Activity of Ni?Mo hydrodesulfurization catalysts supported on mixed alumina-zirconia

The hydrodesulfurization (HDS) of thiophene by nickel-molybdenum catalysts supported on alumina-zirconia has been investigated. The effect of varying the ratios of oxides in the support is to produce a minimum in the activity for HDS, and the coimpregnated catalysts are shown to be more active than the analogous co-precipitated catalysts.

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(HDS) -, . HDS. , .

     

Synthesis of lipid A derivatives and their interactions with polymyxin B and polymyxin B nonapeptide

Lipid A is the causative agent of Gram-negative sepsis, a leading cause of mortality among hospitalized patients. Compounds that bind lipid A can limit its detrimental effects. Polymyxin B, a cationic peptide antibiotic, is one of the simplest molecules capable of selectively binding lipid A and may serve as a model for further development of lipid A binding agents. However, association of polymyxin B with lipid A is not fully understood, primarily due to the low solubility of lipid A in water and inhomogeneity of lipid A preparations. To better understand lipid A-polymyxin B interaction, pure lipid A derivatives were prepared with incrementally varied lipid chain lengths. These compounds proved to be more soluble in water than lipid A, with higher aggregation concentrations. Isothermal titration calorimetric studies of these lipid A derivatives with polymyxin B and polymyxin B nonapeptide indicate that binding stoichiometries (peptide to lipid A derivative) are less than 1 and that affinities of these binding partners correlate with the aggregation states of the lipid A derivatives. These studies also suggest that cooperative ionic interactions dominate association of polymyxin B and polymyxin B nonapeptide with lipid A.     

“Synchrotron radiation research”

Edited by: H. Winick and S. Doniach. Plenum: New York and London, pp. 754 ($65).     

PH-Bestimmungsmethoden

Ohne Zusammenfassung     

183 GHz double diode subharmonically pumped mixer

A double diode subharmonically pumped mixer is described. A diode-whisker contacting arrangement has been developed which avoids many of the problems associated with whisker contacts. Early tests indicate that the circuit structure is rugged and capable of good electrical performance.     

Cauchy transforms of characteristic functions and algebras generated by inner functions

We prove that Cauchy transforms of characteristic functions of subsets of positive measure of the unit circle are equidistributed in the unit disk in the sense that the -closure of the polynomial algebra in these Cauchy transforms coincides with the -closure of the polynomial algebra in a canonical inner function. As a corollary to this result we find conditions describing when the polynomial algebra in two singular inner functions determined by point masses is dense in the Hardy spaces .

     

Living polymerization: Rationale for uniform terminology

Polymer chemistry textbooks (e.g., B. Vollmert, Polymer Chemistry, Springer‐Verlag: New York, 1973, p 37; G. Odian, Principles of Polymerization, 3rd ed., Wiley: New York, 1991, p 8; H. G. Elias, An Introduction to Polymer Science, VCH: Weinheim, 1997, p 51) classify polymerization reactions as chain, step, and living according to the dependence of their degree of polymerization (DP ) or molecular weight (M̄) on conversion. This article discusses the rationale for uniform terminology in living polymerization. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1706–1708, 2000     

Chiral symmetry breaking at finite temperature in Coulomb gauge QCD

Chiral symmetry breaking at finite temperature is analysed in Coulomb gauge QCD, using a suitably renormalised gap equation. In Coulomb gauge the gap equation is derived using the Ward identities and the Dyson equations for the vector and axial-vector vertices. Making the ladder approximation to the Bethe-Salpeter kernel relates the chiral symmetry breaking parameters to the static quark potential. It is thus possible to use a confining potential in the analysis of chiral symmetry breaking. We extend this to finite temperature. For a confining potential there is no chiral symmetry restoration at any finite temperature.