Reactions of Polyfluorinated Telomeric Alcohols with ε-Caprolactam

The possibility of preparing fluorinated oligomeric derivatives of -aminocaproic acid by reaction of polyfluorinated telomeric alcohols H(CF₂CF₂) _n CH₂OH (n = 1-4) with -caprolactam under conditions of homogeneous catalysis (triethylamine, dimethylformamide) was examined. The thermal stability of the oligomers was studied in relation to the fluorine content.     

Coulometric Reversibility of Electrochemical Nanoionic Integrators with Long-Term Memory

Russian Journal of General Chemistry - Ionic and molecular electronics relate to the field of science and technology, which deals with the theory and development of electrochemical converters. The...     

Mechanism and kinetics of electrode processes in systems comprising solid polyaluminate electrolyte

Cathodic reduction of organic semiconductors (charge-transfer complexes and radical-ion salts) at interfaces in Na(Hg)/β-Al₂O₃/organic semiconductor systems is studied by inversion voltammetry and chronopotentiometry. Formation of transition layer at the organic semiconductor/solid electrolyte interface is revealed. The mechanism of the charge transfer complex and radical-ion salt cathodic reduction depends on the potential scan rate; the cathodic process at nonmetal electrodes occurs under the conditions of double injection of electronic and ionic charge carriers to electrode bulk.     

Cerasomes containing magnetic nanoparticles: synthesis and gel-filtration chromatographic characterization

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Heterojunctions in a Solid-state Electrochemical System with Lithium Anode Directly Contacting Organic Semiconductor

Solid-state electrochemical cells containing an alkali metal/organic semiconductor direct contact are studied using a potentiodynamic method. Both ionic and electronic charge transfer processes are possible in heterostructures based on direct contact of alkali metals with p-type semiconductors. The multistage processes proceeding in the systems studied involve chemical reactions and changes in the resistance of both the initial cathode material and the cathodic reduction products.