首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   461篇
  免费   8篇
  国内免费   2篇
化学   202篇
力学   22篇
数学   175篇
物理学   72篇
  2024年   2篇
  2022年   9篇
  2021年   9篇
  2020年   5篇
  2019年   11篇
  2018年   5篇
  2017年   8篇
  2016年   13篇
  2015年   12篇
  2014年   10篇
  2013年   24篇
  2012年   18篇
  2011年   21篇
  2010年   15篇
  2009年   14篇
  2008年   17篇
  2007年   20篇
  2006年   13篇
  2005年   25篇
  2004年   13篇
  2003年   17篇
  2002年   7篇
  2001年   10篇
  2000年   6篇
  1999年   5篇
  1998年   7篇
  1997年   6篇
  1996年   7篇
  1995年   4篇
  1994年   2篇
  1993年   8篇
  1992年   12篇
  1991年   11篇
  1990年   7篇
  1989年   10篇
  1988年   5篇
  1987年   5篇
  1986年   3篇
  1985年   11篇
  1984年   7篇
  1983年   5篇
  1982年   11篇
  1981年   6篇
  1980年   8篇
  1979年   4篇
  1977年   4篇
  1976年   4篇
  1975年   2篇
  1965年   2篇
  1959年   2篇
排序方式: 共有471条查询结果,搜索用时 218 毫秒
1.
A new sample business survey for agriculture, the REA survey, and a project of integration with the FADN network (RICA in Italy) have significantly changed the production of statistical information nowadays available with reference to the agricultural sector. On the basis of this relevant information, new economic analyses are being developed on farms’ performance, agricultural households’ income and the Common Agricultural Policy (CAP). In this paper the authors estimate the relationship between the levels of variables of interest and their sampling errors using models in order to improve the accessibility of the information on estimates accuracy to the final users (agricultural analysts, policy makers). The paper is the result of a joint research of the three authors. Sections 1–3 and 6 by Pizzoli, Sects. 4 and 5 by Rondinelli, Sect. 7 by Filiberti, conclusions joint to the three authors.  相似文献   
2.
Wet chemical synthesis of precursor oxide ceramics is a method to obtain small particulate powders. Such powders are far more prone to ageing in air than more traditional precursors. Thermogravimetric analysis is used to highlight the species responsible for the ageing of ceramic precursors. Indeed water and carbon dioxide are observed to evolve from aged powders. Ceramics obtained from aged precursors can reach a very low final density with respect to the theoretical value. A large degree of the original sintering properties can be recovered after washing the aged powders with ethanol in a basic medium.  相似文献   
3.
Here we prove that every compact differential manifold has a smooth algebraic model defined over Q. In dimension 2 we find an algebraic model (may be singular) defined over Q and birational over Q to the projective plane.  相似文献   
4.
5.
6.
Two new intermetallic compounds have been synthetized and structurally studied by single crystal diffractometric data: Ca7Au3 (oP80, space groupPbca,a = 20.742(8), b = 18.036(8), c = 6.665(2) A?,Z = 8, R = 0.051) and Ca5Au4 (mP18, space groupP21/c, a = 8.028(3), b = 8.019(6), c = 7.727(3) A?, β = 109.16(6)°,Z = 2, R = 0.104). Both atomic arrangements, which represent new structural types, are based on Au-centered Ca trigonal prisms and are geometrically related to the Th7Fe3 and Pu5Rh4 structures.  相似文献   
7.
Joint IR and computational results allow a detailed characterization of the surface properties of a mesoporous benzene-silica hybrid material with crystal-like wall structure. After outgassing at 450 degrees C, hydroxyl species mainly consist of noninteracting silanols, with both O-H and Si-O stretching modes at lower frequencies than those of SiOH in silica. Interaction with several probe molecules, followed both by experiment and calculus, shows that the aryl group in the coordination sphere of Si imparts a lesser acidity with respect to the isolated silanol in silica. In contrast, adsorption isotherms indicate that the interaction with acetone is stronger with benzene-silica than with silica: this is interpreted in terms of secondary interactions taking place between the slightly acidic CH in acetone and the electronic cloud in benzene-like rings. This suggests that both the inorganic component and the organic one play a role in dictating the surface behavior.  相似文献   
8.
Cobalt and chromium release in patients undergone a metal-on-metal total hip replacement (THR) is a matter recently discussed and whose we do not have enough information about it yet. In literature there is little data and not completely indicative, in the biological fluids and organs the amounts of released metals are different. This is also due to the fact that cobalt and chromium blood levels can change depending on physical and working activity, individual feeding and metabolism. The results obtained confirm the presence of an increase of cobalt inthe blood of patients after total hip replacement, while the chromium levels are almost alike: average values in patients operated are 4.1 +/- 1.5 microg/L for cobalt (0.3 +/- 0.1 microg/L in the control group) and 4.5 +/- 2.9 microg/L for chromium (4.7 +/- 2.4 microg/L in the control group). In spite of the cobalt values stand below the concentration generally considered dangerous, the difference between the two examined groups points out that a risk exists for the health of these patients. These results must be confirmed by further studies, providing better information and more reliable and biocompatible materials.  相似文献   
9.
The synthesis and application of three examples of a new class of chiral (C(2)) atropisomeric diphosphines characterized by two interconnected five-membered heteroaromatic rings, with hindered rotation around the interanular bond, are described. Optically pure (+)- and (-)-2,2'-bis(diphenylphosphino)-4,4',6,6'-tetramethyl-3,3'-bibenzo[b]thiophene (tetraMe-bitianp) (1a) and the parent unsubstituted system (+)- and (-)-bitianp (1b) were synthesized. They were found to be optically stable at 100 degrees C and were successfully employed as ligands in the Ru(II)-catalyzed hydrogenation of alpha- and beta-oxo esters to the corresponding alpha- and beta-hydroxy esters and in the hydrogenation of olefinic substrates. The optical and chemical yields were comparable with those reported for the same Ru(II)-binap-catalyzed reactions carried out under the same experimental conditions. The 2,2'-bis(diphenylphosphino)-3,3'-bibenzo[b]furan (1c), the oxygenated analogue of bitianp, was found to be configurationally unstable at room temperature. Complete structural X-ray elucidation of the Pd complexes of 1a-c is reported. The advantages of these biheteroaromatic ligands over the classical biaryl systems are discussed.  相似文献   
10.
Here we show that many numerical computations and bounds on the degrees of the algebraic leaves for singular meromorphic foliations on 2 may be extended to large classes of foliations and complex projective surfaces.The author was partially supported by MURST and GNSAGA of CNR (Italy)  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号