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1.
Summary High-purity indium was analysed by spark source mass spectrometry, using electrical and photoplate detection. For the calibration of the differences in elemental sensitivity, a standard sample was prepared in which 10 impurities were determined by graphite furnace atomic absorption spectrometry. In this way accuracies of less than 40% were obtained for relatively homogeneous elements at ppm and sub-ppm level. About 40 elements could be determined with detection limits of 10 to 30 ppb. Two pattern recognition methods, principal component analysis and clustering analysis, were applied to obtain information on trace element distribution, which indicated that a number of elements were strongly spatially correlated in the analysed sample.
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
Chemische Analyse und Verteilungsbestimmung von Spurenelementen in Indium-Matrix durch Funkenquellen-Massenspektrometrie
On leave from: Department of Chemistry, Nanjing Normal University, Nanjing, People's Republic of China 相似文献
2.
The use of monoenergetic exciting radiation of molybdenum obtained with a secondary target set-up, a conventional water-cooled tungsten anode x-ray tube and a Si(Li) semiconductor detector permits many trace and minor constituents from chlorine to strontium to be determined in particulate material collected on cellulose filters. The method is rapid and economical compared to other multielement techniques. The use of one or more single-element thin-film standards to calibrate for the analysis of many elements appears to be possible, but some systematic errors must be prevented. Absorption of the fluorescent radiation is remedied by a simple correction method. The precision and the accuracy of the method were critically examined by independent analysis of a number of samples with instrumental neutron activation analysis and by interlaboratory comparisons on the same samples. 相似文献
3.
The implementation of an expert system for the automated qualitative interpretation of energy-dispersive x-ray spectra is discussed. The first step in the interpretation process is the extraction of the relevant data from the spectrum, which is done by a preprocessor program, written in FORTRAN. The expert system itself consists of three parts. The knowledge base contains specific information on energy-dispersive x-ray fluorescence spectrometry presented in the form of IF/THEN rules. The data base contains the reduced spectral data and an array of certainty factors associated with each element; the certainty factor for an element represents the probability of its being present in the sample from which the spectrum was taken. Finally, the inference engine performs manipulation of the knowledge. For a particular state of the data base, the certainty factors for all the elements are iteratively modified until convergence is reached by using the rules from the knowledge base. During each cycle, the inference engine selects one rule from the knowledge base and executes it. Rules are selected on the basis of the chemical elements contained in their IF part and according to their previously assigned focus levels. Execution of the THEN part of the selected rule modifies the certainty factors of a number of elements. At the end of the interpretation session, the system lists the elements which have a high probability of being present in the sample. Optionally, the user can be provided with explanations of the reasoning steps taken during the interpretation. Application of the expert system to a particular spectrum shows that it is useful for the reliable interpretation of spectral data obtained from electron microprobe analysis of industrial aerosol particles. 相似文献
4.
Molander P Haugland K Hegna DR Ommundsen E Lundanes E Greibrokk T 《Journal of chromatography. A》1999,864(1):103-109
Sub-ambient column temperatures, promoting strong interactions between the analyte and the stationary phase material, were utilized to focus large volumes of the polyolefin antioxidant Irganox 1076 [benzenepropanoic acid, 3.5-bis(1,1-dimethylethyl)-4-hydroxy-, octadecyl ester] on the column inlet, using pure acetonitrile as sample solvent and mobile phase. Injection volumes up to 100 microl were successfully employed on a 50 cm x 320 microm I.D. capillary column packed with 5 microm Kromasil 100 ODS particles. Irganox 1076 was eluted after completed injection by temperature programming, using a temperature program from 7 to 90 degrees C, in 3 degrees C min(-1). UV detection, using a low-dispersion "U"-shaped flowcell, was performed at 280 nm. The method was applied for the determination of Irganox 1076 that was extracted from low-density polyethylene (0.6 ppm, w/w). Both Soxhlet and microwave-aided solvent extractions were performed, using chloroform and acetonitrile as solvents, respectively. The microwave-aided extraction with acetonitrile was found to give approximately the same yield as the standard Soxhlet reference method. Consequently, small volumes of acetonitrile could be used both as extraction solvent, sample solvent and mobile phase, simplifying the analysis process. The mass limit of detection of the method was found to be 3.3 ng, corresponding to a concentration limit of detection of 33 ng ml(-1), utilizing an injection volume of 100 microl. The within and between day precision of retention times displayed relative standard deviations below 1.2%. 相似文献
5.
