The sol-gel method was used to prepare two different starting gels containing SiCH3-groups for the preparation of SiOC ceramics. To understand the role of Si—H bonds in the incorporation of carbon into the SiOC network, gels prepared from a 1:2 mixture of triethoxysilane and methyldiethoxysilane (THDH2) and solely methyltriethoxysilane (TMe) were investigated. Thermogravimetric analysis coupled with mass spectroscopy (TG-MS) in inert atmosphere was performed to attain an insight into the decomposition reactions involved during gel-glass transformation. Samples calcined at different temperatures up to 1000°C were characterized by 29Si and 13C magic angle spinning nuclear magnetic resonance (MAS-NMR) spectroscopy. The presence of SiH groups in the starting gel allows an efficient conversion of Si—CH3 groups into CSi4 sites at lower temperatures. As a result, despite a much lower amount of carbon in the starting THDH2 gel (C/Si = 0.33) compared to the TMe gel (C/Si = 1), the amount of carbon inserted into the SiOC network of both glasses is equivalent, but the TMe sample contains the 10 fold amount of free carbon. 相似文献
3‐(Bromoacetyl)‐4‐hydroxy‐6‐methyl‐2H‐pyran‐2‐one was synthesized by the reaction of dehydroacetic acid (DHAA) with bromine in glacial acetic acid. Novel heterocyclic products were synthesized from the reaction of bromo‐DHAA with alkanediamines, phenylhydrazines, ortho‐phenylenediamines, and ortho‐aminobenzenethiol. The obtained new products 3‐(2‐N‐substituted‐acetyl)‐4‐hydroxy‐6‐methyl‐2H‐pyran‐2‐ones, 4‐hydroxy‐3‐[1‐hydroxy‐2‐(2‐phenylhydrazinyl)vinyl]‐6‐methyl‐2H‐pyran‐2‐one, 1‐(2,4‐dinitrophenyl)‐7‐methyl‐2,3‐dihydro‐1H‐pyrano[4,3‐c]pyridazine‐4,5‐dione, 3‐(3,4‐dihydroquinoxalin‐2‐yl)‐4‐hydroxy‐6‐methyl‐2H‐pyran‐2‐one/3‐(3,4‐dihydroquinoxalin‐2‐yl)‐6‐methyl‐2H‐pyran‐2,4(3H)‐dione, 6‐methyl‐3‐(3,4‐dihydroquinoxalin‐2‐yl)‐2H‐pyran‐2,4(3H)‐dione, and (E)‐3‐(2H‐benzo[b][1,4]thiazin‐3(4H)‐ylidene)‐6‐methyl‐2H‐pyran‐2,4(3H)‐dione were fully characterized by IR, 1H and 13C NMR, and mass spectra. J. Heterocyclic Chem., 2011. 相似文献
The 1,3-dipolar cycloadditions (13DC) of C-diethoxyphosphoryl-N-methylnitrone and N-(2-fluorophenyl) acrylamide have been studied using density functional theory (DFT) calculations at B3LYP/6-31G(d) level of theory. Our calculations show that this 13DC reaction takes place with complete ortho regioselectivity with endo stereoselectivity, which favours kinetically the formation of the ortho–endo cycloadduct, in agreement with the experimental observations. The inclusion of solvent effects does not modify the gas-phase selectivities but slightly decreases the reactivity of the reagents. Analysis of the bond order and charge transfer at the transition states indicates that this 13DC reaction takes place via a one-step asynchronous mechanism. Analysis of the DFT global reactivity indices and the Parr functions of the reagents allow us to provide an explanation of the regioselectivity of this 13DC reaction. 相似文献
The optimized Monier-Williams method is slightly modified so that it could be applied for determining sulfite content in dried garlic. Dried garlic sample is directly acidified in a reactor at a pH below 3. At this pH level, the alliinase enzyme activity is irreversibly blocked, and the sulfur-containing amino acids such as alliin (the most abundant) present in dried garlic cannot be transformed into corresponding thiosulfinates such as allicin, which is absent in dried garlic. This prevents allicin from reacting with added sulfites and being probably converted to S-allyl thiosulfate, which is not volatile and has no taste. It is found that at a pH below 2.4 and at boiling water temperature, allicin produces sulfur dioxide in adequate quantity to explain the false-positive results when utilizing the optimized Monier-Williams method with allicin suppression for unsulfited dried garlic samples. Finally, when garlic samples are stabilized in a phosphoric acid buffer at a final pH around 2.4, no sulfite is produced during the Monier-Williams distillation, which is further proof there are no naturally occurring sulfites in unsulfited dried garlic under these mild conditions. 相似文献
Hydrotalcite catalysts derived from NiAl and NiAlMg mixed oxides were successfully prepared by coprecipitation at a constant pH of 11. Physicochemical methods were investigated to determine their structural and textural properties. Using isopropanol as a probe molecule, the acid–base properties of the catalysts were investigated, and the evaluation of reactivity, selectivity and lifetime was established.
