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排序方式: 共有78条查询结果,搜索用时 31 毫秒
2.
Zhicheng Xiao Ying Li Dongling Ma Linda S. Schadler Yvonne A. Akpalu 《Journal of Polymer Science.Polymer Physics》2006,44(7):1084-1095
Small‐angle light scattering (SALS) measurements were used to study the structure of titanium dioxide (TiO2)/low‐density polyethylene (LDPE) nanocomposites. The results showed that the scattering from LDPE crystalline structures and the scattering from TiO2 nanoparticles can be resolved and separated. It is shown that the independent effects of crystallization conditions and the presence of nanoparticle aggregates on the spherulitic structure of the LDPE matrix can be determined by analyzing the scattering patterns using the methods proposed. From the SALS results, we conclude that the nanoparticle surface chemistry affects both nucleation of spherulites and their structure particularly under rapid cooling conditions. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 1084–1095, 2006 相似文献
3.
工业废水中微量铜(Ⅱ)和氰化物的流动注射光度分析 总被引:2,自引:0,他引:2
采用FIA技术,以光度比色法为基础,建立了工业废水中微量Cu^2+和CN^-的顺序自动分析方法和装置。其对二种离子的测定频率为60样/h,相对标准偏差<1.0%,工作曲线的r值≥0.999,各项分析技术指标均优于手工法操作。 相似文献
4.
Semiconductor and Metallic Core–Shell Nanostructures: Synthesis and Applications in Solar Cells and Catalysis 下载免费PDF全文
Dr. Mee Rahn Kim Dr. Zhenhe Xu Dr. Guozhu Chen Prof. Dr. Dongling Ma 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(36):11256-11275
Nano‐heterostructures have attracted great attention due to their extraordinary properties beyond those of their single‐component counterparts. This review focuses on a specific type of hybrid structures: core–shell structures. In particular, we present and discuss the recent wet‐chemical synthesis approaches for semiconductor and metallic core–shell nanostructures, and their relevant properties and potential applications in photovoltaics and catalysis, respectively. 相似文献
5.
Dongling Zhou Dr. Wai-Pong To Dr. Glenna So Ming Tong Dr. Gang Cheng Dr. Lili Du Prof. Dr. David Lee Phillips Prof. Dr. Chi-Ming Che 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6437-6444
Structurally robust tetradentate gold(III)-emitters have potent material applications but are rare and unprecedented for those displaying thermally activated delayed fluorescence (TADF). Herein, a novel synthetic route leading to the preparation of highly emissive, charge-neutral tetradentate [C^C^N^C] gold(III) complexes with 5-5-6-membered chelate rings has been developed through microwave-assisted C−H bond activation. These complexes show high thermal stability and with emission origin (3IL, 3ILCT, and TADF) tuned by varying the substituents of the C^C^N^C ligand. With phenoxazine/diphenylamine substituent, we prepared the first tetradentate gold(III) complexes that are TADF emitters with emission quantum yields of up to 94 % and emission lifetimes of down to 0.62 μs in deoxygenated toluene. These tetradentate AuIII TADF emitters showed good performance in vacuum-deposited OLEDs with maximum EQEs of up to 25 % and LT95 of up to 5280 h at 100 cd m−2. 相似文献
6.
ABSTRACT The microstructure evolution and property change of four kinds of low silicon cast aluminum alloy exposed to heat for 0–50?h at 200°C were studied by means of Brinell hardness test, tensile property test, friction and wear property test and XRD analysis. The results show that with increasing thermal exposure time, the tensile strength of each group of samples decreased and the amount of wear increased. The tensile strength of samples with more Si content decreased slowly. When the time increased to 50?h, the increase of wear loss was the largest. The hardness of samples after thermal exposure increases compared with that before thermal exposure. The residual stress of (311) diffraction crystal surface of AlSi3.5Mg0.66 under different thermal exposure time was measured. The type of residual stress changed from residual tensile stress to residual compressive stress after thermal exposure. There is an abnormal phenomenon that the hardness of the sample increased and the amount of wear increased, and it is evident that the distribution of residual stress was inhomogeneous after thermal exposure. It is found that with increasing thermal exposure time to 50?h, the average lattice distortion ε of the low-index crystal plane and the high-index crystal plane in the aluminum alloys gradually increased. 相似文献
7.
