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Potential photosensitizers for photodynamic therapy. III. Photophysical properties of a lipophilic chlorin and its zinc and tin chelates. 总被引:1,自引:0,他引:1
C Grewer G Schermann R Schmidt A V?lcker H D Brauer A Meier F P Montforts 《Journal of photochemistry and photobiology. B, Biology》1991,11(3-4):285-293
Photophysical properties of a lipophilic chlorin derivative and its zinc and tin chelates were investigated in chloroform. The quantum yields of the fluorescence phi F, of the S1----T1 intersystem crossing phi T and of singlet oxygen (1 delta g) formation phi delta, as well as the Stern-Volmer constants for the quenching of the S1 states by oxygen and the rate constants of quenching of O2(1 delta g) by the chlorins were measured. In comparison to the metal-free chlorin an increase of phi T and a decrease of phi F have been observed for the metal-containing derivatives, whereas the phi delta values remain constant. 相似文献
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Franz-Peter Montforts 《Angewandte Chemie (International ed. in English)》1990,29(5):563-563
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Könekamp T Ruiz A Duwenhorst J Schmidt W Borrmann T Stohrer WD Montforts FP 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(23):6595-6604
The enantiomerically pure chlorins 19 and 21 were synthesised from tripyrrolic nickel complex rac-17 and pyrrole building blocks 12 and 16. The pyrroles are annelated with norbornane moieties which contain the chiral information as well as two different functionalities. The functional groups, namely a carboxylic acid ester and a carbonitrile group, of chlorin 21 finally allowed the formation of an amino acid functionality at the periphery of the macrotetracycle. By using principles of peptide chemistry, the two chlorin subunits were joined to form the peptide-linked chlorin-chlorin dyad 24, which mimics the molecular parts of the natural photosynthetic reaction centre. 相似文献
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Synthesis of Sulfolenobilins and Their Cyclization Directed to Chlorinatozinc‐Fullerene Dyads A novel chlorinatozinc‐fullerene dyad 18 was synthesized to model the photosynthetic reaction center. The synthetic key step for the formation of the dyad 18 is an unusual one‐pot reaction of the (sulfolenobilinato)nickel rac‐ 16a , b with concomitant generation of the chlorin macrocycle and linkage to the [5,6]fullerene‐C60‐Ih. This one‐pot reaction is a complex cascade of single reaction steps with a total yield of 32% and an average yield of 83% for the individual steps. The chlorinatozinc‐fullerene dyad is so far one of three examples that contain chlorin moieties, the chromophores in naturally occurring photosynthetic systems. 相似文献
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To model the photosynthetic reaction center, the chlorin - fullerene dyad 1 was synthesized in a one-pot reaction from a linear tetrapyrrole and C(60). It is the first dyad of this type which contains a fullerene and a chlorin unit, the chromophore of naturally occurring photosynthetic systems. 相似文献
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Yvonne Abel Elmar Haake Gerold Haake Wolfgang Schmidt Daria Struve Andreas Walter Franz-Peter Montforts 《Helvetica chimica acta》1998,81(11):1978-1996
A Simple and Flexible Synthesis of Pyrroles from α , β -Unsaturated Sulfones: The addition of alkyl isocyanoacetates and isocyanoacetonitrile to α,β-unsaturated sulfones affords a convenient and broad access to pyrroles with unusual substitution patterns (see Scheme 2). The α,β-unsaturated sulfones required as starting materials are easily obtained from different olefines. 相似文献