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1.
2.
Coherent neutron scattering lengths and total cross sections have been measured on elemental and oxide samples of ordinary Ge and of isotopically enriched substances. From the experimental results the following values were obtained: the coherent scattering lengths (in fm) of the bound atoms Ge(8.185±0.020);70Ge(10.0±0.1);72Ge(8.51±0.10);73Ge(5.02±0.04);74Ge(7.58±0.10) and76Ge(8.2 ±1.5); the absorption cross sections at 0.0253 eV (in barn) for Ge(2.20±0.04);70Ge(2.9±0.2);72Ge(0.8±0.2);73Ge(14.4±0.4) and74Ge(0.4±0.2); the free cross sections for epithermal neutrons and the zero energy scattering cross sections. On the basis of this data, the isotopic- and spin-incoherent cross sections and thes-wave resonance contributions to the coherent scattering lengths have been determined and discussed. Transmission measurements at 0.57 meV on amorphous and crystalline GeO2 yielded for the amorphous sample an inelastic cross section eight times larger than for the crystalline samples. This effect corresponds to a clearly higher density of low energy states in the amorphous than in the crystalline substances. 相似文献
3.
Gerhard Buchbauer Waltraud Pernold Dorothea Rassl Brigitte Blach 《Monatshefte für Chemie / Chemical Monthly》1981,112(4):517-527
The synthesis of some new potentially, nitrogenefree spasmolytics is described. Formally the benzene nucleus in some mandelic acid esters, known by their mild spasmolytic activity, is substituted for the isocamphane bicyclus by a) SeO2 oxidation of 1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone (5) to the corresponding ketoaldehyde6, b) oxidation of6 to the isocamphane analogous mandelic acid4 and c) esterification of derivatives of4 with isoamylalcohol and benzylalcohol. Attemps to dehydrate the methylester7 to camphenylideneacetic acid methylester (12) by various methods failed, probably because of the ring strain.
Teil der Diplomarbeit vonB. Blach, Universität Wien 1981. 相似文献
4.
Total cross section measurements at various neutron energies were performed on metallic and oxide samples of natural Sc, Ti, V, and Mn. By means of the Christiansen filter technique the coherent scattering lengths were determined on natural and isotopically enriched samples of Ti-, V-, and Mn-compounds. From the measured values we deduced the following data: ? the absorption cross sections (at 0.0253 eV in barn) ofnatTi (6.43±0.06) and ofnatV (5.06±0.04); ? the bound coherent scattering lengths (in fm) ofnatTi (?3.370±0.013),46Ti (4.72±0.05),47Ti (3.53±0.07),48Ti (?5.86±0.02),49Ti (0.98±0.05),50Ti (5.88±0.10),natV (?0.443±0.014), and Mn (?3.750±0.018); ? the free potential radii (in fm) of Sc (3.60 ±0.10),46Ti (3.50±0.10),47Ti (3.60±0.10),48Ti (3.90±0.10),49Ti (4.10 ±0.15),50Ti (4.50±0.15),51V (5.20±0.20), and Mn (6.50±20). On the basis of the well known resonance parameters in combination with new fits of bound levels the spin state scattering lengths, the spin incoherence, and the obtained potential radii are discussed. Total cross section calculations were performed by multi-level formalism and are compared with the measurements. 相似文献
5.
A chiral supramolecular assembly encapsulates the two cationic ruthenium sandwich complexes [CpRu(eta(6)-C(6)H(6))](+) and [CpRu(p-cymene)](+). The host-guest complexes K(11)[CpRu(eta(6)-C(6)H(6)) subset Ga(4)L(6)] (2) and K(11)[CpRu(p-cymene) subset Ga(4)L(6)] (3) were characterized by one- and two-dimensional NMR techniques as well as by electrospray mass spectrometry. Encapsulation of the prochiral complex [CpRu(p-cymene)](+) by the chiral host renders enantiotopic protons diastereotopic as evidenced by (1)H NMR spectroscopy. 相似文献
6.
L. Koester K. Knopf W. Waschkowski A. Klüver 《Zeitschrift für Physik A Hadrons and Nuclei》1985,320(4):661-668
Coherent neutron scattering lengths and total cross sections have been measured for elemental Zn,Zn-compounds and on isotopicly enriched samples for neutron energies from 0.5 meV up to 143 keV using different techniques. From the experimental data the following quantities were obtained: the coherent scattering lengths (b in fm) of Zn (5.689±0.014);64Zn (5.23±0.04);66Zn (5.98±0.05);67Zn (7.58±0.08;b +=9.4±0.5/5.8±0.5;b ?=5.0±0.7/10.1±0.7);68Zn (6.04 ±0.03); the potential scattering radii (R′ in fm) of Zn (6.2±0.2),64Zn (6.0±0.3) and66Zn (6.2 ±0.3); the absorption cross sections (σ γ at 0.025 eV in barn) of Zn (1.11±0.02);64Zn (1.1 ±0.1) and66Zn (0.62±0.06). Derived quantities are the “zero energy” scattering cross sections (σ 0 in barn) for Zn (4.128±0.010) and67Zn (7.8±0.3) and the incoherent bound cross sections of Zn (0.061 ±0.023) and67Zn (0.6±0.4). In the epithermal region the Zn-cross section can be described by introduction of two strong bound levels of67Zn+n for which estimated parameters are given. 相似文献
7.
Fiedler D Leung DH Bergman RG Raymond KN 《Journal of the American Chemical Society》2004,126(12):3674-3675
A supramolecular metal-ligand assembly encapsulates a variety of cationic half-sandwich ruthenium complexes. Due to the chirality of both host and guest, chiral recognition is observed with diastereomeric excesses up to 70%. The chiral cavity can be used to carry out a dynamic resolution of the rapidly equilibrating enantiomers of the chiral organometallic guest. 相似文献
8.
9.
Niko Kivel Dorothea Schumann Ines Günther-Leopold 《Analytical and bioanalytical chemistry》2013,405(9):2965-2972
In many scientific fields, the half-life of radionuclides plays an important role. The accurate knowledge of this parameter has direct impact on, e.g., age determination of archeological artifacts and of the elemental synthesis in the universe. In order to derive the half-life of a long-lived radionuclide, the activity and the absolute number of atoms have to be analyzed. Whereas conventional radiation measurement methods are typically applied for activity determinations, the latter can be determined with high accuracy by mass spectrometric techniques. Over the past years, the half-lives of several radionuclides have been specified by means of multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) complementary to the earlier reported values mainly derived by accelerator mass spectrometry. The present paper discusses all critical aspects (amount of material, radiochemical sample preparation, interference correction, isotope dilution mass spectrometry, calculation of measurement uncertainty) for a precise analysis of the number of atoms by MC-ICP-MS exemplified for the recently published half-life determination of $^{60}$ Fe (Rugel et al, Phys Rev Lett 103:072502, 2009). 相似文献
10.