Secondary ion yields produced by keV atomic and polyatomic ion impacts on a self-assembled monolayer surface

A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd.     

Distance matrices for points on a line,on a circle,and at the vertices of ann-dimensional cube

Forn pointsA _i ,i=1, 2, ...,n, in Euclidean space ℝ ^m , the distance matrix is defined as a matrix of the form D=(D _i ,j) _i ,j=1,...,n, where theD _i ,j are the distances between the pointsA _i andA _j . Two configurations of pointsA _i ,i=1, 2,...,n, are considered. These are the configurations of points all lying on a circle or on a line and of points at the vertices of anm-dimensional cube. In the first case, the inverse matrix is obtained in explicit form. In the second case, it is shown that the complete set of eigenvectors is composed of the columns of the Hadamard matrix of appropriate order. Using the fact that distance matrices in Euclidean space are nondegenerate, several inequalities are derived for solving the system of linear equations whose matrix is a given distance matrix. Translated fromMatematicheskie Zametki, Vol. 58, No. 1, pp. 127–138, July, 1995.