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Linko R. V. Polyanskaya N. A. Ryabov M. A. Sergienko V. S. Strashnov P. V. Davydov V. V. Drogova G. M. 《Russian Journal of Coordination Chemistry》2019,45(1):1-10
Russian Journal of Coordination Chemistry - The complexes of (Z)-10-(2-(4-amino-5-thioxo-4,5-dihydro-1Н-1,2,4-triazol-3-yl)hydrazono)-9-phenanthrone (HL) with the Co(II), Ni(II), and Cu(II)... 相似文献
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V. I. Sokol V. B. Kvartalov N. M. Kolyadina V. S. Sergienko A. T. Soldatenkov V. V. Davydov G. M. Drogova 《Russian Journal of Inorganic Chemistry》2014,59(10):1094-1100
The complexes [Cu(L)(H2O)](ClO4)2 · 2H2O (I) and [Zn(L)Cl2] · C2H5OH (II), where L is the macrocyclic substituted aza-14-crown-4 ether molecule containing di(α-pyridyl)bispidine insert, were synthesized and studied by X-ray diffraction. The Cu atoms in complex I and the Zn atoms in complex II have equal coordination numbers of 5 and different highly distorted polyhedra (the CuN4O tetragonal pyramid and ZnN3Cl2 trigonal bipyramid). Ligand L in structure I performs the tetradentate tetrachelate (4N) structural function and in II, it performs the tridentate bis-chelate (3N) function. The key difference between the structures of complexes I and II is determined by different conformations of both the aza-macrocycles and bispidine substituents of ligand L. 相似文献
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