Synthesis and thermolysis of the 2,3‐dihydro‐1H‐pyrole‐2,3‐diones,pseudopericyclic reactions of formyl(N‐phenylimidoyl)ketene: Experimental data and PM3 calculations

The reactions of the 2,3‐dihydro‐1H‐furan‐2,3‐dione 1 with Schiff bases 2a‐f at 60–70°C furnish the corresponding 2,3‐dihydro‐1H‐pyrole‐2,3‐diones 3a‐f . The heating of 3a‐d afforded the corresponding 4‐methoxybenzoyl(N‐arylimidoyl)k:etenes 4a‐d as intermediates which undergo a very facile cyclization to quinoline‐4‐ones 5a‐d . According to our PM3 calculations, fragmentation of 4‐formyl‐2,3‐dihydro‐1H‐pyrole‐2,3‐dione and 1,4‐cyclization of formyl(N‐phenylimidoyl)k:etene IN1 to azetin‐2‐one IN2 and oxe‐tone IN3 are pseudopericyclic reactions with two orbital connections, proceed via planar transition structures. Due to to the possibility of syn and anti conformations of the imine phenyl, there are eight E/Z‐iso‐mers of IN1 . In addition, we have also calculated reaction mechanism of formation of quinoline‐4‐ones by the PM3 method.     

Preparation and characterization of Co(II), Ni(II) and Cu(II) complexes of a ligand containing 1,3,4-thiadiazole groups

(1R,2R)-1,2-bis-(5-amino-1,3,4-thiadiazole-2-yl)ethane-1,2-diol (L) has been prepared by the reaction of thiosemicarbazide with (2R,3R)-(+)-tartaric acid (I) and phosphorous oxychloride, and its complexes with Co(II), Ni(II) and Cu(II) have been obtained. The structures of the ligand and its complexes have been established by i. r., ¹H- and ¹³C-n.m.r. spectra, u.v.–vis–nir spectroscopy, elemental analyses, T.g.-D.t.a. and magnetic susceptibility measurements.     

Hydrophobic cryogels for DNA adsorption: Effect of embedding of monosize microbeads into cryogel network on their adsorptive performances

As alternative hydrophobic adsorbent for DNA adsorption, supermacroporous cryogel disks were synthesized via free radical polymerization. In this study, we have prepared two kinds of cryogel disks: (i) poly(2‐hydroxyethyl methacrylate‐N‐methacryloyl‐l ‐tryptophan) [p(HEMA‐MATrp)] cryogel containing specific hydrophobic ligand MATrp; and (ii) monosize p(HEMA‐MATrp) particles synthesized via suspension polymerization embedded into p(HEMA) cryogel structure to obtain p(HEMA‐MATrp)/p(HEMA) composite cryogel disks. These cryogel disks containing hydrophobic functional group were characterized via swelling studies, Fourier transform infrared spectroscopy, elemental analysis, surface area measurements and scanning electron microscopy. DNA adsorption onto both p(HEMA‐MATrp) cryogel and p(HEMA‐MATrp)/p(HEMA) composite cryogels was investigated. Maximum adsorption of DNA on p(HEMA‐MATrp) cryogel was found to be 15 mg/g polymer. Otherwise, p(HEMA‐MATrp)/p(HEMA) composite cryogels significantly increased the DNA adsorption capacity to 38 mg/g polymer. Composite cryogels could be used repeatedly without significant loss on adsorption capacity after 10 repetitive adsorption–desorption cycles. Copyright © 2013 John Wiley & Sons, Ltd.     

New analytical expressions,symmetry relations and numerical solutions for the rotational overlap integrals

In this article, extremely simple analytical formulas are obtained for rotational overlap integrals which occur in integrals over two reduced rotation matrix elements. The analytical derivations are based on the properties of the Jacobi polynomials and beta functions. Numerical results and special values for rotational overlap integrals are obtained by using symmetry properties and recurrence relationships for reduced rotation matrix elements. The final results are of surprisingly simple structures and very useful for practical applications. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2012