Three categories of tea, black, green and oolong tea, with those varieties in each category were analyzed for their contents of cellulose, hemicellulose, lignin, polyphenols, caffeine and amino acids. The data were subjected to multivarige analysis. Principal component analysis and principal component classification provide discrimination between the different categories and varieties. The quality index, assigned to these tea standards by experts, could be predicted form the principal component scores. 相似文献
6.
Problems in the use of x-ray spectrometry for the fast multi-element analysis of environmental samples such as aerosols collected on filters arise from absorption of the fluorescence intensity in the filter and in the collected matter. A procedure is described for the determination of the elements sulphur to calcium in aerosols collected on Whatman 41 filters. Two methods are compared for deconvolution of the spectra. These are based on counting in fixed energy channels or on non-linear least-squares analysis. Corrections for absorption effects have been calculated. Calibration is done with thin film standard deposits. The accuracy of the method is better than 15%. Difficulties in ascertaining the chlorine content of the filter are discussed. The evaporation of the chlorine fraction from the filter was studied in detail. 相似文献
7.
Eva C. Sonnenschein Marc Stierhof Stephan Goralczyk Floriane M. Vabre Leonie Pellissier Kine Østnes Hanssen Mercedes de la Cruz Caridad Díaz Peter de Witte Daniëlle Copmans Jeanette Hammer Andersen Espen Hansen Venke Kristoffersen José R. Tormo Rainer Ebel Bruce F. Milne Hai Deng Lone Gram Jioji N. Tabudravu 《Tetrahedron》2017,73(18):2633-2637
A new siderophore containing a 4,5-dihydroimidazole moiety was isolated from Pseudoalteromonas piscicida S2040 together with myxochelins A and B, alteramide A and its cycloaddition product, and bromo- and dibromoalterochromides. The structure of pseudochelin A was established by spectroscopic techniques including 2D NMR and MS/MS fragmentation data. In bioassays selected fractions of the crude extract of S2040 inhibited the opportunistic pathogen Pseudomonas aeruginosa. Pseudochelin A displayed siderophore activity in the chrome azurol S assay at concentrations higher than 50 μM, and showed weak activity against the fungus Aspergillus fumigatus, but did not display antibacterial, anti-inflammatory or anticonvulsant activity. 相似文献
8.
Friis Helmer André Pedersen Janne Jettestuen Espen Helland Johan Olav Prodanović Maša 《Transport in Porous Media》2019,128(1):123-151
Transport in Porous Media - Multiphase flow simulations on imaged porous rock structures require numerical methods that are accurate and robust when applied on complex geometries. A key element in... 相似文献
9.
Fred Espen Benth 《Applied Mathematical Finance》2018,25(1):36-65
The recent introduction of wind power futures written on the German wind power production index has brought with it new interesting challenges in terms of modelling and pricing. Some particularities of this product are the strong seasonal component embedded in the underlying, the fact that the wind index is bounded from both above and below and also that the futures are settled against a synthetically generated spot index. Here, we consider the non-Gaussian Ornstein–Uhlenbeck type processes proposed by Barndorff-Nielsen and Shephard in the context of modelling the wind power production index. We discuss the properties of the model and estimation of the model parameters. Further, the model allows for an analytical formula for pricing wind power futures. We provide an empirical study, where the model is calibrated to 37 years of German wind power production index that is synthetically generated assuming a constant level of installed capacity. Also, based on 1 year of observed prices for wind power futures with different delivery periods, we study the market price of risk. Generally, we find a negative risk premium whose magnitude decreases as the length of the delivery period increases. To further demonstrate the benefits of our proposed model, we address the pricing of European options written on wind power futures, which can be achieved through Fourier techniques. 相似文献
10.
W. Van Borm P. Van Espen F. Adams M. Demuynck 《International journal of environmental analytical chemistry》2013,93(2-4):165-182
Abstract A methodology is described for the apportionment of zinc-containing particulate matter sampled in the vicinity of a zinc smelter to their corresponding sources in the factory. Bulk samples of particulate matter from six potential emission sources were analysed by automated electron probe microanalysis (EPMA) in order to characterize the individual particles. Based on a data set of relative peak intensities and with the aid of a binary clustering method, the most important particle classes were identified. They were used as a basis for the development of a set of disjunct identification rules (decision rules), which were able to describe the classes in a unique manner. Applying these rules upon ambient particulate data enabled the estimation of relative contributions of different types of zinc-containing particles. Evidence was found that a large number of particles was modified by a soil component or by gas phase reactions. 相似文献