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Sonja Eichholz Martin Lerch Michael Heck Dirk Walter 《Journal of Thermal Analysis and Calorimetry》2012,110(1):437-441
Nano-sized carbon dusts are suspected of having negative effects on human health. An exact characterization of such particles is necessary to understand possible toxic effects, i.e. in the lung. Observed by transmission electron microscopy (TEM), the carbon dusts are a composite of very small primary particles and larger agglomerates of these. A differentiation of the primary particles and agglomerates according to source is not possible by TEM, however, thermogravimetry investigations in synthetic air atmosphere are helpful. Standardized carbon black and graphite show a single-step oxidation behaviour, whereas ethene soot and diesel soot, for example, show more complex-reaction mechanisms. The results of ethene soot exemplarily demonstrate the oxidation mechanism. In addition to the oxidation reaction to carbon dioxide, a sintering process takes place. To confirm the oxidation mechanism, thermal behaviour of ethene soot has been simulated by kinetic modulation using a three-step reaction mechanism of n-th order. The reaction order indicates a complex mechanism for the first-reaction step. For the second and third-reaction step, a phase boundary mechanism could be suggested. 相似文献
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Thomas Eichholz 《Archive for Mathematical Logic》1957,3(1-2):19-28
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Weimin?HanEmail author Joseph?A.?Eichholz Ge?Wang 《Journal of mathematical chemistry》2012,50(4):689-702
The radiative transfer equation (RTE) arises in a variety of applications and is challenging to solve numerically due to its
integro-differential form and high dimension. For highly forward-peaked media, it is even more difficult to solve RTE since
accurate numerical solutions require a high resolution of the direction variable. For this reason, various approximations
of RTE have been proposed in the literature. In this paper, we study a family of differential approximations of the RTE in
three spatial variables. We explain the idea of constructing the differential approximations, and comment on the usefulness
of the approximations. 相似文献
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Runmiao Xue Ariel Donovan Honglan Shi John Yang Bin Hua Enos Inniss Todd Eichholz 《Analytical and bioanalytical chemistry》2016,408(24):6613-6622
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Linear optical coherence tomography (LOCT) systems are a simple and robust alternative to time-domain optical coherence tomography systems, but a detector with approximately 10(4) pixels is needed for an imaging depth of 2 mm. We present a new system for LOCT with a special mask attached to the image sensor. The mask essentially performs a downconversion of the spatial frequencies by multiplication with a second spatial frequency. This reduces the fringe frequency of the optical coherence tomography signal so that the signal can be sampled with fewer pixels. 相似文献
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Sedimentation based processes are widely used in industry to separate particles from a liquid phase. Since the advent of the "Nanoworld" the demand for effective separation technologies has rapidly risen, calling for the development of new separation concepts, one of which lies in hybrid separation using the superposition of a magnetic field for magnetic particles. Possible product portfolio of such separation consists of pigment production, nanomagnetics production for electronics and bio separation, A promising step in that direction is magnetic field enhanced cake filtration, which has by now progressed from batch to continuous ooeration.
In sedimentation processes in a mass force field the settling behaviour of particles strongly depends on physico-chemical properties, concentration and size distribution of the particles. By adjusting the pH, the interparticle forces, in particular the electrostatic repulsion, can be manipulated. For remanent magnetic particles such as magnetite, pre-treatment in a magnetic field could lead to a change of interparticle interactions. By magnetizing the particles apart from van der Waals attraction and electrostatic repulsion, an additional potential is induced, the magnetic attraction, which could easily dominate the other potentials and result in agglomeration in the primary minimum. By sedimentation analysis, a wide spectrum of parameters like pH, magnetic field strength and concentration have been investigated. The results show a strong increase of sedimentation velocity by magnetic flocculation of the raw suspension. This leads to a rise in throughput due to the acceleration of sedimentation kinetics by imparting a non-chemical interaction to the physico-chemical properties in the feed stream of the separation apparatus. 相似文献
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H. F. Kappert K. F. Heidemann D. Eichholz E. te Kaat W. Tothemund 《Applied Physics A: Materials Science & Processing》1980,21(2):151-158
Oxygen profiles in silicon implanted with energies between 2 and 20 MeV by means of a Tandem accelerator have been investigated with a microprobe after bevelling the sample surface. It is shown that the measured profiles correspond to the implantation profiles when the microprobe is operated with a well focussed 2 keV electron beam. The projected ion ranges and the profiles thus obtained are compared with theoretical profiles which have been calculated by a Monte Carlo simulation of the stopping procedure. Takingk=1.30k LSS for the electronic stopping coefficient in the LSS region up to 2.55 MeV and a constant value of 162 eV/Å for the electronic stopping at higher energies the calculation yields satisfactory range estimates, whereas the range straggling is systematically too small up to 13% in comparison with the experimental results. 相似文献
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H. Salomon R. Diehl Ch. Porcher A. Bonis P. Defrance A. J. P. Pacini D. W. Russell Lewis Benedict L. Panchaud E. Auerbach G. D. Elsdon W. Eichholz Cotton Baier Neumann A. Backe A. Wiborg und E. Röer 《Fresenius' Journal of Analytical Chemistry》1920,59(8-9):378-381
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