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排序方式: 共有2759条查询结果,搜索用时 15 毫秒
1.
de Santana Felipe Silva Gracioso Louise Hase Karolski Bruno dos Passos Galluzzi Baltazar Marcela Mendes Maria Anita do Nascimento Claudio Augusto Oller Perpetuo Elen Aquino 《Applied biochemistry and biotechnology》2019,189(1):103-115
Applied Biochemistry and Biotechnology - The human exposure to bisphenol A (BPA) occurs frequently. Once, this compound was one of the highest volume chemicals produced worldwide and used as a... 相似文献
2.
3.
Edson Vargas 《Communications in Mathematical Physics》1991,138(3):521-535
We considerC
2 unimodal mapsf such that all periodic points are hyperbolic, the critical point is non-degenerated and non-recurrent, and the Julia set does not contain intervals. We construct a Markov partition for a big part of the Julia set. Then we use it to estimate the limit capacity and Hausdorff dimension of the Julia set.Partially supported by CNPq, S.C.T.-Brazil 相似文献
4.
Ohne Zusammenfassung 相似文献
5.
The aim of this work is to study the dynamic formation and dissociation of trions and excitons in double barrier resonant tunneling diodes. We propose a system of rate equations that takes into account the formation, dissociation and annihilation of these complexes inside the quantum well. From the solutions of the coupled equations, we are able to study the modulation of excitons and trions formation in the device as a function of the applied bias. The results of our model agree qualitatively with the experiments showing the viability of these rate equations system to study the dynamics of complex systems. 相似文献
6.
Tereza C. R. dos Santos Ricardo Q. Aucélio Reinaldo C. Campos 《Mikrochimica acta》2003,142(1-2):63-66
A simple and direct spectrofluorimetric method has been developed for the determination of aluminum using alizarin red PS
(1,2,4-trihydroxy 9,10-anthraquinone-3-sulfonic acid). The method is based on the strong fluorescence (480/564 nm) of Al3+ and alizarin red. Experimental parameters such as pH, concentration of the ligand, ionic strength of the solution, reaction
time and temperature were optimized in order to maximize the analytical signal. Interferences of several ions (anions and
cations) were studied and evaluated. The linear range of the method extends from 3 to 100 μg L−1. Limit of detection (3sb) was 0.9 μg L−1. The method was tested with a silicate certified reference material. Interferences were eliminated by a liquid extraction
with cupferron.
Author for correspondence. E-mail: aucelior@rdc.puc-rio.br
Received September 10, 2002; accepted January 15, 2003
Published online May 5, 2003 相似文献
7.
Biosorption of Chromium(III) by Biomass of Seaweed Sargassum sp. in a Fixed-Bed Column 总被引:2,自引:0,他引:2
Eneida Sala Cossich Edson Antonio da Silva Célia Regina Granhen Tavares Lúcio Cardozo Filho Teresa Massako Kakuta Ravagnani 《Adsorption》2004,10(2):129-138
This work aimed at modeling chromium biosorption using the biomass of seaweed Sargassum sp. in a fixed-bed column. The mathematical model used was obtained from the mass balance of the component in the liquid phase and in the biosorbent material. The effects of both axial dispersion in the column and the resistance to mass transfer in the solid were considered for the solution of the partial differential equations of the model, using the Galerkin method on finite elements. To represent the equilibrium data of the batch system the Langmuir isotherm were used. The chromium ion adsorption capacity of the seaweed Sargassum sp., at a temperature of 30°C and pH 3.5, was 2.61 mmol/g. The model performance was evaluated from experimental data obtained at 30°C for flow rates of 2, 6 and 8 mL/min. The parameters of the model, mass transfer and axial dispersion coefficients, were adjusted from these experimental data. The model proved adequate to describe chromium biosorption dynamics in fixed-bed columns. 相似文献
8.
G. Garcia-Belmonte J. Bisquert L. M. Navarro J. R. Jurado F. M. B. Marques 《Ionics》1995,1(5-6):377-383
In ionic conductors, long range-migrating charges are a main cause of polarization processes. This has complicated, up to
date, the study of ionic thermocurrents (ITC) in solid electrolytes. However, the method is appealing, as it probes directly
charge-formation phenomena that are important both from a scientific point of view and for applications.
This work reports on the observation of ITC in solid electrolytes. Under appropriate experimental conditions, the ITC response
of a zirconia sample electroded with platinum is a reproducible one, thus opening the way to a new characterization method
that may complement other well established methods, such as Impedance Spectroscopy and a number of electrochemical techniques.
The general trends of the response, which is composed of two well resolved ITC peaks, is discussed. One of them, taking place
at higher temperatures, conforms to the standard shape of a first order kinetics depolarization process.
Paper presented at the 2nd Euroconference on Solid State Ionics, Funchal, Madeira, Portugal, Sept. 10–16, 1995 相似文献
9.
Maria Marques Zhengtian Yu Marvin D. Rausch James C. W. Chien 《Journal of polymer science. Part A, Polymer chemistry》1995,33(16):2787-2793
4-Vinylcyclohexene (VCH) and cyclooctadiene (COD) were investigated as termonomers in EPDM (ethylene/propylene/diene) synthesis by using rac-ethylenebis (1-η5-indenyl) zir-conium dichloride ( 1 ) as a catalyst precursor. Homopolymerizations of VCH, vinylcycloh-exane and cyclohexene were compared. The parameter Kπκp, which is the apparent rate constant for Ziegler-Natta polymerization, is about the same for VCH and vinylcyclohexanebut is 10 times smaller for cyclohexene. Therefore, the linear olefinic double bond is more active than the cyclic internal double bond. VCH reduces ethylene polymerization rate but not propylene polymerization rate in copolymerizations. In terpolymerizations, VCH tends to suppress ethylene incorporation especially at elevated polymerization temperature and Lowers the polymer MW by about two-fold. COD has very low activity as a termonomer. © 1995 John Wiley & Sons, Inc. 相似文献
10.
U. Täuber C.E.M. Carvalho R.F. dos Santos C.G. Carvalhaes C.E. Fellows 《Applied physics. B, Lasers and optics》2007,87(3):475-481
A six level rate equation system was used to investigate the impact of photodepletion to amplified spontaneous emission (ASE)
of intramolecular proton-transfer (IPT) dyes incorporated into polymeric hosts. The model includes the most important transitions
for the normal and tautomer form of the molecule as well as intersystem crossing and triplet–triplet transitions. The experimentally
observed pulse shape as well as photodepletion phenomena, i.e. a first order exponential decay of the ASE intensity and a
shortening in ASE pulse width, have been simulated successfully. Additionally, the model was used to propose an explanation
of the unexpected high photodepletion of proton-transfer dyes in solids. The results show that the emission cross section
and reabsorption cross section of the tautomer form of the molecule are the most important parameter not only for efficiency
but also for photodepletion. The model was tested by comparison with experimental results of 2-(2’-hydroxyphenyl)benzimidazole
in polymethylmethacrylate (PMMA), polystyrene (PS) and a 1:1 alternating copolymer matrix PS-co-PMMA.
PACS 78.45.th; 42.55.Mv; 42.70.Jk 相似文献