Lei Sun Tian Du Cheng Wang Prof. Dongling Geng Dr. Lin Li Prof. Yang Han Prof. Yunfeng Deng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(69):17437-17443
Low-bandgap organic semiconductors have attracted much attention for their multiple applications in optoelectronics. However, the realization of narrow bandgap is challenging particularly for small molecules. Herein, we have synthesized four quinoidal compounds, i. e., QSN3 , QSN4 , QSN5 and QSN6 , with electron rich S,N-heteroacene as the quinoidal core and indandione as the end-groups. The optical bandgap of the quinoidal compounds is systematically decreased with the extension of quinoidal skeleton, while maintaining stable closed-shell ground state. QSN6 absorbs an intense absorption in the first and second near-infrared region in the solid state, and has extremely low optical bandgap of 0.74 eV. Cyclic voltammetry analyses reveal that the lowest unoccupied molecular orbital (LUMO) energy levels of the four quinoidal compounds all lie below −4.1 eV, resulting in good electron-transporting characteristics in organic thin-film transistors. These results demonstrated that the combination of π-extended quinoidal core and end-groups in quinoidal compounds is an effective strategy for the synthesis of low-bandgap small molecules with good stability. 相似文献
8.
Na Zhao Liansong Wang Dongling Huang Tianyao Zhang Lifang Zhang Chengdong Xiong 《Crystal Research and Technology》2010,45(3):275-280
We investigated the effect of isothermal annealing on the degree of crystallinity and mechanical properties of a random copolymer‐poly(l‐lactide‐co ‐glycolide) (PLLGA)‐with monomer molar ratios of 85/15 (PLLGA85/15) by performing polarizing optical microscopy, differential scanning calorimetry, and X‐ray diffraction, and studying the tensile properties. Isothermal annealing of PLLGA at 130 °C was conducted to improve the degree of crystallinity of the copolymer; the maximum degree of crystallinity (44.5%) was achieved after 60 min of annealing. The crystal size/perfection was observed to increase with annealing time. The highest tensile strength of 65.8 MPa was achieved after 80 min of annealing. However, the degree of crystallinity and tensile strength can only reach to certain extent. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
9.
Lei Li & Dongling Wang 《计算数学(英文版)》2023,41(1):107-132
We introduce a new class of parametrized structure--preserving partitioned Runge-Kutta ($\alpha$-PRK) methods for Hamiltonian systems with holonomic constraints. The methods are symplectic for any fixed scalar parameter $\alpha$, and are reduced to the usual symplectic PRK methods like Shake-Rattle method or PRK schemes based on Lobatto IIIA-IIIB pairs when $\alpha=0$. We provide a new variational formulation for symplectic PRK schemes and use it to prove that the $\alpha$-PRK methods can preserve the quadratic invariants for Hamiltonian systems subject to holonomic constraints. Meanwhile, for any given consistent initial values $(p_{0}, q_0)$ and small step size $h>0$, it is proved that there exists $\alpha^*=\alpha(h, p_0, q_0)$ such that the Hamiltonian energy can also be exactly preserved at each step. Based on this, we propose some energy and quadratic invariants preserving $\alpha$-PRK methods. These $\alpha$-PRK methods are shown to have the same convergence rate as the usual PRK methods and perform very well in various numerical experiments. 相似文献
10.
Chen G Desinan S Nechache R Rosei R Rosei F Ma D 《Chemical communications (Cambridge, England)》2011,47(22):6308-6310
Core-shell structured Ni@Ru bimetallic nanoparticles are demonstrated as a bifunctional nanoplatform system for the hydrolysis reaction of ammonia-borane and also for magnetic separation. 相似文献