A preemptive repeat priority queue with resampling: Performance analysis

In this paper, we analyze a discrete-time preemptive repeat priority queue with resampling. High-priority packets have preemptive repeat priority, and interrupted low-priority packets are subjected to independent retransmission attempts. Both classes contain packets with generally distributed transmission times. We show that the use of generating functions is beneficial for analyzing the system contents and packet delay of both classes. The influence of the priority scheduling on the performance measures is illustrated by some numerical examples. This work has been supported by the Interuniversity Attraction Poles Programme–Belgian Science Policy.     

Analytic study of multiserver buffers with two-state Markovian arrivals and constant service times of multiple slots

In this paper, we study the behavior of a discrete-time multiserver buffer system with infinite buffer size. Packets arrive at the system according to a two-state Markovian arrival process. The service times of the packets are assumed to be constant, equal to multiple slots. The behavior of the system is analyzed by means of an analytical technique based on probability generating functions (PGF’s). Explicit expressions are obtained for the PGF’s of the system contents and the packet delay. From these, the mean values, the variances and the tail distributions of the system contents and the packet delay are calculated. Numerical examples are given to show the influence of various model parameters on the system behavior.     

Blends of carbon blacks and multiwall carbon nanotubes as reinforcing fillers for hydrocarbon rubbers

The reinforcement of a styrene‐butadiene rubber (SBR) by single fillers—carbon black (CB) or multiwall carbon nanotubes (MWNTs)—or by mixtures of CB and MWNTs, is investigated. The morphologies, mechanical and electrical properties of the composites, are analyzed. A significant improvement in the tensile properties is observed for samples containing a dual phase. Using atomic force (AFM) and transmission electron (TEM) microscopies, we demonstrate that the double loading improves the dispersion of the nanotubes in SBR. Electrical measurements show lower resistivity and a lower percolation threshhold for composites containing blends of fillers, which provides further evidence of better dispersion. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 46: 1939–1951, 2008     

A modified HOL priority scheduling discipline: Performance analysis

In this paper, we introduce and analyze a modified HOL (head-of-the-line) priority scheduling discipline. The modification is incorporated to cope with the so-called starvation problem of regular HOL priority queues. We consider a discrete-time single-server queueing system with two priority queues of infinite capacity and with the introduced priority scheme. We show that the use of probability generating functions is suitable for analyzing the system contents and the packet delay. Some performance measures (such as means and variances) of these stochastic quantities will be derived. Furthermore, approximate expressions of the tail probabilities are obtained from the probability generating functions, by means of the dominant-singularity method. These expressions, together with their characteristics, constitute one of the main contributions of this paper. Finally, the impact and significance of the m-HOL (modified HOL) priority scheduling on these performance measures is illustrated by some numerical examples.     

Organocatalytic functionalization of carboxylic acids: isothiourea-catalyzed asymmetric intra- and intermolecular Michael addition--lactonizations

Tetramisole promotes the catalytic asymmetric intramolecular Michael addition-lactonization of a variety of enone acids, giving carbo- and heterocyclic products with high diastereo- and enantiocontrol (up to 99:1 dr, up to 99% ee) that are readily derivatized to afford functionalized indene and dihydrobenzofuran carboxylates. Chiral isothioureas also promote the catalytic asymmetric intermolecular Michael addition-lactonization of arylacetic acids and α-keto-β,γ-unsaturated esters, giving anti-dihydropyranones with high diastereo- and enantiocontrol (up to 98:2 dr, up to 99% ee).     

Structure-enantioselectivity effects in 3,4-dihydropyrimido[2,1-b]benzothiazole-based isothioureas as enantioselective acylation catalysts

The catalytic activity and enantioselectivity in the kinetic resolution of (±)-1-naphthylethanol with a range of structurally related 3,4-dihydropyrimido[2,1-b]benzothiazole-based catalysts is examined. Of the isothiourea catalysts screened, (2S,3R)-2-phenyl-3-isopropyl substitution proved optimal, giving good levels of selectivity in the kinetic resolution of a number of secondary alcohols (S values up to >100 at ~50% conversion). Low catalyst loadings (0.10-0.25 mol%) of the optimal isothiourea can be used to generate enantiopure alcohols (>99% ee) in good yields.     

Correlation between boson peak and anomalous elastic behavior in GeO2 glass: an in situ Raman scattering study under high-pressure

We present low-frequency Raman scattering of pure GeO(2) glass under pressure up to 4 GPa, corresponding to an elastic transformation. Intensity variation and frequency shift of the boson peak are analysed and compared to the Debye model. The decrease of the boson peak intensity scaled by the Debye energy is correlated to the elastic anomalous properties under pressure up to 1.5 GPa, and interpreted as an elastic homogenisation process at the local scale. We emphasize similarities between a-GeO(2) and a-SiO(2) behavior under pressure, and compare our results to other experiments, numerical studies, and predictions of several models concerning amorphous systems.     

The discrete-time preemptive repeat identical priority queue

Priority queueing systems come natural when customers with diversified delay requirements have to wait to get service. The customers that cannot tolerate but small delays get service priority over customers which are less delay-sensitive. In this contribution, we analyze a discrete-time two-class preemptive repeat identical priority queue with infinite buffer space and generally distributed service times. Newly arriving high-priority customers interrupt the on-going service of a low-priority customer. After all high-priority customers have left the system, the interrupted service of the low-priority customer has to be repeated completely. By means of a probability generating functions approach, we analyze the system content and the delay of both types of customers. Performance measures (such as means and variances) are calculated and the impact of the priority scheduling is discussed by means of some numerical examples.     

Queueing systems with different types of server interruptions

We consider a queueing system with disruptive and non-disruptive server interruptions. Both disruptive and non-disruptive interruptions may start when there is a customer in service. The customer repeats its service after a disruptive interruption, and continues its service after a non-disruptive interruption. Using a transform approach, we obtain various performance measures such as the moments of the queue content and waiting times. We illustrate our approach by means of some numerical examples.