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John W. Tolan Philip Eskola David W. Fink Helmut Mrozik Laurie A. Zimmerman 《Journal of chromatography. A》1980,190(2)
An analytical method is described for the determination of the avermectins in plasma based upon high-performance liquid chromatography of flourescent derivatives of these compounds. The analyte is isolated by adsorption chromatography on Florisil, dehydrated in an acetic anhydride-pyridine mixture, and the fluorophore is further separated by chromatorgraphy on silica gel in advance of introduction into a reversed-phase system. This method, which can be applied to samples containing as little as 0.2 ng drug per ml, has an accuracy of 5% mean relative error and a precision of 8% relative standard deviation. A study and discussion of several factors which affect the analytical reaction are included. 相似文献
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4″,5-Bis-O-(-butyldimethylsilyloxyacetyl)-23-O-(4-methylphenyloxythiocarbonyl)avermectin B2a gave on pyrolysis and deprotection avermectin Bla, while reduction with tri-n-butyltin hydride followed by deprotection afforded 22,23-dihydroavermectin Bla (ivermectin). 相似文献
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M. Leino J. Uusitalo T. Enqvist K. Eskola A. Jokinen K. Loberg W. H. Trzaska J. Äystö 《Zeitschrift für Physik A Hadrons and Nuclei》1994,348(2):151-152
Two new neutron-deficient isotopes207,208Ac have been produced in fusion reactions with 5.2–5.6 MeV/nucleon40Ar ions on175Lu and identified on the basis of genetic correlations. The fusion evaporation products were separated on-line using a gas-filled magnetic recoil separator. The alpha energy and half-life of208Ac were determined to be (7572±15) keV and (95 ?16 +24 ) ms, respectively. A new alpha line with a half-life of (25 ?5 +9 ) ms and an energy of (7758±20) keV is assigned to the decay of an isomeric state in208Ac. Another new activity with a half-life of (22 ?9 +40 ) ms and an alpha energy of (7712±25) keV is assigned to207Ac. 相似文献
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M. Leino J. Uusitalo R. G. Allatt P. Armbruster T. Enqvist K. Eskola S. Hofmann S. Hurskanen A. Jokinen V. Ninov R. D. Page W. H. Trzaska 《Zeitschrift für Physik A Hadrons and Nuclei》1996,355(1):157-164
Neutron-deficient isotopes of radium have been produced in the reactions35Cl+175Lu,40Ar+170,171Yb, and36Ar+170,171Yb and separated in-flight with a gas-filled recoil separator. The activities have been identified on the basis of correlated alpha decay chains. The alpha particle energy Eα and the half-life T1/2 of an isomeric state of the new isotope,203m Ra, have been determined to be (7615±20) keV and (33 ?10 +22 ) ms, respectively. An assignment of another decay with Eα = (7577±20) keV and T1/2=(1.1 ?0.5 +5.0 ) ms to203g Ra is made on the basis of one observed three-decay chain. Tentative evidence for the production of the new isotope202Ra is also given. The values Eα = (7860±60) keV and T1/2=(0.7 ?0.3 +3.3 ) ms were measured. Improved decay data have been obtained for204Ra. The results are Eα = (7484±10) keV and T1/2=(59 ?9 +12 ) ms. Earlier findings concerning the decay of two states in205Ra and an isomer in207Ra have been confirmed. Approximate values for cross sections have been determined for202Ra, produced using the36Ar+170Yb reaction and for203Ra,204Ra, and205Ra using the35Cl+175Lu reaction. The results are 2 nb (202Ra), 4 nb (203Ra), 40 nb (204Ra), and 800 nb (205Ra). 相似文献
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Markus Håkansson Johanna Suomi Mauri Nauma Jouko Kankare Jarkko U. Eskola 《Analytica chimica acta》2006,556(2):450-454
Double insulating barrier tunnel emission electrodes were fabricated by adding a new pure aluminum layer upon oxidized aluminum electrodes by vacuum evaporation and thermally oxidizing the new aluminum layer in air at room temperature. Resulting Al/Al2O3/Al/Al2O3 electrodes allow the use of various aluminum alloys in the electrode body necessary for hardness or shaping ability of the electrode while obtaining the luminescence properties of pure aluminum oxide. During electrical excitation of luminescent labels by cathodic hot electron injection into aqueous electrolyte solution, the background noise is mainly based on high-field-induced solid-state electroluminescence and F-center luminescence of the outer aluminum oxide film. The more defect states and/or impurity centers the outer oxide film contains, the higher is the background emission intensity. The present electrode fabrication method provides a considerable improvement in signal-to-noise ratio for time-resolved electrochemiluminescence (TR-ECL) measurements when the original native oxide film of the electrode body contains luminescence centers displaying long-lived luminescence. The excellent performance of the present electrodes is demonstrated by extremely low-level detection of Tb(III) chelates, luminol, Pt(II) coproporphyrin and Tb(III) labels in an immunometric immunoassay by time-resolved electrochemiluminescence. 相似文献
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