全文获取类型
收费全文 | 83篇 |
免费 | 8篇 |
专业分类
化学 | 86篇 |
力学 | 1篇 |
数学 | 2篇 |
物理学 | 2篇 |
出版年
2023年 | 2篇 |
2021年 | 3篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2017年 | 2篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 1篇 |
2013年 | 6篇 |
2012年 | 6篇 |
2011年 | 8篇 |
2010年 | 10篇 |
2009年 | 2篇 |
2008年 | 6篇 |
2007年 | 6篇 |
2006年 | 3篇 |
2005年 | 4篇 |
2004年 | 1篇 |
2003年 | 2篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有91条查询结果,搜索用时 15 毫秒
1.
Computerized analytical instruments of late 70's and 80's are facing rapid technological obsolescence, although they are often retaining good analytical performances. Responsibility is to be attributed to the fast advance in computer technology, which is leaving little or no back-compatibility with old standards and data formats. Rejuvenation may be reached by simple hardware and software modifications, to allow data exchange with modern PC's and LIMS. Two typical case histories for spectrometric instrumentation of late 70's are then presented and discussed in a general fashion. 相似文献
2.
Patrina Paraskevopoulou Eleftheria Petalidou Nikos Psaroudakis Pericles Stavropoulos Konstantinos Mertis 《Monatshefte für Chemie / Chemical Monthly》2005,136(12):2035-2039
Summary. Primary phenylmethanols are selectively and efficiently oxidized to the corresponding aldehydes by the system C6H5IO/(C6H5)4PBr/CH2Cl2, T = 298 K under aerobic conditions. The use of the relatively stable iodosobenzene, an iodine(III) compound, in place of the
usually employed and potentially explosive iodine(V) reagents, the easy work-up procedure, and the facile recycling of solvent
and oxidant provides a convenient and environmentally benign oxidation method. 相似文献
3.
Katarzyna Skrzypek Milou Groot Nibbelink Jolanda Liefers‐Visser Alexandra M. Smink Eleftheria Stoimenou Marten A. Engelse Eelco J. P. de Koning Marcel Karperien Paul de Vos Aart van Apeldoorn Dimitrios Stamatialis 《Macromolecular bioscience》2020,20(8)
Macroencapsulation of islets of Langerhans is a promising strategy for transplantation of insulin‐producing cells in the absence of immunosuppression to treat type 1 diabetes. Hollow fiber membranes are of interest there because they offer a large surface‐to‐volume ratio and can potentially be retrieved or refilled. However, current available fibers have limitations in exchange of nutrients, oxygen, and delivery of insulin potentially impacting graft survival. Here, multibore hollow fibers for islets encapsulation are designed and tested. They consist of seven bores and are prepared using nondegradable polymers with high mechanical stability and low cell adhesion properties. Human islets encapsulated there have a glucose induced insulin response (GIIS) similar to nonencapsulated islets. During 7 d of cell culture in vitro, the GIIS increases with graded doses of islets demonstrating the suitability of the microenvironment for islet survival. Moreover, first implantation studies in mice demonstrate device material biocompatibility with minimal tissue responses. Besides, formation of new blood vessels close to the implanted device is observed, an important requirement for maintaining islet viability and fast exchange of glucose and insulin. The results indicate that the developed fibers have high islet bearing capacity and can potentially be applied for a clinically applicable bioartificial pancreas. 相似文献
4.
Eleftheria Antoniou 《European Polymer Journal》2010,46(2):324-10540
The conformation of the common polysaccharide dextran has been investigated in mixed solvents at two different temperatures using viscosity measurements. In particular we considered binary mixtures of water with the polar organic solvents glycerol, formamide, dimethylsulfoxide, or ethanol. The intrinsic viscosity of dextran T500 in the different systems has been determined, and the solvent effects, as manifested in variations of the dextran intrinsic viscosity and coil radius, have been correlated to the surface tension and the fractional solubility parameters of the solvent mixture. The coil dimension changes observed in the different solvent mixtures are consistent with expectations from water-cosolvent-dextran interactions, especially as they pertain to hydrogen bonding. 相似文献
5.
Eleftheria Katechaki Theodoros Solomonidis Argyro Bekatorou Athanasios A. Koutinas 《Applied biochemistry and biotechnology》2010,162(5):1270-1285
Lactobacillus bulgaricus grown on whey was dried by a simple thermal drying method at the range 35–55°C and its efficiency for lactic acid fermentation
of whey was evaluated. Drying of cells in whey suspension in the examined temperature range did not affect significantly their
viability (82–87% survival), indicating a protective effect of whey as both growth and drying medium. The kinetics of fermentation
of whey and mixtures of whey/molasses using the dried culture were comparable to those of non-dried cells, and only low pH
had a detrimental effect on the fermentation ability of the dried cells. Furthermore, dried L. bulgaricus, free or immobilized on casein coagulates, was used as starter for the production of unsalted hard-type cheese. The effects
of the amount of starter culture and the immobilization technique, the evolution of microbial counts, and the sensory properties
of the produced cheeses were evaluated during ripening at various temperatures. 相似文献
6.
