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R. Santhosh Reddy Tanveer Mahamadali Shaikh Varun Rawat Pratibha U. Karabal Gajanan Dewkar Gurunath Suryavanshi Arumugam Sudalai 《Catalysis Surveys from Asia》2010,14(1):21-32
A novel, exceptionally stable titanium superoxide radical ion was prepared and its structure determined by FTIR, ESR, Raman
spectroscopy, X-ray diffraction, thermogravimetric/differential thermal analysis and elemental analysis. This heterogeneous
catalyst has been found to be effective for the selective oxidation of aromatic amines and phenols to the corresponding nitro
aromatics and p-quinones, respectively. In addition, this non-toxic, inexpensive and reusable catalyst has also been used in aminobromination
of olefins, which proceed to give the 1, 2-bromoaminated anti-Markovnikov product. A brief account of these results is summarized in this review. 相似文献
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Molar extinction coefficients of some carbohydrates viz. l-arabinose (C5H10O5), d-glucose (C6H12O6), d-mannose (C6H12O6), d-galactose (C6H12O6), d(-) fructose (C6H12O6) and maltose (C12H24O12) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by gamma ray transmission method in a
narrow beam good geometry set-up. These coefficients have been found to depend upon the photon energy following a 4-parameter
polynomial. These extinction coefficients for different sugars having the same molecular formula have same values varying
within experimental uncertainty. Within concentration ranges studied, Beer-Lambert law is obeyed very well. 相似文献
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离子液体作为溶剂/催化剂用于卤代烃对胺的选择性烷基化反应 总被引:1,自引:0,他引:1
在三乙胺存在下,在离子液体([bmim]I和[bmim]PF6)中进行了各种卤代烃对胺类化合物中氨基的选择性烷基化反应.反应在相对温和的条件下进行,转化率和选择性优异.离子液体可以回收并重复使用. 相似文献
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The structure of 1,3-dehydro-5-adamantyl cation and its isoelectronic boron analogue 1,3-dehydro-5-boraadamantane as well as some related adamantane systems, hitherto unknown as persistent long-lived species, were investigated by using the density functional theory (DFT) method. (13)C and (11)B NMR chemical shifts of the compounds were also calculated using the IGLO method. Stabilization of the systems due to homoconjugation is discussed. 相似文献
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GK Johri Akhilesh Tiwari Saumya Saxena Rajesh Sharma Kuldeep Srivastava Manoj Johri 《Pramana》2002,58(3):563-567
Calculations for the relative width (Δω/ω0) as a function of refractive index and relative radius of the photonic band gap for the fcc closed packed 3-D dielectric
microstructure are reported and comparison of experimental observations and theoretical predictions are given. This work is
useful for the understanding of photonic crystals and occurrence of the photonic band gap. 相似文献
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[reaction: see text] NaIO(4) oxidizes alkali metal halides efficiently in aqueous medium to halogenate alkenes and aromatics and produce the corresponding halo derivatives in excellent regio and stereoselectivity. The system also demonstrates the asymmetric version of bromo hydroxylation using beta-cyclodextrin complexes, resulting in moderate ee. 相似文献
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<正>The square soft-edge diaphragm with round angle is designed by Matlab,and is sent to a liquid crystal spatial light modulator by the computer.In order to obtain precompensation for the following laser system, local diaphragm transmission can be adjusted by feedback signals of surface-channel charge-coupled device (SCCD).This method can reduce the diffraction effect and realize no modulation,high stability,high homogeneity,and large scale laser beam.Several parameters of soft-edge diaphragms which affect the laser beam quality are studied systematically,and the optimized values are obtained.The method can avoid the serious modulation of hard edges and provide soft-edge diaphragms of different shapes in a fast and convenient way for the large scale laser beam system. 相似文献
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Copper(II) triflate catalyzes efficiently the three-component condensation reaction of an aldehyde, β-ketoester and urea in acetonitrile to afford the corresponding 3,4-dihydropyrimidin-2(1H)-ones in high yields. The catalyst exhibited remarkable reusable activity. 相似文献
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