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1.
Morteza Bahram Khalil Farhadi Abbas Afkhami Donya Shokatynia Farzin Arjmand 《Central European Journal of Chemistry》2009,7(3):375-381
A partial least squares (PLS-1) calibration model based on kinetic—spectrophotometric measurement, for the simultaneous determination
of Cu(II), Ni(II) and Co(II) ions is described. The method was based on the difference in the rate of the reaction between
Co(II), Ni(II) and Cu(II) ions with 1-(2-pyridylazo)2-naphthol in a pH 5.8 buffer solution and in micellar media at 25°C.
The absorption kinetic profiles of the solutions were monitored by measuring the absorbance at 570 nm at 2 s intervals during
the time range of 0–10 min after initiation of the reaction. The experimental calibration matrix for the partial least squares
(PLS-1) model was designed with 30 samples. The cross-validation method was used for selecting the number of factors. The
results showed that simultaneous determination could be performed in the range 0.1-2 μg mL−1 for each cation. The proposed method was successfully applied to the simultaneous determination of Cu(II), Ni(II) and Co(II)
ions in water and in synthetic alloy samples.
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2.
Central composite design (CCD) and response surface methodology (RSM) were developed as experimental strategies for modeling and optimization of the influence of some variables on the performance of a new PVC membrane triiodide ion-selective electrode. This triiodide sensor is based on triiodide-clozapine ion-pair complexation. PVC, plasticizers, ion-pair amounts and pH were investigated as four variables to build a model to achieve the best Nernstian slope (59.9 mV) as response. The electrode is prepared by incorporating the ion-exchanger in PVC matrix plasticized with 2-nitrophenyl octal ether, which is directly coated on the surface of a graphite electrode. The influence of foreign ions on the electrode performance was also investigated. The optimized membranes demonstrate Nernstian response for triiodide ions over a wide linear range from 5.0 x 10(-6) to 1.0 x 10(-2)mol L(-1) with a limit of detection 2.0 x 10(-6) mol L(-1) at 25 degrees C. The electrodes could be used over a wide pH range 4-8, and have the advantages of easy to prepare, good selectivity and fast response time, long lifetime (over 3 months) and small interferences from hydrogen ion. The proposed electrode was successfully used as indicator electrode in potentiometric titration of triiodide ions and ascorbic acid. 相似文献
3.
Hassan Mallaekeh Alireza Shams Mohammad Shaker Ehsan Bahramzadeh Donya Arefi 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(12):2081-2086
In this paper the complexation reaction of the 5,5′-(2E,2′E)-2,2′-(ethane-1,2-diylidene)bis(hydrazine-1-yl-2-ylidene)bis(4-amino-4H-1,2,4-triazole-3-thiol) ligand (HYT) with Cd2+ education was studied in some binary mixtures of methanol (MeOH), n-propanol (PrOH) and dimethyl-formamide (DMF) at different temperatures using the conductometry and spectrophotometry. The stability constants of the complex was determined using a GENPLOT computer program. The conductance data and absorbance-mole ratio plots show that in all solvent systems, the stoichiometry of the complex formed between (HYT) and Cd2+ cation is 1: 1. The obtained results show that the stability of (HYT)-Cd complex is sensitive to the mixed solvents composition. The values of thermodynamic parameters (ΔG °, ΔH °, and ΔS °) for formation of (HYT)-Cd complex were obtained from temperature dependence of the stability constant using the van’t Hoff plots. The results show that in most cases, the complex are enthalpy destabilized but entropy stabilized and the complex formation is affected by pH, time, temperature and the nature of the solvent. 相似文献
4.
A. R. El-Sersy A. Hussein H. M. El-samman N. E. Khaled A. El-Adawy H. Donya 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(1):65-69
The total mass attenuation coefficients, partial interaction and the effective atomic numbers (Zeff) of glass system (80−x)B2O3–10Al2O3–10SiO2–xCaF2 (where x = 5, 10, 20, 25, 30, 35 and 40 mol %) have been calculated at photon energies 0.662 and 1.25 MeV using the WinXCom software
on the basis of mixture rule. Results indicated that the total mass attenuation coefficients showed a decrease with increasing
the CaF2 concentration, due to a decrease in Compton scattering probability, which gave a dominant contribution to the total mass
attenuation coefficients for the studied glass samples at both energies. However, the photoelectric absorption and coherent
scattering showed an increase with increasing the CaF2, concentrations at same energies. For a comparison, the total mass attenuation coefficients of the glass system had lower
values at the energy 1.25 MeV than that at 0.662 MeV. Zeff was found to increase linearly with the increase of CaF2 concentrations. It was concluded that low CaF2 concentrations in glass system, under study, have Zeff close to that of human tissue and have higher total absorption coefficients at energy of 0.662 MeV than that at 1.25 MeV.
These results are very useful in designing gamma radiation detectors using thermoluminescence technique. Therefore, it is
recommended to use low CaF2 concentration of our glass system as good gamma detectors at energy of 1.25 MeV. 相似文献
5.