In this paper, we aim to investigate the role of cooperation between low level heuristics within a hyper-heuristic framework.
Since different low level heuristics have different strengths and weaknesses, we believe that cooperation can allow the strengths
of one low level heuristic to compensate for the weaknesses of another. We propose an agent-based cooperative hyper-heuristic
framework composed of a population of heuristic agents and a cooperative hyper-heuristic agent. The heuristic agents perform
a local search through the same solution space starting from the same or different initial solution, and using different low
level heuristics. The heuristic agents cooperate synchronously or asynchronously through the cooperative hyper-heuristic agent
by exchanging the solutions of the low level heuristics. The cooperative hyper-heuristic agent makes use of a pool of the
solutions of the low level heuristics for the overall selection of the low level heuristics and the exchange of solutions.
Computational experiments carried out on a set of permutation flow shop benchmark instances illustrated the superior performance
of the cooperative hyper-heuristic framework over sequential hyper-heuristics. Also, the comparative study of synchronous
and asynchronous cooperative hyper-heuristics showed that asynchronous cooperative hyper-heuristics outperformed the synchronous
ones. 相似文献
This paper discusses the Two-dimensional Loading Vehicle Routing Problem with Heterogeneous Fleet, Sequential Loading, and Item Rotation (2L-HFVRP-SR). Despite the fact that the 2L-HFVRP-SR can be found in many real-life situations related to the transportation of voluminous items, where heterogeneity of fleets, two-dimensional packing restrictions, sequential loading, and items rotation have to be considered, this rich version of vehicle routing-and-packing problem has been rarely analysed in the literature. Accordingly, this paper contributes to filling the gap by presenting a relatively simple-to-implement algorithm which is able to provide state-of-the-art solutions for such a complex problem in relatively short computational times. The proposed algorithm integrates inside an Iterated Local Search framework, biased-randomized versions of both vehicle routing and packing heuristics. The efficiency of the proposed algorithm is validated throughout an extensive set of computational tests. 相似文献
The problem of selecting sugarcane varieties has been widely discussed due to its computational complexity and its great impact for the sugar and ethanol industry. This paper proposes a new integrated mathematical programming model to deal with the selection of sugarcane varieties to be planted and the determination of the optimal period for planting and harvesting in order to increase production in the sugarcane industry. The proposed model optimizes the production of sugarcane and improves the quality of biomass whilst satisfying the main constraints imposed by sugarcane companies. The problem is modelled as an integer linear program and solved using an exact method to generate optimal solutions for small and medium problems. For large problems, metaheuristic approaches based on Genetic Algorithm and Variable Neighbourhood Search are proposed. According to the results, the proposed methodology provides sugarcane company managers with decision support in selecting the most suitable varieties and in determining the best period to plant and harvest their sugarcane.