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Wen Zhang Hui Huang Yu Ding Margherita Gavagnin Ernesto Mollo Guido Cimino Yue‐Wei Guo 《Helvetica chimica acta》2006,89(4):813-820
Three new polyoxygenated steroids, muricesteroid ( 1 ), and menellsteroids A ( 2 ) and B ( 3 ), were isolated from two species of the South China Sea gorgonian Muricella flexuosa and Menella verrucosa Brundin , respectively. The structures of these new compounds were elucidated on the basis of extensive spectroscopic analysis, chemical methods and comparison with known related compounds. 相似文献
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Guido Wauters Jacques Dewaele Carlo Vandecasteele Richard Dams 《Mikrochimica acta》1989,98(4-6):157-162
Proton activation analysis was used for the determination of cadmium and lead in three sediment reference materials. The method is based on the111,112Cd(p, xn)111 In and the206,207,208Pb(p, xn)206Bi reactions.111In and206Bi were chemically separated by anion exchange. The results obtained were taken into account for the certification of the materials and are in the excellent agreement with the certified values. 相似文献
6.
Guido Pintacuda Andrei Kaikkonen Gottfried Otting 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,171(2):387-243
Paramagnetic metal ions with fast-relaxing electronic spin and anisotropic susceptibility tensor provide a rich source of structural information that can be derived from pseudo-contact shifts, residual dipolar couplings, dipole-dipole Curie spin cross-correlation, and paramagnetic relaxation enhancements. The present study draws attention to a cross-correlation effect between nuclear relaxation due to anisotropic chemical shielding (CSA) and due to the anisotropic dipolar shielding (DSA) caused by the electronic Curie spin. This CSA x DSA cross-correlation contribution seems to have been overlooked in previous interpretations of paramagnetic relaxation enhancements. It is shown to be sufficiently large to compromise the 1/r6 distance dependence usually assumed. The effect cannot experimentally be separated from auto-correlated DSA relaxation. It can increase or decrease the observed paramagnetic relaxation enhancement. Under certain conditions, the effect can dominate the entire paramagnetic relaxation, resulting in nuclear resonances narrower than in the absence of the paramagnetic center. CSAxDSA cross-correlation becomes important when paramagnetic relaxation is predominantly due to the Curie rather than the Solomon mechanism. Therefore the effect is most pronounced for relaxation by metal ions with large magnetic susceptibility and fast-relaxing electron spin. It most strongly affects paramagnetic enhancements of transverse relaxation in macromolecules and of longitudinal relaxation in small molecules. 相似文献
7.
Guido Cortesani 《Annali dell'Universita di Ferrara》1997,43(1):27-49
Let Ω be an open and bounded subset ofR
n
with locally Lipschitz boundary. We prove that the functionsv∈SBV(Ω,R
m
) whose jump setS
vis essentially closed and polyhedral and which are of classW
k, ∞ (S
v,R
m) for every integerk are strongly dense inGSBV
p(Ω,R
m
), in the sense that every functionu inGSBV
p(Ω,R
m
) is approximated inL
p(Ω,R
m
) by a sequence of functions {v
k{j∈N with the described regularity such that the approximate gradients ∇v
jconverge inL
p(Ω,R
nm
) to the approximate gradient ∇u and the (n−1)-dimensional measure of the jump setsS
v
j converges to the (n−1)-dimensional measure ofS
u. The structure ofS
v can be further improved in casep≤2.
Sunto Sia Ω un aperto limitato diR n con frontiera localmente Lipschitziana. In questo lavoro si dimostra che le funzioniv∈SBV(Ω,R m ) con insieme di saltoS v essenzialmente chiuso e poliedrale che sono di classeW k, ∞ (S v,R m ) per ogni interok sono fortemente dense inGSBV p(Ω,R m ), nel senso che ogni funzioneu∈GSBV p(Ω,R m ) è approssimata inL p(Ω,R m ) da una successione di funzioni {v j}j∈N con la regolaritá descritta tali che i gradienti approssimati ∇v jconvergono inL p(Ω,R nm ) al gradiente approssimato ∇u e la misura (n−1)-dimensionale degli insiemi di saltoS v jconverge alla misura (n−1)-dimensionale diS u. La struttura diS vpuó essere migliorata nel caso in cuip≤2.相似文献
8.
Holger Poths Erik Wischerhoff Rudolf Zentel Axel Sch nfeld Guido Henn Friedrich Kremer 《Liquid crystals》1995,18(5):811-818
Two new ferroelectric oligosiloxanes, a cyclic tetramer and a twin, have been synthesized. By a comparative study with their corresponding monomer and side chain polysiloxanes, the influence of oligo- and polymerization on the liquid crystalline and ferroelectric properties have been investigated. Polymerization leads to a stabilization of LC phases through increase of the clearing temperatures and suppression of crystallization. Oligomerization also leads to mesophase broadening, but, due to the low degree of polymerization, the effect is inferior to the linear polysiloxanes. The low viscosity of the oligosiloxanes ensures response times in the microsecond region, thus being comparable with their monomer and conventional LMWFLCs. It is found that polymerization increases the spontaneous polarization Ps. This is attributed to the density increase after polymerization, enhancing the inter-mesogenic interactions. The collective and local dynamics of the OFLCs are influenced differently with respect to their molecular structures. Each oligomer is already a good model for its corresponding polymer concerning the soft mode dynamics. For the local β-relaxation a similar temperature dependence of the relaxation times τ for the cyclic tetramer and for the side chain polysiloxanes is observed. The long axial rotation of the twin, having a very efficient decoupling, is significantly faster, thus resembling the monomer. 相似文献
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10.
Reaction diffusion systems on cylindrical domains with terms that vary rapidly and periodically in the unbounded direction can be analyzed by averaging techniques. Here, using iterated normal form transformations and Gevrey regularity of bounded solutions, we prove a result on exponential averaging for such systems, i.e., we show that traveling wave solutions can be described by a spatially homogenous equation and exponentially small remainders. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献