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1.
Polycarbonates and copolycarbonates based on BPSi and BPA were easily made using the standard interfacial technique. Molecular weight and NMR data indicate that up to 4 mol % of the BPSi decomposes during polymerization via a base-catalyzed rearrangement of BPSi to arylsiloxanes. Oxygen index studies show an increased flame resistance with increasing BPSi monomer content. DSC measurements show a decrease in glass transition with BPSi monomer concentration while TGA shows an increase in char residue with BPSi monomer content. In addition, TGA indicates no change in either thermal or thermooxidative stability with the relative BPSi/BPA concentrations. Outdoor weathering of BPSi PC and BPA PC films indicates that BPSi PC is ca. 5 times more weathering resistant than BPA PC. This latter result can be attributed to a combination of BPSi PC's lower UV absorptivity, higher water repellency, and lower likelihood for side chain photooxidation. © 1993 John Wiley & Sons, Inc. 相似文献
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Charles E. Carraher JR. 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(8):1293-1356
This review emphasizes the breadth of metallic and metallic-like polymers evaluated as to thermal properties. Techniques usefully applied to particular systems are noted with the aim of suggesting their application to other systems. 相似文献
4.
Multireference configuration interaction (MRCI) and complete active space second-order perturbation theory (CASPT2) calculations are performed on Fe2 and Fe? 2. Although it is not possible to definitively identify the ground states of Fe2 and Fe? 2, the calculations suggest that the ground state of Fe? 2 in 8Σ? u derived from 3d134σ2 g4σ2 u and that the states observed in photodetachment are the 9Σ? g and 7Σ? g states with a 3d134σ2 g4σ1 u occupation, but that the ground state of Fe2 is 7Δu(3d144σ2 g) and is not observed in the photo-detachment spectra. 相似文献
5.
Standardized electronic formats for data are needed to efficiently and transparently communicate the results of scientific studies. A format for the unique identification of chemical species is a requirement in the field of chemistry, and the IUPAC International Chemical Identifier (InChI) has been widely adopted for this purpose. The InChI identifier has proved to be very useful. The InChI identifier, however, is currently insufficient to uniquely specify some types of molecular entities at a detailed molecular level needed to fully characterize their chemical nature, to differentiate between chemically distinct conformers, to uniquely identify structures used in quantum chemical calculations, and to completely describe elementary chemical reactions. To address this limitation, we propose an augmented form of InChI, denoted as InChI–ER, which contains additional optional layers that allow the unique and unambiguous identification of molecules at a detailed molecular level. The new layers proposed herein are optional extensions of the existing InChI formalism and, like all other InChI layers, would not interfere with InChI identifiers currently in use. The focus of the present work is the better specification of required molecular entities such as rotational conformations, ring conformations, and electronic states. In companion articles, we propose additional reaction layers using an extended InChI format that will enable the unique identification of elementary chemical reactions, including specification of associated transition states, specification of the changes in bonds that occur during reaction, and classification of reaction types. 相似文献
6.
Miklos Guttman David D. Weis John R. Engen Kelly K. Lee 《Journal of the American Society for Mass Spectrometry》2013,24(12):1906-1912
Noisy and overlapped mass spectrometry data hinder the sequence coverage that can be obtained from hydrogen deuterium exchange analysis, and places a limit on the complexity of the samples that can be studied by this technique. Advances in instrumentation have addressed these limits, but as the complexity of the biological samples under investigation increases, these problems are re-encountered. Here we describe the use of binomial distribution fitting with asymmetric linear squares regression for calculating the accurate deuterium content for mass envelopes of low signal or that contain significant overlap. The approach is demonstrated with a test data set of HIV Env gp140 wherein inclusion of the new analysis regime resulted in obtaining exchange data for 42 additional peptides, improving the sequence coverage by 11 %. At the same time, the precision of deuterium uptake measurements was improved for nearly every peptide examined. The improved processing algorithms also provide an efficient method for deconvolution of bimodal mass envelopes and EX1 kinetic signatures. All these functions and visualization tools have been implemented in the new version of the freely available software, HX-Express v2. Figure
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7.
Magnetic properties and magneto-optical spectroscopy of Heusler alloys based on transition metals and Sn 总被引:1,自引:0,他引:1
The formation and magnetic properties of Heusler compounds of the general formula X2YSn were studied, where X represents a 3d transition metal or Cu and where Y represents a second 3d transition metal or a metal of group IV A, VA and VI A of the periodic table. The lattice constant was determined for all Heusler compounds studied. The Co moment in the Co2YSn compounds was not found to scale in a sample manner to the electronegativity difference E φ* between Co and the Y components as was previously observed in the series Co2YAl and Co2YGa. All compounds of the type Ni2YSn were found to be Pauli paramagnetic when Y is non-magnetic metal. Compounds having a Curie temperature above room temperature were investigated by means of magneto-optical polar Kerr-effect spectroscopy. Experimental indications were obtained for charge transfer transitions in the series Co2TiSn, Co2HfSn. 相似文献
8.
Alves GA Amato S Anjos JC Appel JA Astorga J Bracker SB Cremaldi LM Dagenhart WD Darling CL Dixon RL Errede D Fenker HC Gay C Green DR Jedicke R Karchin PE Kennedy C Kwan S Lueking LH de Mello Neto JR Metheny J Milburn RH de Miranda JM da Motta Filho H Napier A Passmore D Rafatian A dos Reis AC Ross WR Santoro AF Sheaff M Souza MH Spalding WJ Stoughton C Streetman ME Summers DJ Takach SF Wallace A Wu Z 《Physical review letters》1996,77(12):2388-2391
9.
OPTIMAL FISH HARVESTING FOR A POPULATION MODELED BY A NONLINEAR PARABOLIC PARTIAL DIFFERENTIAL EQUATION 下载免费PDF全文
As the human population continues to grow, there is a need for better management of our natural resources in order for our planet to be able to produce enough to sustain us. One important resource we must consider is marine fish populations. We use the tool of optimal control to investigate harvesting strategies for maximizing yield of a fish population in a heterogeneous, finite domain. We determine whether these solutions include no‐take marine reserves as part of the optimal solution. The fishery stock is modeled using a nonlinear, parabolic partial differential equation with logistic growth, movement by diffusion and advection, and with Robin boundary conditions. The objective for the problem is to find the harvest rate that maximizes the discounted yield. Optimal harvesting strategies are found numerically. 相似文献
10.
The fractionation technique described in this paper was used to characterize the melting-point, monomer, and blocking distributions for polymers and copolymers. It is different from the molecular-weight fractionation technique in that the fractions are obtained by using a single solvent to extract the solid polymer below its melting point at stepwise-increasing temperatures. The reproducibility of this technique is excellent, and the technique is sufficient to distinguish pellet-to-pellet variation in a commercially available polypropylene. It was used to show the influence of preparation variables on the melting-point distributions of polyethylene and polypropylene and on the monomer and blocking distribution of copolymers, and to distinguish copolymers from blends. 相似文献