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1.
Mathieu Boiret Anna de Juan Nathalie Gorretta Yves-Michel Ginot Jean-Michel Roger 《Analytica chimica acta》2015
Raman chemical imaging provides chemical and spatial information about pharmaceutical drug product. By using resolution methods on acquired spectra, the objective is to calculate pure spectra and distribution maps of image compounds. With multivariate curve resolution-alternating least squares, constraints are used to improve the performance of the resolution and to decrease the ambiguity linked to the final solution. Non negativity and spatial local rank constraints have been identified as the most powerful constraints to be used. 相似文献
2.
Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis
Dr. Damien Dambournet Dr. Karena W Chapman Dr. Mathieu Duttine Dr. Olaf Borkiewicz Dr. Peter J Chupas Dr. Henri Groult 《ChemistryOpen》2015,4(4):443-447
The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties. 相似文献
3.
Naphthalimide‐phthalimide derivative based photoinitiating systems for polymerization reactions under blue lights
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Pu Xiao Frédéric Dumur Jing Zhang Bernadette Graff Didier Gigmes Jean Pierre Fouassier Jacques Lalevée 《Journal of polymer science. Part A, Polymer chemistry》2015,53(5):665-674
Naphthalimide‐phthalimide derivatives (NDPDs) have been synthesized and combined with an iodonium salt, N‐vinylcarbazole, amine or 2,4,6‐tris(trichloromethyl)‐1,3,5‐triazine to produce reactive species (i.e., radicals and cations). These generated reactive species are capable of initiating the cationic polymerization of epoxides and/or the radical polymerization of acrylates upon exposure to very soft polychromatic visible lights or blue lights. Compared with the well‐known camphorquinone based systems used as references, the novel NDPD based combinations employed here demonstrate clearly higher efficiencies for the cationic polymerization of epoxides under air as well as the radical polymerization of acrylates. Remarkably, one of the NDPDs (i.e., NDPD2) based systems is characterized by an outstanding reactivity. The structure/reactivity/efficiency relationships of the investigated NDPDs were studied by fluorescence, cyclic voltammetry, laser flash photolysis, electron spin resonance spin trapping, and steady state photolysis techniques. The key parameters for their reactivity are provided. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 665–674 相似文献
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We present some new results for the asymptotic behavior of the complex parabolic Ginzburg–Landau equation. In particular, we establish that, as the parameter ε tends to 0, vorticity evolves according to motion by mean curvature in Brakke's weak formulation. The only assumption we make is a natural energy bound on the initial data. In some cases, we also prove convergence to enhanced motion in the sense of Ilmanen. To cite this article: F. Bethuel et al., C. R. Acad. Sci. Paris, Ser. I 336 (2003). 相似文献
6.
E. Mathieu Y. Foucher P. Dellamonica J. P. Daures 《Methodology and Computing in Applied Probability》2007,9(3):389-397
In AIDS control, physicians have a growing need to use pragmatically useful and interpretable tools in their daily medical
taking care of patients. Semi-Markov process seems to be well adapted to model the evolution of HIV-1 infected patients. In
this study, we introduce and define a non homogeneous semi-Markov (NHSM) model in continuous time. Then the problem of finding
the equations that describe the biological evolution of patient is studied and the interval transition probabilities are computed.
A parametric approach is used and the maximum likelihood estimators of the process are given. A Monte Carlo algorithm is presented
for realizing non homogeneous semi-Markov trajectories. As results, interval transition probabilities are computed for distinct
times and follow-up has an impact on the evolution of patients.
相似文献
7.
Following our investigation of the USA Standard and Poor index anti-bubble that started in August 2000 (Quant. Finance 2 (2002) 468), we analyze 38 world stock market indices and identify 21 “bearish anti-bubbles” and six “bullish anti-bubbles”. An “anti-bubble” is defined as a self-reinforcing price trajectory with self-similar expanding log-periodic oscillations. Mathematically, a bearish anti-bubble is characterize by a power law decrease of the price (or of the logarithm of the price) as a function of time and by expanding log-periodic oscillations. We propose that bearish anti-bubbles are created by positive price-to-price feedbacks feeding overall pessimism and negative market sentiment further strengthened by inter-personal interactions. Bullish anti-bubbles are here identified for the first time. The most striking discovery is that the majority of European and Western stock market indices as well as other stock indices exhibit practically the same log-periodic power law anti-bubble structure as found for the USA S&P500 index. These anti-bubbles are found to start approximately at the same time, August 2000, in all these markets. This shows a remarkable degree of worldwide synchronization. The descent of the worldwide stock markets since 2000 is thus an international event, suggesting the strengthening of globalization. 相似文献
8.
Joe Warren Scott Schaefer Anil N. Hirani Mathieu Desbrun 《Advances in Computational Mathematics》2007,27(3):319-338
In this paper we provide an extension of barycentric coordinates from simplices to arbitrary convex sets. Barycentric coordinates
over convex 2D polygons have found numerous applications in various fields as they allow smooth interpolation of data located
on vertices. However, no explicit formulation valid for arbitrary convex polytopes has been proposed to extend this interpolation
in higher dimensions. Moreover, there has been no attempt to extend these functions into the continuous domain, where barycentric
coordinates are related to Green’s functions and construct functions that satisfy a boundary value problem. First, we review
the properties and construction of barycentric coordinates in the discrete domain for convex polytopes. Next, we show how
these concepts extend into the continuous domain to yield barycentric coordinates for continuous functions. We then provide
a proof that our functions satisfy all the desirable properties of barycentric coordinates in arbitrary dimensions. Finally,
we provide an example of constructing such barycentric functions over regions bounded by parametric curves and show how they
can be used to perform freeform deformations.
相似文献
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10.
Fatima Hassine Said Gmouh Mathieu Pucheault Michel Vaultier 《Monatshefte für Chemie / Chemical Monthly》2007,57(12):1167-1174
In this work was presented an application of the use of task specific onium salts (TSOSs) as soluble supports in Grieco’s multicomponent synthesis of tetrahydroquinolines. These soluble supports are of wide applicability and combine advantages
of solid phase synthesis without its limitations with those of solution phase chemistry. After a simple washing step, products
were cleaved from the supports and obtained in pure form and good yields. 相似文献