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Lyakhova E. G. Fedorov S. N. Shubina L. K. Radchenko O. S. Kalinovsky A. I. Dvitrenok P. S. Stonik V. A. 《Russian Chemical Bulletin》2003,52(4):1022-1026
The structures of products obtained by reductive debromination and CF3COOH- and KOH-induced transformations of natural chamigrane-type sesquiterpenoid (6S,10R)-10-bromo-3,11,11-trimethyl-7-methylidenespiro[5,5]undec-2-en-4-one (dactylone) isolated from the sea hare Aplysia dactylomela were analyzed. The absolute configurations of the reaction products were established by CD spectra taking into account the configuration of the starting dactylone. 相似文献
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