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1.
The Stokes eigenmodes in the square are numerically determined and their symmetry properties are identified. The spectra evolution laws are in excellent qualitative agreement with the theoretical asymptotic predictions proposed by Constantin and Foias (in “Navier–Stokes equations”, University of Chicago Press, 1988),
. The slopes are reported here and are found to be specific to the eigenmodes symmetry family. The dynamic equilibria are analyzed and show a linear relationship between the vorticity and the stream function in the core of the eigenmodes. These features of the Stokes eigenmodes confined in the square are shared by the fully periodic Stokes eigenmodes. 相似文献
2.
Kanibolotsky A Roquet S Cariou M Leriche P Turrin CO de Bettignies R Caminade AM Majoral JP Khodorkovsky V Gorgues A 《Organic letters》2004,6(13):2109-2112
[structure: see text] In four new dendrimers terminated by 12 electroactive tetrathiafulvalenyl substituents, the tridimensional character of the inter- and intradendrimeric charge and electron transfer, and hence of the electroconductivity, is evidenced by examination of the electronic spectra of their corresponding neutral state and cation radical, dication, and mixed-valence salts, including a closed-shell anion. 相似文献
3.
Ludivine Louise‐Leriche Emilia Pǎunescu Géraldine Saint‐André Rachid Baati Anthony Romieu Alain Wagner Pierre‐Yves Renard 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(11):3510-3523
A new pro‐fluorescent probe aimed at a HTS assay of scavengers is able to selectively and efficiently cleave the P? S bond of organophosphorus nerve agents and by this provides non‐toxic phosphonic acid has been designed and synthesised. The previously described pro‐fluorescent probes were based on a conventional activated P? Oaryl bond cleavage, whereas our approach uses a self‐immolative linker strategy that allows the detection of phosphonothioase activity with respect to a non‐activated P? Salkyl bond. Further, we have also developed and optimised a high‐throughput screening assay for the selection of decontaminants (chemical or biochemical scavengers) that could efficiently hydrolyse highly toxic V ‐type nerve agents. A preliminary screening, realised on a small α‐nucleophile library, allowed us to identify some preliminary “hits”, among which pyridinealdoximes, α‐oxo oximes, hydroxamic acids and, less active but more original, amidoximes were the most promising. Their selective phosphonothioase activity has been further confirmed by using PhX as the substrate, and thus they offer new perspectives for the synthesis of more potent V nerve agent scavengers. 相似文献
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Emilie RipaudCharlotte Mallet Magali AllainPhilippe Leriche Pierre FrèreJean Roncali 《Tetrahedron letters》2011,52(49):6573-6577
Two triphenylamine derivatives bearing terminal perfluorophenyl groups have been synthesized. Their HOMO, LUMO levels and electronic band gap have been evaluated by spectroscopic and electrochemical measurements and rationalized with theoretical calculations. X-ray structure analysis of crystals allowed the observation of multiple intermolecular interactions due to the presence of the perfluorophenyl pendant groups. The multiplication of these interactions explains the differences between calculated (in gas phase) and observed (in solid states) structures. 相似文献
6.
Unger EL Morandeira A Persson M Zietz B Ripaud E Leriche P Roncali J Hagfeldt A Boschloo G 《Physical chemistry chemical physics : PCCP》2011,13(45):20172-20177
The hole transporting medium in solid-state dye-sensitized solar cells can be utilized to harvest sunlight. Herein we demonstrate that a triphenylamine-based dye, used as hole-transporting medium, contributes to the photocurrent in a squaraine-sensitized solid-state dye-sensitized solar cell. Steady-state photoluminescence measurements have been used to distinguish between electron transfer and energy transfer processes leading to energy conversion upon light absorption in the hole-transporting dye. 相似文献
7.
Takaoki Koyanagi Dr. Geoffray Leriche Alvin Yep David Onofrei Prof. Gregory P. Holland Prof. Michael Mayer Prof. Jerry Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(24):8074-8077
This paper examines the effects of four different polar headgroups on small‐ion membrane permeability from liposomes comprised of Archaea‐inspired glycerolmonoalkyl glycerol tetraether (GMGT) lipids. We found that the membrane‐leakage rate across GMGT lipid membranes varied by a factor of ≤1.6 as a function of headgroup structure. However, the leakage rates of small ions across membranes comprised of commercial bilayer‐forming 1‐palmitoyl‐2‐oleoyl‐sn‐glycerol (PO) lipids varied by as much as 32‐fold within the same series of headgroups. These results demonstrate that membrane leakage from GMGT lipids is less influenced by headgroup structure, making it possible to tailor the structure of the polar headgroups on GMGT lipids while retaining predictable leakage properties of membranes comprised of these tethered lipids. 相似文献
8.
The unsteady dynamics of the Stokes flows, where
, is shown to verify the vector potential–vorticity (
) correlation
, where the field
is the pressure-gradient vector potential defined by
. This correlation is analyzed for the Stokes eigenmodes,
, subjected to no-slip boundary conditions on any two-dimensional (2D) closed contour or three-dimensional (3D) surface. It is established that an asymptotic linear relationship appears, verified in the core part of the domain, between the vector potential and vorticity,
, where
is a constant offset field, possibly zero. 相似文献
9.
Cravino A Roquet S Leriche P Alévêque O Frère P Roncali J 《Chemical communications (Cambridge, England)》2006,(13):1416-1418
Introduction of dicyanovinyl groups on a triphenylamine-based conjugated system leads to an intramolecular charge transfer which extends the spectral response and raises the open-circuit voltage of the resulting hetero-junction solar cells. 相似文献
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