排序方式: 共有27条查询结果,搜索用时 15 毫秒
1.
Mori Toshiyuki Drennan John Wang Yarong Li Ji-Guang Ikegami Takayasu 《Journal of Thermal Analysis and Calorimetry》2002,70(2):309-319
Doped ceria (CeO2) compounds are fluorite type oxides that show oxygen ionic conductivity higher than yttria stabilized zirconia, in oxidizing
atmosphere. In order to improve the conductivity, the effective index was suggested to maximize the oxygen ionic conductivity
in doped CeO2 based oxides. In addition, the true microstructure of doped CeO2 was observed at atomic scale for conclusion of conduction mechanism. Doped CeO2 had small domains (10-50 nm) with ordered structure in a grain. It is found that the electrolytic properties strongly depended
on the nano-structural feature at atomic scale in doped CeO2 electrolyte.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
2.
The cathode–electrolyte interface in a solid oxide fuel cell is examined to understand why premature delamination is observed in alumina substituted YSZ electrolyte. From XRD, SEM and TEM observations it was concluded that after high temperature sintering a tetragonal (Mn,Al)3O4 forms at the interface, which during prolonged fuel cell operation forms a cubic (Mn,Al)3O4 phase. This transformation is associated with volume decrease creating voids which ultimately weaken the cathode–electrolyte interface sufficiently for the cathode layer to delaminate off the YSZ–Al2O3 electrolyte. 相似文献
3.
Nicholas C. Harris David A. Born Wenlong Cai Yaobing Huang Joelle Martin Ryan Khalaf Catherine L. Drennan Wenjun Zhang 《Angewandte Chemie (International ed. in English)》2018,57(31):9707-9710
The electron‐rich isonitrile is an important functionality in bioactive natural products, but its biosynthesis has been restricted to the IsnA family of isonitrile synthases. We herein provide the first structural and biochemical evidence of an alternative mechanism for isonitrile formation. ScoE, a putative non‐heme iron(II)‐dependent enzyme from Streptomyces coeruleorubidus, was shown to catalyze the conversion of (R)‐3‐((carboxymethyl)amino)butanoic acid to (R)‐3‐isocyanobutanoic acid through an oxidative decarboxylation mechanism. This work further provides a revised scheme for the biosynthesis of a unique class of isonitrile lipopeptides, of which several members are critical for the virulence of pathogenic mycobacteria. 相似文献
4.
Zhi-Peng Li Toshiyuki Mori Jin Zou John Drennan 《Journal of solid state chemistry》2011,184(9):2458-2461
Analytical transmission electron microscopy, in particular with the combination of energy dispersive X-ray spectroscopy (EDX) and electron energy-loss spectroscopy (EELS), has been performed to investigate the microstructure and microchemistry of the interfacial region between the cathode (La0.6Sr0.4Co0.8Fe0.2O3, LSCF) and the electrolyte (Gd-doped ceria, GDC). Two types of diffusions, mutual diffusion between cathode and electrolyte as well as the diffusion along grain boundaries, have been clarified. These diffusions suggest that the chemical stability of LSCF and GDC are not as good as previously reported. The results are more noteworthy if we take into consideration the fact that such interdiffusions occur even during the sintering process of cell preparation. 相似文献
5.
6.
7.
Pei Yuan Lingzhi Zhao Nian Liu Guangfeng Wei Yunhua Wang Prof. Graeme J. Auchterlonie J. Drennan Prof. Gao Qing Lu Prof. Jin Zou Prof. Chengzhong Yu Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(5):1629-1637
An intriguing evolution from a simple internal helix to a hierarchical helical (HH) mesostructure with both internal and external helices or a complicated screwlike and concentric circular (CC) mesostructure is successfully observed. The complicated helical structures are determined by TEM studies and 3D electron tomography. We demonstrate a topological helix–coil transition between the internal and external helices to reveal the origin of the HH mesostructure and the relationship between the straight helical and HH rods. Moreover, the boundary condition of the helix–coil transition is clarified to explain in detail the formation of complex helical structures, such as the screwlike mesostructure. It is proposed that the final structural characteristics are determined exactly by the balance between the decrease in the surface free energy and the maintenance of the hexagonal packing in one individual rod, which explains the formation of unusual CC, HH, and screwlike morphologies in one pot. Our success has opened new opportunities in the characterization of complex porous architectures, thus paving a way to remarkable advances in the fields of synthesis, understanding, and application of novel porous materials. 相似文献
8.
Ruth Knibbe Kazuhiro Nogita John Drennan Tsuneyuki Noguchi Katsuyoshi Tatenuma Pou Liu Fumihito Arai Eiji Yashima Michiru Nishiwaki Shigeki Kato 《Journal of nanoparticle research》2007,9(6):1201-1204
Multi-wall carbon nanotubes (MWNTs) have a great commercial potential as electron field emitters, but suffer from fundamental
problems such as stability and brightness. By depositing the MWNTs with nano-sized ruthenium dioxide (RuO2) particles, a new high performance emitter has been developed. When compared to MWNTs, the MWNTs impregnated with 1–2 nm
sized RuO2 have superior and more efficient electrical characteristics. MWNTs supported by a silicon substrate showed a reduction in
the onset voltage from 5.4 to 4 V/μm after RuO2 impregnation. The long-term stability of the impregnated MWNTs is also demonstrated with only a 20% increase in applied voltage
required after 700 h operation at 40 mA/cm2. 相似文献
9.
10.
Atomistic simulation based on an energy minimization technique has been carried out to investigate defect clusters of R(2)O(3) (R = La, Pr, Nd, Sm, Gd, Dy, Y, Yb) solid solutions in fluorite CeO(2). Defect clusters composed of up to six oxygen vacancies and twelve accompanied dopant cations have been simulated and compared. The binding energy of defect clusters increases as a function of the cluster size. A highly symmetric dumbbell structure can be formed by six oxygen vacancies, which is considered as a basic building block for larger defect clusters. This is also believed to be a universal vacancy structure in an oxygen-deficient fluorite lattice. Nevertheless, the accurate positions of associated dopants depend on the dopant radius. As a consequence, the correlation between dopant size and oxygen-ion conductivity has been elucidated based on the ordered defect cluster model. This study sheds light on the choice of dopants from a physical perspective, and suggests the possibility of searching for optimal solid electrolyte materials through atomistic simulations. 相似文献