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排序方式: 共有5591条查询结果,搜索用时 15 毫秒
1.
Nonlinear Dynamics - In this paper, we analyze the effect which the choice of a friction model has on tippe top inversion in the case where the resulting action of all dissipative forces is... 相似文献
2.
Synthesis of Highly Substituted γ‐Butyrolactones by a Gold‐Catalyzed Cascade Reaction of Benzyl Esters
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Maria Camila Blanco Jaimes Alexander Ahrens Daniel Pflästerer Dr. Matthias Rudolph Prof. Dr. A. Stephen K. Hashmi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):427-433
Easily accessible benzylic esters of 3‐butynoic acids in a gold‐catalyzed cyclization/rearrangement cascade reaction provided 3‐propargyl γ‐butyrolactones with the alkene and the carbonyl group not being conjugated. Crossover experiments showed that the formation of the new C?C bond is an intermolecular process. Initially propargylic–benzylic esters were used, but alkyl‐substituted benzylic esters worked equally well. In the case of the propargylic–benzylic products, a simple treatment of the products with aluminum oxide initiated a twofold tautomerization to the allenyl‐substituted γ‐butyrolactones with conjugation of the carbonyl group, the olefin, and the allene. The synthetic sequence can be conducted stepwise or as a one‐pot cascade reaction with similar yields. Even in the presence of the gold catalyst the new allene remains intact. 相似文献
3.
Carello Giuliana Landa Paolo Tnfani Elena Testi Angela 《Central European Journal of Operations Research》2022,30(1):159-187
Central European Journal of Operations Research - In the past years, the number of patients in need of chemotherapy treatments has been constantly increasing. Chemotherapy treatments must be... 相似文献
4.
Elena Kardash-Strochkova Yakov I. Tur’yan I. Kuselman Naphtali Brodsky 《Accreditation and quality assurance》2002,7(6):250-254
The results of two interlaboratory comparisons of acid number determinations in used motor oils are discussed. It is shown
that the comparability of the measurement results is not as good as that required by known standards for petroleum products.
The problem is motor oil contaminants which accumulated during use, and which are the source of a matrix effect in the acid
number determination. The standard methods’ drawbacks are analyzed and some improvements are proposed. Repeatability and accuracy
of the improved methods are evaluated.
Received: 11 December 2001 Accepted: 15 February 2002 相似文献
5.
Rhodium catalysts have been prepared on palygorskite and montmorillonite (clay) supports by reduction with hydrogen (1 atmosphere) at room temperature of a cationic organometallic rhodium compound anchored to the support. The activity of these catalysts for the hydrogenation of liquid-phase 1-hexene remains constant with increase of prehydrogenation time and with re-use for several runs. No rhodium leaching is observed. 相似文献
6.
Mariusz Bednarz Peter Reineker Elena Mena-Osteritz Peter Buerle 《Journal of luminescence》2004,110(4):225-231
We theoretically study the size-dependent relation between absorption spectra of thiophene-based oligomers and the corresponding cyclothiophenes. In our approach based on a Frenkel exciton Hamiltonian, we demonstrate that the geometry and selection rules determine the observed relations between the spectra. 相似文献
7.
8.
The magnetic properties of a TbNi2Si2 single crystal have been investigated experimentally by specific heat, anisotropy of the susceptibility and magnetization, and inelastic neutron scattering, leading to the determination of its fundamental coupling parameters. The lowest crystalline electric field states are two singlets close to each other, that explains the different magnetic structures evidenced in TbNi2Si2: an amplitude modulated structure, close to T N , a simple antiferromagnetic one at low temperature and an antiphase one when an external magnetic field is applied along the c direction. 相似文献
9.
In [7] point-reflection geometries were studied which can be derived from commutative kinematic
spaces without involutory elements. But the class of point-reflection geometries is larger. For example, elliptic
planes with their reflections cannot be derived from commutative kinematic spaces. Here we investigate a larger
class of reflection geometries.This paper was sponsored by Vigoni Program 1999. 相似文献
10.
Elena Larraz Carlos Elvira Julio San Romn 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1641-1649
This article explores the synthesis of a novel methacrylic macromonomer with an amphiphilic character derived from poly(ethylene glycol) tert‐octylphenyl ether (MT) and its respective homopolymer. To know their reactivity in radical copolymerization reactions with methyl methacrylate (MMA), a model monomer (MTm) was synthesized to determine the reactivity ratios and compare them with the low molar fractions of copolymers of MT with MMA because they were difficult to isolate. They were rMTm = 0.97 and rMMA = 0.95. The compositional diagrams when representing the weight fraction of MT and MTm in the feed and the copolymer suggested that a clear correlation exists between the experimental points of the model monomer MTm and the macromonomer MT ones, suggesting that the length of the side poly(ethylene oxide) chain does not affect the reactivity of the methacrylic double bond in the prepared monomers for this type of polymerization reaction. The reactivity ratios of the copolymers have a tendency for the formation of random or Bernoullian copolymers. The glass‐transition temperatures (Tg's) of the prepared copolymers were determined by differential scanning calorimetry, deviated from the Fox equation, and discussed on the basis of treatments that consider the influence of the monomeric units along the copolymer chains, determining the Tg of the corresponding alternating dyads. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1641–1649, 2003 相似文献