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排序方式: 共有109条查询结果,搜索用时 31 毫秒
1.
Soft matter, like colloidal suspensions and surfactant gels, exhibit strong response to modest external perturbations. This
paper reviews our recent experiments on the nonlinear flow behaviour of surfactant worm-like micellar gels. A rich dynamic
behaviour exhibiting regular, quasi-periodic, intermittency and chaos is observed. In particular, we have shown experimentally
that the route to chaos is via Type-II intermittency in shear thinning worm-like micellar solution of cetyltrimethylammonium
tosylate where the strength of flow-concentration coupling is tuned by the addition of sodium chloride. A Poincaré first return
map of the time series and the probability distribution of laminar length between burst events show that our data are consistent
with Type-II intermittency. The existence of a ‘Butterfly’ intensity pattern in small angle light scattering (SALS) measurements
performed simultaneously with the rheological measurements confirms the coupling of flow to concentration fluctuations in
the system under study. The scattered depolarised intensity in SALS, sensitive to orientational order fluctuations, shows
the same time-dependence (like intermittency) as that of shear stress. 相似文献
2.
R. Ganapathy 《Journal of Radioanalytical and Nuclear Chemistry》1978,43(1):131-138
The thermal neutron activation cross-section of94Zr was found to be 49.3±0.6 millibarns. It is shown that neutron activation analysis of Zr in silicate samples with a Zr/U
ratio<10 has considerable uncertainty due to fission contribution. A correction factor for the fission contribution has been
determined experimentally. 相似文献
3.
R. Ganapathy 《Journal of Radioanalytical and Nuclear Chemistry》1978,44(1):199-206
A rapid non-destructive neutron activation technique for the determination of the238U/235U ratio is described. Reagent grade uranium salts from commercial sources have a widely variable238U/235U ratio. The isotopic composition of uranium found in such salts is quite different from the natural value. This difference
is largely due to the use of by-product uranium depleted in235U. 相似文献
4.
The kinetics of oxidation of allyl alcohol byN-bromosuccinimide (NBS) has been studied at 35 °C in aqueous medium. The reaction shows first order dependence on bothNBS and allyl alcohol. In fairly high acid concentration, there is no change in the rate of the reaction but at low acid concentration, the rate is considerably enhanced. There is no primary salt effect. At varying mercuric acetate concentrations, the rate constant remains the same. But in the absence of mercuric acetate, the rate is enhanced. The kinetic parameters,E
a,Arrhenius factorA, H, G and S have been calculated. A rate law in agreement with experimental results has been derived. A mechanism is proposed.
Kinetik und Mechanismus der Oxidation von Allylalkohol mixN-Bromsuccinimid
Zusammenfassung Die Kinetik der Oxidation von Allylalkohol mitN-Bromsuccinimid (NBS) wurde bei 35 °C in wäßrigem Medium untersucht. Die Reaktion zeigt erste Ordnung gegenüberNBS und Allylalkohol. Bei relativ hoher Säurekonzentration zeigt sich keine Änderung der Reaktionsgeschwindigkeit, bei niedriger Säurekonzentration wird die Reaktionsgeschwindigkeit beträchtlich erhöht. Es wurde kein primärer Salzeffekt festgestellt. Bei varriierender Quecksilberacetatkonzentration bleibt die Reaktionsgeschwindigkeit gleich, bei Abwesenheit von Quecksilberacetat wird jedoch die Geschwindigkeitskonstante erhöht. Die kinetischen Parameter,E a, derArrheniusfaktorA, H , G und S wurden bestimmt. Ein Geschwindigkeitsgesetz in Übereinstimmung mit den experimentellen Befunden wurde abgeleitet und ein Mechanismus vorgeschlagen.相似文献
5.
6.
R. Ganapathy 《Communications in Nonlinear Science & Numerical Simulation》2012,17(12):4544-4550
We consider the concept of quasisoliton propagation in a dispersion management fiber and study the soliton dynamics for soliton dispersion management case, soliton energy control case and guiding center soliton case. We also study the interaction scenario in detail for all the cases. 相似文献
7.
Chandrika Nanjappa Gopalpur Nagendrappa Pasura Subbaiah Sujan Ganapathy Shirur Dakappa Shruthi Sunil S. More 《合成通讯》2013,43(22):2529-2545
A new 2,2′-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS)-radical scavenging and antiproliferative agents of pyrrolo[1,2-a]quinoline derivatives have been synthesized. An efficient method for the synthesis of 14 novel diversified pyrrolo[1,2-a]quinoline derivatives has been described using 4-(1,3-dioxolan-2-yl)quinoline and different phenacyl bromides in acetone and followed by reacting with different acetylenes in dimethylformamide/K2CO3. The structure of the newly synthesized compounds was determined by infrared, 1H NMR, 13C NMR, mass spectrometry, and elemental analysis. The in vitro antioxidant activity revealed that among all the tested compounds 5n exhibited maximum scavenging activity with ABTS. Compound 5b has showed good antiproliferative activity as an inhibitor of epidermal growth factor receptor (EGFR) tyrosine kinase. 相似文献
8.
Rajendran Duraisamy Ramalingam Ganapathy Sundaram Esakkimuthu Jawahar Paulraj Sivakumar Vaithilingam Mahian Omid Bellos Evangelos 《Journal of Thermal Analysis and Calorimetry》2020,140(1):33-51
Journal of Thermal Analysis and Calorimetry - The solar collector (reflector and receiver) is the primary device being used in the concentrating solar power technologies for tapping the solar... 相似文献
9.
Free convection motion induced by a travelling thermal wave in a horizontal porous layer is studied analytically assuming the validity of the Brinkman model. Under Boussinesq and long-wave approximations analytical expressions are obtained for the fluctuating and mean velocity components. The vertically averaged mean motion is highlighted. 相似文献
10.
K. Porsezian K. Nithyanandan R. Vasantha Jayakantha Raja R. Ganapathy 《The European physical journal. Special topics》2013,222(3-4):625-640
The supercontinuum generation (SCG) in liquid core photonic crystal fiber (LCPCF) with versatile nonlinear response and the spectral broadening in dual core optical fiber is presented. The analysis is presented in two phase, phase I deals with the SCG in LCPCF with the effect of saturable nonlinearity and re-orientational nonlinearity. We identify and discuss the generic nature of the saturable nonlinearity and reorientational nonlinearity in the SCG, using suitable model. For the physical explanation, modulational instability and soliton fission techniques is implemented to investigate the impact of saturable nonlinear response and slow nonlinear response, respectively. It is observed that the saturable nonlinearity inevitably suppresses the MI and the subsequent SCG. On the other hand, the re-orientational nonlinearity contributes to the slow nonlinear response in addition to the conventional fast response due to the electronic contribution. The phase II features the exclusive investigation of the spectral broadening in the dual core optical fiber. 相似文献