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排序方式: 共有229条查询结果,搜索用时 15 毫秒
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Aleksandr V. Prichodko Evgenii V. Shatkovski Sergei G. Yastrebov 《International Journal of Infrared and Millimeter Waves》1994,15(3):579-584
Photostimulated changes in thin carbon films deposited onto fused silica substrates by reactive magnetron sputtering and irradiated by the light of the first (1060nm) and the second (530nm) harmonics of a QW-switched Nd3+ AVG laser were investigated. The changes are supposed to be connected with the reordering of chemical bounds. 相似文献
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Konstantin P Bryliakov Nina V Semikolenova Vladimir A Zakharov Martin Ystenes Evgenii P Talsi 《Journal of organometallic chemistry》2003,683(1):92-102
Using 1H- and 13C-NMR spectroscopies, cationic intermediates formed by activation of L2ZrCl2 with methylaluminoxane (MAO) in toluene were monitored at Al/Zr ratios from 50 to 1000 (L2 are various cyclopentadienyl (Cp), indenyl (Ind) and fluorenyl (Flu) ligands). The following catalysts were studied: (Cp-R)2ZrCl2 (R=Me, 1,2-Me2, 1,2,3-Me3, 1,2,4-Me3, Me4, Me5, n-Bu, t-Bu), rac-ethanediyl(Ind)2ZrCl2, rac-Me2Si(Ind)2ZrCl2, rac-Me2Si(1-Ind-2-Me)2ZrCl2, rac-ethanediyl(1-Ind-4,5,6,7-H4)2ZrCl2, (Ind-2-Me)2ZrCl2, Me2C(Cp)(Flu)ZrCl2, Me2C(Cp-3-Me)(Flu)ZrCl2 and Me2Si(Flu)2ZrCl2. Correlations between spectroscopic and ethene polymerization data for catalysts (Cp-R)2ZrCl2/MAO (R=H, Me, 1,2-Me2, 1,2,3-Me3, 1,2,4-Me3, Me4, Me5, n-Bu, t-Bu) and rac-Me2Si(Ind)2ZrCl2 were established. The catalysts (Cp-R)2ZrCl2/AlMe3/CPh3+B(C6F5)4− (R=Me, 1,2-Me2, 1,2,3-Me3, 1,2,4-Me3, Me4, n-Bu, t-Bu) were also studied for comparison of spectroscopic and polymerization data with MAO-based systems. Complexes of type (Cp-R)2ZrMe+←Me−-Al≡MAO (IV) with different [Me-MAO]− counteranions have been identified in the (Cp-R)2ZrCl2/MAO (R=n-Bu, t-Bu) systems at low Al/Zr ratios (50-200). At Al/Zr ratios of 500-1000, the complex [L2Zr(μ-Me)2AlMe2]+[Me-MAO]− (III) dominates in all MAO-based reaction systems studied. Ethene polymerization activity strongly depends on the Al/Zr ratio (Al/Zr=200-1000) for the systems (Cp-R)2ZrCl2/MAO (R=H, Me, n-Bu, t-Bu), while it is virtually constant in the same range of Al/Zr ratios for the catalytic systems (Cp-R)2ZrCl2/MAO (R=1,2-Me2, 1,2,3-Me3, 1,2,4-Me3, Me4) and rac-Me2Si(Ind)2ZrCl2/MAO. The data obtained are interpreted on assumption that complex III is the main precursor of the active centers of polymerization in MAO-based systems. 相似文献
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Tat'yana T Kucherenko Roman Gutsul Vladimir M Kisel Vladimir A Kovtunenko 《Tetrahedron》2004,60(1):211-217
Previously unknown 3-arylamino-1,2-dihydro-1-isoquinolones were obtained by condensation of 2-cyanomethylbenzoic acid with arylamines. Isonicotinoylation of the compounds was shown to proceed at the carbon atom in the 4-position to give 3-arylamino-4-isonicotinoyl-1,2-dihydro-1-isoquinolones which were quaternized with alkylating agents and formed the corresponding pyridinium salts. Deprotonation of the latter induced intramolecular conjugated addition with the pyrrole ring closure and formation of spiro compounds. The structure of the products was confirmed by NMR, IR and UV spectroscopy and by synthesis of the model compound, 3-(4-tolyl)-2,3,4,5-tetrahydro-1H-pyrrolo[2,3-c]isoquinoline-1,5-dione. 相似文献
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Elena S. Osipova Ekaterina S. Gulyaeva Evgenii I. Gutsul Vladislava A. Kirkina Alexander A. Pavlov Yulia V. Nelyubina Andrea Rossin Maurizio Peruzzini Lina M. Epstein Natalia V. Belkova Oleg A. Filippov Elena S. Shubina 《Chemical science》2021,12(10):3682
The reaction between basic [(PCP)Pd(H)] (PCP = 2,6-(CH2P(t-C4H9)2)2C6H4) and acidic [LWH(CO)3] (L = Cp (1a), Tp (1b); Cp = η5-cyclopentadienyl, Tp = κ3-hydridotris(pyrazolyl)borate) leads to the formation of bimolecular complexes [LW(CO)2(μ-CO)⋯Pd(PCP)] (4a, 4b), which catalyze amine-borane (Me2NHBH3, tBuNH2BH3) dehydrogenation. The combination of variable-temperature (1H, 31P{1H}, 11B NMR and IR) spectroscopies and computational (ωB97XD/def2-TZVP) studies reveal the formation of an η1-borane complex [(PCP)Pd(Me2NHBH3)]+[LW(CO3)]− (5) in the first step, where a BH bond strongly binds palladium and an amine group is hydrogen-bonded to tungsten. The subsequent intracomplex proton transfer is the rate-determining step, followed by an almost barrierless hydride transfer. Bimetallic species 4 are easily regenerated through hydrogen evolution in the reaction between two hydrides.Bimetallic complexes [LW(CO)2(μ-CO)⋯Pd(PCP)] cooperatively activate amine-boranes for their dehydrogenation via N–H proton tunneling at RDS and H2 evolution from two neutral hydrides. 相似文献
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Galina A. Gazieva Yurii B. Vikharev Lada V. Anikina Tatyana B. Karpova Angelina N. Kravchenko Evgenii A. Permyakov Igor V. Svitanko 《Mendeleev Communications》2013,23(4):202-203
Target synthesis of substituted thioglycolurils possessing sedative activity predicted by preliminary 3D-QSAR simulation of bioactive structures has been carried out. 相似文献
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The drive belt set on two pulleys is considered as a plane elastic rod. The nonlinear theory of rods with tension is used. The static frictionless contact problem for the rod is formulated. The derived boundary value problem for the nonlinear ordinary differential equations is solved by the finite difference method and by the shooting method by means of computer mathematics. The belt shape and the stresses are determined. The contact reaction and the contact area are obtained in the solution. A benchmark study of extensible and inextensible models is performed. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献