Tribute
Special issue of FOA10 in honor of our colleagues in Japan and New Zealand 相似文献7.
Eleftheria Lehmann John Kouinis Prof. Dr. Andreas Galinos 《Monatshefte für Chemie / Chemical Monthly》1975,106(2):499-502
Tribromomanganese(II) acid has been prepared for the first time and will be described. A complex of the acid with pyridine was obtained and its UV, visible, IR and1H-NMR spectra will be reported. 相似文献
8.
Margherita Albano Emma Barchiesi Roberto Biancardi Marco Dossi Giuliana Geniram Paola Vaccarono 《Macromolecular Symposia》2013,324(1):41-48
Summary: In this work an investigation of the chain end groups produced in the free radical copolymerization of vinilydene fluoride (VDF) and hexafluoropropylene (HFP) is performed. Type and amount of chain end groups are evaluated by a meticulous analytical characterization of VDF/HFP copolymer. At first pulsed gradient spin-echo nuclear magnetic resonance (spin-echo NMR) is used to identify all the chain end groups also at very low concentration (equal to 0.1 mmol · Kg−1). The instrument sensitivity is increased of an order of magnitude in comparison with the traditional NMR. Moreover potentiometric titration and ion chromatography (IC) are also used to study the chain end groups and, as a consequence, the nature and the amount of the acidity showed by the polymer chains. In details two intensity of acidity are detected by potentiometric titration, namely strong and weak. The strong acidity is associated to the presence of residual surfactant and can be removed washing the polymer, while the weak acidity is due to free molecules of fluoride acid (HF). The standard ion chromatography facility is properly modified to quantify the fluoride in the polymer matrix without any pre extraction in water. Thanks to this the HF concentration in the polymer is evaluated with high accuracy. A detailed kinetic scheme for the VDF/HFP polymerization is also proposed taking into account all the findings obtained studying the chain end groups. 相似文献
9.
Ivan Zuliani Andrea Fattori Rossella Svigelj Nicolò Dossi Cristian Grazioli Gino Bontempelli Rosanna Toniolo 《Electroanalysis》2023,35(2):e202200150
A convenient assembly recently proposed for screen printed gold electrodes (SPEs) suitable for measurements in gaseous samples is here tested for the analysis of the ethanol content in alcoholic drinks. This assembly involves the use of a circular crown of filter paper, soaked in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium hydrogen sulfate, which is simply placed upon a disposable screen printed cell, so as to contact the outer edge of the gold disc working electrode, as well as peripheral counter and reference electrodes. The electrical contact between the paper crown soaked in RTIL and the SPE electrode is assured by a gasket and all components are installed in a polylactic acid holder. This assembly provides a portable and disposable electrochemical platform, assembled by the easy immobilization onto a porous and inexpensive supporting material such as paper of a RTIL characterized by profitable electrical conductivity and negligible vapor pressure. The electroanalytical performance of this device was assayed for the flow injection analysis of the ethanol concentration in some real samples of wine and beer and the results obtained are compared with the alcoholic degree reported in the relevant bottle-labels, thus highlighting a substantially satisfactory agreement. Repeatable sharp peaks (RSD=6–8 %) were detected for ethanol over a wide linear range (1–20 % v/v in water) and a detection and quantitation limit of 0.55 % v/v and 1.60 % v/v were inferred for a signal-to-noise ratio of 3 and 10, respectively. 相似文献
10.
Litos IK Emmanouilidou E Glynou KM Laios E Ioannou PC Christopoulos TK Kampa M Castanas E Gravanis A 《Analytical and bioanalytical chemistry》2007,389(6):1849-1857
In recent years an increasing amount of interest has been directed at the study and routine testing of polymorphisms responsible
for variations in drug metabolism. Most of the current methods involve either time-consuming electrophoresis steps or specialized
and expensive equipment. In this context, we have developed a rapid, simple and robust method for genotyping of CYP2D6*3,
CYP2D6*4, CYP2C19*2, CYP2C19*3 and TPMT*2 single nucleotide polymorphisms (SNP). Genomic DNA is isolated from whole blood
and the segments that span the SNP of interest are amplified by PCR. The products are subjected directly (without purification)
to two primer extension (PEXT) reactions (three cycles each) using normal and mutant primers in the presence of biotin-dUTP.
The PEXT primers contain a (dA)30 segment at the 5′ end. The PEXT products are detected visually by a dry-reagent dipstick-type assay in which the biotinylated
extension products are captured from immobilized streptavidin on the test zone of the strip and detected by hybridization
with oligo(dT)-functionalized gold nanoparticles. Patient samples (76 variants in total) were genotyped and the results were
fully concordant with those obtained by direct DNA sequencing. 相似文献