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2.
Mariano Giaquinta Giuseppe Modica Jiří souček 《Archive for Rational Mechanics and Analysis》1989,106(2):97-159
Summary In this paper we introduce some new classes of functions, among these a class of weak diffeomorphisms. In these classes we prove by direct methods the existence of minimizers for several kinds of variational integrals. In particular, we prove the existence of one-to-one orientation-preserving maps that minimize suitable energies associated with hyperelastic materials. The minimizers are also proved to satisfy equilibrium equations. Finally radial deformations are discussed in connection with cavitation. 相似文献
3.
M. Giaquinta G. Modica J. Souček 《Calculus of Variations and Partial Differential Equations》1994,2(1):65-100
On the ground of four axioms we define thekinematics of perfectly elastic bodies and in particular the notion ofweak deformations of a perfectly elastic body. Weak deformations turn out to agree withweak diffeomorphisms introduced in [10], a class of rectifiable currents which enjoys good closure and compactness properties. Defining thedynamics of perfectly elastic bodies in terms of twoconstitutive conditions on the stored energy function, we can therefore prove existence of stable equilibrium weak deformations for mixed boundary value problems, which moreover satisfy equilibrium and conservation equations.This work has been partially supported by the Ministero dell'Universitá e della Ricerca Scientifica, by C.N.R. contract n. 91.01343.CT01, by the European Research Project GADGET, and by Grant n.11957 of the zech Acad. of Sciences.This article was processed by the author using the LaTEX style filepljour1 from Springer-Verlag. 相似文献
4.
The authors study an example, suggested by E. De Giorgi, of a second-order uniformly elliptic partial differential operator in divergence form with continuous coefficients on a smooth domain in the plane such that the associated harmonic measure on the boundary is not absolutely continuous with respect to the ordinary surface measure. 相似文献
5.
Carlo Mazzocchia Akim Kaddouri Giovanni Modica Roberto Nannicini Guido Audisio Costantino Barbieri Fabio Bertini 《Journal of Analytical and Applied Pyrolysis》2003,70(2):263-276
Pyrolysis of hardware components wastes consisting mainly in computers and television components was performed under nitrogen. The degradation products were separated in three fractions, solid, liquid and gaseous. Analyses of the three phases were carried out using gas chromatography (GC), mass spectrometry (MS), thermal analysis and infrared spectroscopy. The energetic content of the gas phase and the economic value of the liquid phase were also determined. The gas fraction produced was rich in light hydrocarbons and hydrogen. Consequently, its calorific value was high and widely sufficient to make the pyrolysis process self-sustained. The main products of the liquid phase were phenol and isopropylphenol (ca. 50–80 wt.%). The presence of Br-based compounds, deriving from the flame retardant employed in hardware components, were also detected. A controlled combustion of the solid phase permitted to obtain the glass fibres unaltered, which can be recycled. 相似文献
6.
Daniele Mazza Maria Lucco-Borlera Esterina Lepore Silvia Ronchetti 《Journal of Thermal Analysis and Calorimetry》1996,46(6):1625-1632
A calorimetric method is proposed to evaluate the catalytic activity of a solid catalyst with respect to the exothermic oxidation of Volatile Organic Compounds (VOC).This method employs a differential thermal analyzer in which an inert reference and a catalytically active sample are both fluxed at a constant rate with a reactive gaseous mixture composed of an inert gas (N2 90% vol.), oxygen and VOC, the last typically 900 to 5000 ppm. While the temperature is varied according to a predefined cycle, the output signal due to the exothermic reaction on the catalyst is continuously recorded. The design of the test chamber, the amount of catalyst, the shape of the holders and finally the flow rate and composition of the gaseous mixture should be carefully selected in order to achieve reproducible results. 相似文献
7.
8.
Uniform catalytic site in Sn-beta-zeolite determined using X-ray absorption fine structure 总被引:1,自引:0,他引:1
Bare SR Kelly SD Sinkler W Low JJ Modica FS Valencia S Corma A Nemeth LT 《Journal of the American Chemical Society》2005,127(37):12924-12932
The Sn silicate zeolite, Sn-beta, has been shown to be an efficient, selective heterogeneous catalyst for Baeyer-Villiger oxidations. Using primarily a multishell fit to extended X-ray absorption fine structure (EXAFS) data, we show that the Sn does not randomly insert into the beta-zeolite structure but rather occupies identical, specific, crystallographic sites. These sites are the T5/T6 sites in the six-membered rings. Moreover, the Sn is substituted in pairs on opposite sides of these six-membered rings. We believe that it is the specific, uniform crystallographic location of the Sn in the beta crystal structure that leads to sites with uniform catalytic activity, and consequently to the high chemical selectivity demonstrated for this catalyst. This manifests itself in the almost enzyme-like selectivity of this catalyst in Baeyer-Villiger oxidations. This uniform site distribution of the Sn suggests that there is likely a symbiotic relationship between the structure-directing agent in the zeolite synthesis and the Sn heteroatoms during the framework formation. 相似文献
9.
Aurora Modica Marco Di Bella Maria Francesca Alberghina Maria Brai Dorotea Fontana 《Natural product research》2019,33(7):987-996
AbstractThe subject of this present work is a group of nine historical pictures shot in Palermo by the Sicilian photographer E. Interguglielmi in 1912. They are nine matte-collodion prints mounted on the original cardboard supports and all of them show foxing stains affecting the paper surface. In order to characterise the chemical composition of the supports and investigate foxing spots, non-destructive and micro-destructive analysis were carried out. X-rays fluorescence (XRF) analysis was used to characterise the elemental composition of all the mounting boards, allowing a comparison between the foxing spots and non-affected areas. Laser-Induced Breakdown Spectroscopy was used to investigate the presence of lower atomic number elements, not detectable by XRF, while SEM imaging allowed the investigation of surface appearance and nature of original paper samples from the cardboards. 相似文献
10.
Hall WP Anker JN Lin Y Modica J Mrksich M Van Duyne RP 《Journal of the American Chemical Society》2008,130(18):5836-5837
A plasmonic switch based on the calcium-induced conformational changes of calmodulin is shown to exhibit reversible wavelength modulations in response to changing calcium concentration. The extinction maximum (lambdamax) of a localized surface plasmon resonance (LSPR) sensor functionalized with a novel calmodulin construct, cutinase-calmodulin-cutinase (CutCaMCut), reversibly shifts by 2-3 nm. A high-resolution (HR) LSPR spectrometer with a wavelength resolution (3sigma) of 1.5 x 10-2 nm was developed to detect these wavelength modulations in real-time, providing information about the dynamics and structure of the protein. The rate of conversion from open (Ca2+-bound) to closed (Ca2+-free) calmodulin is shown to be 4-fold faster than the reverse process, with a closing rate of 0.127 s-1 and opening rate of 0.034 s-1. As far as we are aware, this plasmonic switch marks the first use of LSPR spectroscopy to detect reversible conformational changes in an unlabeled protein. 相似文献