Well-dispersed palladium nanoparticles immobilized onto modified silica(SiO 2-pr-NH-cyanuric-SH) have been prepared in some facile steps.The catalyst exhibits high catalytic activity in the Heck reaction,and can be easily recovered and reused without significant loss of its activity in several runs. 相似文献
6.
Donya Rahmani Reza Ramezanian Parviz Fattahi Mahdi Heydari 《Applied Mathematical Modelling》2013,37(20-21):8957-8971
Production planning (PP) is one of the most important issues carried out in manufacturing environments which seeks efficient planning, scheduling and coordination of all production activities that optimizes the company’s objectives. In this paper, we studied a two-stage real world capacitated production system with lead time and setup decisions in which some parameters such as production costs and customer demand are uncertain. A robust optimization model is developed to formulate the problem in which minimization of the total costs including the setup costs, production costs, labor costs, inventory costs, and workforce changing costs is considered as performance measure. The robust approach is used to reduce the effects of fluctuations of the uncertain parameters with regards to all the possible future scenarios. A mixed-integer programming (MIP) model is developed to formulate the related robust production planning problem. In fact the robust proposed model is presented to generate an initial robust schedule. The performance of this schedule could be improved against of any possible occurrences of uncertain parameters. A case from an Iran refrigerator factory is studied and the characteristics of factory and its products are discussed. The computational results display the robustness and effectiveness of the model and highlight the importance of using robust optimization approach in generating more robust production plans in the uncertain environments. The tradeoff between solution robustness and model robustness is also analyzed. 相似文献
7.
Razieh Sanavi Khoshnood Elaheh Hatami Donya Arefi Fatemeh Zahra Maknoni 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(2):308-317
In the present work the complexation process between Ag+ and Mg2+ cations and 4-hydroxyphenyl-2,5-bis(2-benzofuranyl)pyridine (HBFPY) ligand was studied in pure dimethylformamide (DMF), ethanol (EtOH), acetonitrile (AN) and in (DMF-EtOH), (AN-EtOH) and (DMF-AN) binary mixed solvent solutions at different temperatures using the conductometric method. Also in this work the complexation reaction between Ca2+, K+ cations and HBFPY ligand, was studied in pure dimethylformamide (DMF), propanol (PrOH), 1,4-dioxane (DOX), ethanol (EtOH) and in DMF-PrOH, DMF-DOX and DMF-EtOH binary mixed solvent solutions at different temperatures using the conductometric method. The conductance data show that the stoichiometry of the complexes formed between this ligand and the studied cations is 1 : 1 [ML]. In most cases, addition of HBFPY to solutions of these cations, causes a continuous increase in the molar conductivities which indicates that the mobility of complexed cations is more than the uncomplexed ones. The stability constants of the complexes were obtained from fitting of molar conductivity curves using a computer program, GENPLOT. The stability constant of [Mg(HBFPY)]2+ complex in various neat solvents at 15°C decreases in order: EtOH > DMF > AN and the stability constant of [Ag(HBFPY)]+ complex in various neat solvents at 35°C decreases in order: DMF > EtOH. The values of standard enthalpy changes (ΔH° c ) for complexation reactions were obtained from the slope of the Van’t Hoff plots and the changes in standard entropy (ΔS° c ) were calculated from the relationship ΔH° c,295.15= ΔH° c –298.15ΔS° c . 相似文献
8.
Saeedeh Sepehrikia Donya Arefi Alireza Shams 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(13):2462-2465
Fluorescence quantum yield of two novel compounds—dibenzo[c,k]-1,2-dithia-6,9-diazacyclododecane-5,10-dione (1) and dibenzo[c,k]-1,2-dithia-6,9-diaza-7-methylcyclododecane-5,10-dione (2) was studied by Williams method using anthracene as a reference. 相似文献
9.
A new method is described for the oxidative chlorination of thiols to sulfonyl chlorides using titanium tetrachloride in combination with the oxidant hydrogen peroxide. Direct conversion of thiols into their corresponding thiosulfonates is also reported. Good to excellent yields, short reaction times, high efficiencies, cost-effectiveness, and, facile isolation of the desired products make the present methodology a practical alternative. 相似文献
10.
Modifications to the traditional Onsager theory for modeling isotropic–nematic phase transitions in hard prolate spheroidal systems are presented. Pure component systems are used to identify the need to update the Lee–Parsons resummation term. The Lee–Parsons resummation term uses the Carnahan–Starling equation of state to approximate higher-order virial coefficients beyond the second virial coefficient employed in Onsager’s original theoretical approach. As more exact ways of calculating the excluded volume of two hard prolate spheroids of a given orientation are used, the division of the excluded volume by eight, which is an empirical correction used in the original Lee–Parsons resummation term, must be replaced by six to yield a better match between the theoretical and simulation results. These modifications are also extended to binary mixtures of hard prolate spheroids using the Boublík–Mansoori–Carnahan–Starling–Leland (BMCSL) equation of state. 相似文献