首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   41篇
  免费   6篇
化学   26篇
晶体学   2篇
数学   13篇
物理学   6篇
  2021年   1篇
  2020年   3篇
  2019年   2篇
  2018年   1篇
  2017年   2篇
  2016年   6篇
  2015年   6篇
  2014年   4篇
  2013年   3篇
  2012年   1篇
  2011年   2篇
  2010年   2篇
  2005年   2篇
  2003年   2篇
  2002年   1篇
  2000年   2篇
  1999年   1篇
  1997年   2篇
  1992年   1篇
  1988年   1篇
  1970年   1篇
  1968年   1篇
排序方式: 共有47条查询结果,搜索用时 296 毫秒
1.
The title compounds were prepared by dehydrocyclization of corresponding substituted N-nitrosoglycines obtained from isomeric o-, m- and p-aminodiphenyl ether with ethyl bromoacetate and subsequent nitrosation of the intermediate N-arylsubstituted glycines.  相似文献   
2.
The new tertiary furfurylamine with triple bond as a dienophylic part i.e. N-(5-methyl-2-furfuryl)-N-prop-2-ynyl-p-toluidine (1) was prepared and the intramolecular Diels-Alder reaction of the amine (1) was performed under microwave irradiation conditions and by heating a benzene solution of the amine under nitrogen. Comparing the results of the usual thermal and the MAOS reaction, we confirmed our expectations that MAOS could promote the outcome of IMDA reaction of the suitably N-substituted tertiary 2-furfuryl-amines. In the present example, N-p-tolyl-5-methyl-5,7a-dihydro-5,7a-epoxyisoindoline was obtained in much better yield and of higher purity.  相似文献   
3.
Double-polarization asymmetries for inclusive ep scattering were measured at Jefferson Lab using 2.6 and 4.3 GeV longitudinally polarized electrons incident on a longitudinally polarized NH3 target in the CLAS detector. The polarized structure function g(1)(x,Q2) was extracted throughout the nucleon resonance region and into the deep inelastic regime, for Q(2)=0.15-1.64 GeV2. The contributions to the first moment Gamma(1)(Q2)= integral g(1)(x,Q2) dx were determined up to Q(2)=1.2 GeV2. Using a parametrization for g(1) in the unmeasured low x regions, the complete first moment was estimated over this Q2 region. A rapid change in Gamma(1) is observed for Q2<1 GeV2, with a sign change near Q(2)=0.3 GeV2, indicating dominant contributions from the resonance region. At Q(2)=1.2 GeV2 our data are below the perturbative QCD evolved scaling value.  相似文献   
4.

Abstract  

In order to investigate the intramolecular [4 + 2] cycloaddition, we prepared some new tertiary N-(5-substituted-2-furfuryl)-N-prop-2-ynyl-p-toluidines [Hergold-Brundić et al., Acta Cryst C56:e520, 2000; Mance and Jakopčić, Mol Divers 9:229, 2005; Mance, “unpublished results”] by the alkylation of secondary N-(5-substituted-2-furfuryl)-p-toluidines with the propargyl-bromide [Mance and Šindler-Kulyk, Synth Commun 26:923, 1996]. In the course of preparation of N-(5-methoxy-2-furfuryl)-N-prop-2-ynyl-p-toluidine [Mance, “unpublished results”], besides the main product (compound 1) (Scheme 1) we obtained N,N-di(prop-2-ynyl)-p-toluidine (compound 2) as the colourless crystals. The title compound 2, N,N-di(prop-2-ynyl)-p-toluidine, C13H13N, crystallizes in monoclinic C 2/c space group with unit cell parameters: a = 19.5319(9) ?, b = 7.5230(3) ?, c = 15.9000(7) ?, β = 112.554(5)°, V = 2157.64(18) ?3, Z = 8. The crystal structure is dominated by van der Waals forces only. The bond distances around amine N atom correspond to σ dominated bonds (1.467(2), 1.462(2) and 1.419(2) ?). The angles sum around amine N atom is in accord with sp3 hybridization (343°).  相似文献   
5.
1H‐detection can greatly improve spectral sensitivity in biological solid‐state NMR (ssNMR), thus allowing the study of larger and more complex proteins. However, the general requirement to perdeuterate proteins critically curtails the potential of 1H‐detection by the loss of aliphatic side‐chain protons, which are important probes for protein structure and function. Introduced herein is a labelling scheme for 1H‐detected ssNMR, and it gives high quality spectra for both side‐chain and backbone protons, and allows quantitative assignments and aids in probing interresidual contacts. Excellent 1H resolution in membrane proteins is obtained, the topology and dynamics of an ion channel were studied. This labelling scheme will open new avenues for the study of challenging proteins by ssNMR.  相似文献   
6.
Rényi (Mat Lapok 7:77–100, 1956) made a definition that gives a generalization of simple normality in the context of Q-Cantor series. In Mance ), a definition of Q-normality was given that generalizes the notion of normality in the context of Q-Cantor series. In this work, we examine both Q-normality and Q-distribution normality, treated in Lafer (Normal numbers with respect to Cantor series representation, 1974) and S̆alát (Czechoslovak Math J 18(93):476–488, 1968). Specifically, while the non-equivalence of these two notions is implicit in Lafer (Normal numbers with respect to Cantor series representation. Washington State University, 1974), in this paper, we give an explicit construction witnessing the nontrivial direction. That is, we construct a base Q as well as a real x that is Q-normal yet not Q-distribution normal. We next approach the topic of simultaneous normality by constructing an explicit example of a base Q as well as a real x that is both Q-normal and Q-distribution normal.  相似文献   
7.
8.
1H detection can significantly improve solid‐state NMR spectral sensitivity and thereby allows studying more complex proteins. However, the common prerequisite for 1H detection is the introduction of exchangeable protons in otherwise deuterated proteins, which has thus far significantly hampered studies of partly water‐inaccessible proteins, such as membrane proteins. Herein, we present an approach that enables high‐resolution 1H‐detected solid‐state NMR (ssNMR) studies of water‐inaccessible proteins, and that even works in highly complex environments such as cellular surfaces. In particular, the method was applied to study the K+ channel KcsA in liposomes and in situ in native bacterial cell membranes. We used our data for a dynamic analysis, and we show that the selectivity filter, which is responsible for ion conduction and highly conserved in K+ channels, undergoes pronounced molecular motion. We expect this approach to open new avenues for biomolecular ssNMR.  相似文献   
9.
Let Q = (qn)n=1 be a sequence of bases with qi ≥ 2. In the case when the qi are slowly growing and satisfy some additional weak conditions, we provide a construction of a number whose Q-Cantor series expansion is both Q-normal and Q-distribution normal. Moreover, this construction will result in a computable number provided we have some additional conditions on the computability of Q, and from this construction we can provide computable constructions of numbers with atypical normality properties.  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号