A comparative investigation of the fatty acid compositions of the seeds of a number of lines of a genetic collection of Gossypium hirsutum

A comparative analysis has been made of the amounts of lipids and their fatty-acid compositions in the seeds of the lines of agenetic collection of cotton plants of the speciesGossypium hirsutum and their hybrids and the variety Tashkent-1. The results obtained on the fatty-acid compositions of some hybrids make it possible to recommend the use of individual lines of cotton plants as donors for improving the food-value indices of cottonseed oil.Institute of Chemsitry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. V. I. Lenin Tashkent State University. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 173–176, March–April, 1991.     

Protonation and methylation of η-2,3,5,6-tetramethyl-1,4-benzoquinone(η-pentamethylcyclopentadienyl)cobalt

The preparation of the η⁴-4-2,3,5,6-tetramethyl-1,4-benzoquinonecomplex [CO(C₅Me₅)(C₁₀H₁₂O₂)] (I) is reported. Complex I undergoesreversible protonation to yield the 2-6-η-4-hydroxy-1-oxo-2,3,5,6-tetramethylcyclohexadienyl complex [Co(C₅Me₅)(C₁₀H₁₃O₂)BF₄ (II) and diprotonation to yield the η⁶-6-1,4-dihydroxy-2,3,5,6-tetramethylbenzene complex [Co(C₅Me₅)(C₁₀H₁₄O₂)] (BF₄)₂ (III). Methylation of complex I with MeI/AgPF₆ gives the 2---6-η-4-methoxy-1-oxo-2,3,5,6-tetramethylcyclohexadienyl complex [Co(C₅Me₅)(C₁₁H₁₅O₂])PF₆ (IV). In trifluoroacetic acid solution complex IV is protonated to form the η⁶-1-hydroxy-4-methoxy-2,3,5,6-tetramethylbenzene cation [Co(C₅Me₅)-(C₁₁H₁₆O₂)]²⁺     

Determination of selenium in human tissues by atomic absorption spectrometry

A simple method is described for the determination of selenium in human tissues without the use of perchloric acid. Digestion with nitric and sulphuric acids is followed by hydride generation and atomic absorption spectrometry. Results for NBS bovine liver and IAEA horse kidney reference materials were in good agreement with assigned concentrations, as was also achieved with the perchloric acid digestion. Recovery of added selenium was >90%, and the relative standard deviation was 5.5% for within-batch and 6.9% for between-batch analyses. The values of selenium in heart tissue were 0.9–1.3 μg g^?1 dry weight.     

高能核碰撞中带电多重数快度与能量和中心度的关系

用强子–弦级联模型JPCIAE及相应的Monte Carlo事例产生器研究相对论性核–核碰撞中带电粒子多重数的赝快度密度对能量和中心度的依赖关系.无需另调任何模型参数的条件下,此模型可以同时较好地描述相对论性pp实验数据及PHOBOS和PHENIX实验组的Au+Au实验数据.本文指出:因〈N_part〉并非严格定义的物理量,致使实验上和理论上确定〈N_part〉有一定任意性,从而使得每参加者核子对的带电粒子赝快度密度随着〈N_part〉的增加可能逐渐增大,也可能逐渐减小,因此用它来区分粒子产生机制是欠妥的.     

Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence (Fe(I)-Fe(II)) bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase

Iron(I) in biology?: one-electron oxidation of an (Fe(I)-Fe(I)) carbonyl cyanide precursor bearing a proximal thioether group leads to an (Fe(I)-Fe(II)) bridging carbonyl transient with spectral features similar to the di-iron sub-site of the CO inhibited paramagnetic centre of all-iron hydrogenase.     

A radiotracer study of adsorption on activated carbon cloth from aqueous solution

A study has been made on the effect of pH upon the equilibrium adsorption capacity of triethyl phosphate, dimethyl phosphate and orthophosphate on to activated carbon cloth. It is shown that for molecular phosphates no dependence upon pH exists, whilst the adsorption of ionic phosphates exhibit a strong pH dependence. These adsorption trends may be explained in terms of pKa values, ionic strength and the surface charge of the activated carbon cloth is aqueous solution.     

Exploration for Degradation of Λ Polarization Produced in Relativistic Nucleus Nucleus Collisions

The degradation of Λ transverse polarization produced in S+Pb central collisions at energy 200 GeV per nucleon has been studied in detail. The S+Pb central collision events have been generated using Monte-Carlo generator——LUCIAE at 200 GeV per nucleon. The various factors degrading Λ transverse polarization have been analysed quantitatively. The ratios of Λ′s produced from rescattering, secondary production and decays of Σ, Ξ hyperons to the total measurable Λ′s in experiment have been investigeted and the degradation effect of these Λ on the total polarization has been determined. The simulation and calculation show that above three factors decrease the Λ transverse polarization strongly, however, can not eliminate the polarization completely when the Λ′s are assumed to be produced from hadronic gas in the final state. To explan the experimental data of vanished Λ polarization, it probably needs to consider new mechanisms of Λ production, including a weak effect of QGP formation.     

多功能两亲梳状聚合物的合成及包覆荧光量子点

利用溶液聚合和成酰胺反应合成了多功能梳状两亲性共聚物,聚(甲基丙烯酸-co-甲基丙烯酸十八酯)-(乙醇胺-乙二胺叶酸)(PSM-EE-FA).用红外光谱(FTIR),核磁共振(1H-NMR)及凝胶渗透色谱(GPC)表征了该聚合物的结构及分子量分布.实验结果证明合成了该聚合物,其数均分子量(Mn)为28600,多分散性为1.375.用该两亲梳状聚合物包覆油溶性CdSe/ZnS量子点,通过相转移作用,得到水溶性靶向量子点(PSM-EE-FA-QDs).该水溶性量子点溶液具有较好的稳定性.通过紫外-可见(UV-Vis)及荧光发射光谱分析对该量子点的光学性质进行研究.结果表明,PSM-EE-FA-QDs的紫外-可见光谱及荧光发射光谱峰形与原量子点基本一致.由于量子点表面聚合物层的形成,峰位发生少量红移.该量子点水溶液的荧光强度是原量子点氯仿溶液的98%,荧光产率是原量子点氯仿溶液的95%.动态光散射(DLS)及透射电镜(TEM)测试结果表明水溶性量子点分布均匀.合成的水溶性量子点不但光学性能稳定,而且聚合物及水溶性量子点的合成方法较为简便.     

THE EVIDENCE OF DECONFINEMENT PHASE TRANSITION OF SU(2) LATTICE GAUGE MODEL BY MONTE CARLO METHOD

In this paper,we have calculated the SU(2) lattice gauge by the Monte Carlo method.For the finite temperature problem 8³×4 lattice is used and for the zero temperature problem 8⁴ lattice.From the calculations of the energy density,heat capacity and entropy density,the results indicate that there is a deconfinement phase transition when T/Λ_L=40—50.