排序方式: 共有52条查询结果,搜索用时 31 毫秒
1.
I. A. Uspenskaya Z. S. Vakhovskaya M. M. Efremova M. L. Kovba A. L. Emelina Zh. V. Dobrokhotova Yu. V. Goryushkina L. A. Tiflova A. A. Popova A. S. Monaenkova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(4):529-534
The thermodynamic properties of the Ln2BaO4 phases (Ln = Dy, Ho, Sm) were studied by the electromotive force method with a fluoride electrolyte (890–1180 K), solution calorimetry in 1.07 N hydrochloric acid at 298.15 K, and differential scanning calorimetry (298–860 K). The experimental data were jointly processed, and the thermodynamic functions of the compounds over the temperature range 298–1200 K were calculated. 相似文献
2.
Russian Journal of Organic Chemistry - 相似文献
3.
R. O. Grishchenko A. L. Emelina 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(1):1-5
A pure phase of monosodium aluminate hydrate Na2O · Al2O3 · 2.5H2O (MAH) is synthesized and characterized by means of XRD, IR, SEM, TGA, and DSC. The heat capacity of the compound is measured in the temperature range of ?100 to 100°C, and the thermal contributions to enthalpy and entropy are calculated. The standard entropy, enthalpy, and Gibbs energy of formation of MAH at 298 K are estimated. 相似文献
4.
Electrocatalytic properties of platinum metal electrodes and their dependence on nitrogen- and sulfur-containing additives to electrolyte are studied by an X
discrete variation method. It is shown that rhodium catalysts are the most promising, while iridium is unsuitable for the synthesis of percompounds. 相似文献
5.
R. N. Gadel’shin A. D. Khusainov Yu. N. Khakimullin R. S. Davletbaev O. Yu. Emelina I. M. Davletbaeva 《Russian Journal of Applied Chemistry》2013,86(9):1430-1434
A modifying effect of amino esters of boric acid on polydimethyl/methylvinyl siloxane caoutchouc and resin based on them was studied. It is shown that small amount of this type of modifying agent leads to a marked increase in viscosity of the compositions, and improved mechanical and thermal properties of the vulcanizates. With increasing the amount of the modifying agent they begin to show properties of a plasticizer. 相似文献
6.
I. M. Davletbaeva V. F. Shkodich A. M. Gumerov O. Yu. Emelina A. V. Naumov 《Polymer Science Series A》2010,52(4):392-397
The interaction of 2,4-toluylene diisocyanate with open-chain analogs of crown ethers containing potassium alcoholate groups
is studied, and the mechanism of stabilization of the formed O-polyisocyanate end units via intermolecular interactions is proposed. The electron delocalization in intermolecular cyclic
structures may be responsible for electron-transfer processes in the polymers under study. 相似文献
7.
Anna Polishchuk Tatyna Emelina Emilya Karaseva Oana Cramariuc Vladimir Chukharev Vladimir Karasev 《Photochemistry and photobiology》2014,90(1):79-84
The effect of intermolecular proton transfer on the spectral properties of levofloxacin in the ground and excited electronic states was studied. The preferred direction of possible protolytic reactions induced by UV irradiation in this compound was studied. It was found that the proton transfer processes have a considerable effect on the capability of the compound to emit light and occur on the nanosecond timescale. The photochemical reactions of the tree forms of levofloxacin (pH: 4.0, 7.0, 10.0) were studied by laser flash photolysis and product studies. Irradiation at pH 4 yielded a pulse and transient (λmax = 395, 515, 575 nm) assigned to the protonated triplet. Irradiation at pH 7 yielded a transient species (λmax = 525, 610 nm) assigned to the neutral form. Protonation of the anionic singlet excited state was also observed (λmax = 440, 570, 680 nm). 相似文献
8.
E. S. Tkachenko A. I. Druzhinina N. V. Avramenko R. M. Varushchenko A. L. Emelina I. A. Nesterov T. N. Nesterova 《Moscow University Chemistry Bulletin》2011,66(5):282-289
The heat capacity of 4,4′-dinitrodiphenyl ether and 4-nitro-4′-biphenylcarboxylic acid were measured by adiabatic calorimetry
(AC) in temperature ranges of 8–372 K and 10–372 K, respectively. The heat capacity of 4,4′-dinitrodiphenyl ether in the temperature
range 323–500 K, the thermodynamic properties of fusion, and the purity of the ether were measured by differential scanning
calorimetry (DSC). The main thermodynamic functions in the temperature range 5–370 K were calculated for both compounds using
the heat capacities of adiabatic calorimetry. Related thermodynamic functions of 4,4′-dinitrodiphenyl ether in the temperature
range 370–500 K were calculated on the basis of DSC data. 相似文献
9.
M. L. Kovba A. L. Emelina M. M. Batuk V. V. Sorokin 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2011,85(9):1533-1539
Thermodynamic properties of rare-earth Ln2CuO4 (Ln = Nd, Sm, Eu), Ho2Cu2O5 and Ln2BaCuO5 (Ln = Nd, Sm, Eu, Ho, Yb) cuprates were determined using the electromotive force method with a fluorine-ion electrolyte in
the temperature interval of 1000–1230 K. The thermodynamic data obtained by different experimental methods were compared. 相似文献
10.
E. V. Orlova A. E. Goldberg M. A. Kiskin P. S. Koroteev A. L. Emelina M. A. Bykov G. G. Aleksandrov Zh. V. Dobrokhotova V. M. Novotortsev I. L. Eremenko 《Russian Chemical Bulletin》2011,60(11):2236-2250
Binuclear heterometallic complexes (??2-bpy)CoLn(Piv)5(H2O), (??2-bpy)NiLn(Piv)5(H2O), and (??2-bpy)CuLn(Piv)5(HPiv) (Ln = Sm or Gd, Piv- is the pivalate anion) were synthesized. A comparative study of the structural characteristics and the thermolysis of the resulting compounds was performed. 相似文献