \({\mathcal {U}}_\xi \) turns the original sequence into another orthogonal one). 相似文献
4.
Abdelhak Fahsi Mohamed Belhaq Faouzi Lakrad 《Communications in Nonlinear Science & Numerical Simulation》2009,14(4):1609-1616
This paper examines the suppression of hysteresis in a forced nonlinear self-sustained oscillator near the fundamental resonance. The suppression is studied by applying a rapid forcing on the oscillator. Analytical treatment based on perturbation analysis is performed to capture the entrainment zone, the quasiperiodic modulation domain and the hysteresis area as well. The analysis leads to a strategy for the suppression of hysteresis occurring between 1:1 frequency-locked motion and quasiperiodic response. This hysteresis suppression causes the disappearance of nonlinear effects leading to a smooth transition between the quasiperiodic and the frequency-locked responses. Specifically, it appears that a rapid forcing introduces additional apparent nonlinear stiffness which can effectively suppress hysteresis in a certain range of the rapid excitation frequency. This work was motivated by the important issue of controlling and eliminating hysteresis often undesirable in mechanical systems, in general, and in application to microscale devices, especially. 相似文献
5.
6.
NaAgPbP2O7 was prepared with a solid-state reaction. The electrical properties were investigated by using impedance measurements in
the frequency range from 200 Hz to 5 MHz with the TEGAM 3550 ALF automatic bridge monitored by a microcomputer between 581 K
and 703 K. The Z′ and Z″ versus frequency plots are well fitted to an equivalent circuit model. The conductivity data obey the universal power law.
The conductivity in the material is due to the hopping of monovalent ions parallel to (001) plane. 相似文献
7.
Mabrouk Khelifi Imen Mkaouar Faouzi Hlel Abdelhamid Ben Salah Ridha Zouari 《Ionics》2010,16(8):709-715
The crystal structure of (C5N2H7)4.HBi2Cl11 has been determined at room temperature by single crystal X-ray diffraction. The compound crystallizes in the triclinic system with Pī space group. The crystal structure consists of two asymmetric inequivalent molecules of 4-aminopyridinium and anionic HBi2Cl11 chains. The HBi2Cl11 anionic chains stacked along the a-axis are formed with Bi2Cl11 dimers connected to each other via hydrogen atoms. The crystal packing is stabilized with N–H...Cl hydrogen bonds connecting aminopyridinium units to the HBi2Cl11 anionic chains. The title compound exhibits an order–disorder phase transition at 338 K. The AC electrical conductivity properties of (C5N2H7)4.HBi2Cl11 compound have been investigated by means of impedance spectroscopy measurements over wide ranges of frequencies and temperatures, 200 Hz to 5 MHz and 303 to 418 K, respectively. Detailed analysis of the impedance spectrum suggests that the electrical properties of the material are strongly temperature dependent. The frequency-dependent conductivity data were fitted in the Jonscher's law: $ \sigma \left( \omega \right) = \sigma (0) + A{\omega^n} $ . The nature of variation of DC conductivity suggests Arrhenius type of electrical conductivity. 相似文献
8.
Hamadi Jerbi Thouraya Kharrat Faouzi Omri 《Mediterranean Journal of Mathematics》2016,13(5):2507-2524
In this paper, we consider a class of bilinear systems in dimension three which can be an extension of another one in \({\mathbbm{R}^{2}}\). We prove that there exists some homogeneous feedback of degree zero stabilizing the considered class if and only if these feedbacks are constants. 相似文献
9.
Nabil Smichi Ahmed Fendri Raja Chaabouni Faouzi Ben Rebah Youssef Gargouri Nabil Miled 《Applied biochemistry and biotechnology》2010,162(5):1483-1496
A lipolytic activity was located in the sardine digestive glands (pyloric caeca), from which a sardine digestive lipase (SaDL)
was purified. Pure SaDL has a molecular mass of 43 kDa as determined by sodium dodecyl sulfate polyacrylamide gel electrophoresis
analysis. The enzyme was found to be more active on short-chain triacylglycerols than on long-chain ones. SaDL does not present
the interfacial activation phenomenon. Control experiments were performed under the same experimental conditions, with dromedary
and turkey pancreatic lipases and showed a positive interfacial activation phenomenon. Sodium deoxycholate (NaDC) has an inhibitory
effect on the lipase activity. The pure enzyme lost 40% of its activity in presence of 8 mM NaDC. SaDL was found to be mostly
stable at low pH values. Interestingly, no colipase was detected in the sardine pyloric caeca. Analogous results were reported
for the scorpion and the crab digestive systems. This is in line with the idea that colipase might has evolved in mammal animals
simultaneously with the appearance of an exocrine pancreas. No similarity was found between the NH2-terminal amino acid residues of SaDL and those of lipases from the digestive tract of other species. Altogether, these results
suggest that SaDL is a member of a new group of lipases belonging to aquatic species. 相似文献
10.
Najoua Ouerfelli Daniele Mazza Mohamed Faouzi Zid 《Journal of solid state chemistry》2007,180(4):1224-1229
A new solid solution TlFe0.22Al0.78As2O7 has been synthesized by a solid-state reaction. The structure of the title compound has been determined from a single-crystal X-ray diffraction and refined to final values of the reliability factors: R(F2)=0.030 and wR(F2)=0.081 for 1343 independent reflections with I>2σ(I). It crystallizes in the triclinic space group P-1, with a=6.296(2) Å, b=6.397(2) Å, c=8.242(2) Å, α=96.74(2)°, β=103.78(2)°, γ=102.99(3)°, V=309.0(2) Å3 and Z=2. The structure can be described as a three-dimensional framework containing (Fe/Al)O6 octahedra connected through As2O7 groups. The metallic units and diarsenate groups share oxygen corners to form a three-dimensional framework with interconnected tunnels parallel to the a, b and c directions, where Tl+ cations are located. The ionic conductivity measurements are performed on pellets of the polycrystalline powder. At 683 K, The conductivity value is 5.23×10−6 S cm−1 and the ionic jump activation energy is 0.656 eV. The bond valence analysis reveals that the ionic conductivity is ensured by Tl+ along the [001] direction. 相似文献