Transfer and Trapping of Resonance Radiation in a Two-Level System

Optics and Spectroscopy - The population kinetics of a two-level system has been theoretically investigated taking into account the transfer of spontaneous radiation under continuous optical...     

Triacetic acid lactone as a bioprivileged molecule in organic synthesis

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On a bifurcation governed by hysteresis nonlinearity

We consider autonomous systems with a nonlinear part depending on a parameter and study Hopf bifurcations at infinity. The nonlinear part consists of the nonlinear functional term and the Prandtl--Ishlinskii hysteresis term. The linear part of the system has a special form such that the close-loop system can be considered as a hysteresis perturbation of a quasilinear Hamiltonian system. The Hamiltonian system has a continuum of arbitrarily large cycles for each value of the parameter. We present sufficient conditions for the existence of bifurcation points for the non-Hamiltonian system with hysteresis. These bifurcation points are determined by simple characteristics of the hysteresis nonlinearity.     

New methods for determining the volumetric flow rate in the column and the retention time of the unretained substance in gas chromatography

New methods for calculating the mean volumetric flow rate of the carrier gas and the retention time of the unretained substance in the column under conditions of gas chromatography were proposed. The methods are based on preliminary isothermal calibrations of the flow rate and holdup time for a packed column. A theoretical substantiation of the methods was given. Procedures of plotting calibration dependences for determining the indicated quantities at a desired temperature were described. The calculation results were compared to experimental data obtained by traditional methods. It was demonstrated that the use of calculation methods substantially simplifies the determination of the specific retention volume over a wide temperature range.     

Coupling for Markov renewal processes and the rate of convergence in ergodic theorems for processes with semi-Markov switchings

Coupling procedures for Markov renewal processes are described. Applications to ergodic theorems for processes with semi-Markov switchings are considered.This paper was partly prepared with the support of NFR Grant F-UP 10257-300.     

Phenol biosensor based on electrochemically controlled integration of tyrosinase in a redox polymer

An amperometric biosensor for the detection of phenolic compounds was developed based on the immobilization of tyrosinase within an Os-complex functionalized electrodeposition polymer. Integration of tyrosinase within the redox polymer assures efficient catechol recycling between the enzyme and the polymer bound redox sites. The non-manual immobilization procedure improves the reproducibility of fabrication process, greatly reduces the desorption of the enzyme from the immobilization layer, and, most importantly prevents fast inactivation of the enzyme by its substrate due to fast redox cycling. A two-layer sensor architecture was developed involving ascorbic acid oxidase entrapped within an electrodeposition polymer in a second layer on top of the redox polymer/tyrosinase layer. Using this sensor architecture it was possible to eliminate the current interference arising from direct ascorbate oxidation up to a concentration of 630 μM ascorbic acid. The effects of the polymer thickness, the enzyme/polymer ratio, and the applied potential were evaluated with respect to optimal sensor properties. The sensitivity of the optimized sensors for catechol was 6.1 nA μM⁻¹ with a detection limit of 10 nM, and for phenol 0.15 nA μM⁻¹ with a detection limit of 100 nM.     

Power expansions for the self-similar solutions of the modified Sawada-Kotera equation

The fourth-order ordinary differential equation that defines the self-similar solutions of the Kaup—Kupershmidt and Sawada—Kotera equations is studied. This equation belongs to the class of fourth-order analogues of the Painlevé equations. All the power and non-power asymptotic forms and expansions near points z = 0, z = ∞ and near an arbitrary point z = z ₀ are found by means of power geometry methods. The exponential additions to the solutions of the studied equation are also determined.      

Properties of nonlinear waves in dissipative-dispersive media with instability

Wave processes in dissipative-dispersive media with instability described by a fourth-order nonlinear evolution equation are considered. Analytic solutions in the form of solitary and cnoidal waves are obtained. The existence of a critical value of the dispersion coefficient beyond which an initial disturbance (in particular, white noise) is transformed into a structure is demonstrated by numerical modeling.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 130–136, July–August, 1990.     

The adsorption of organic compounds on a modified carbon adsorbent Carbopack B

The thermodynamic characteristics of adsorption of several organic compounds on the carbon adsorbent Carbopack B before and after its modification by a monomolecular layer of cholesteryl-n-pentyl oxybenzoate were determined by gas chromatography. The initial adsorbent was close in its properties to graphitized carbon black. Modification weakened adsorbate-adsorbent attraction and increased the mobility of adsorbed molecules, to a greater extent for nonpolar adsorbents and to a lesser extent for compounds capable of specifically interacting with modifier molecules.     

Extended generalized octagons and the groupHe

Let be an extended generalized octagon such that the points of a triple {u, v, w} not on a block are pairwise adjacent if and only if the distance betweenv andw in the local generalized octagon _u equals 3 and there is a thick line through any point of _u . Then is one of the two examples related to the groups 2·L ₃(4).2² andHe. It is also shown that does not admit further extensions.